2,2,3,3,4,4,5,5,6,6-Decafluoroheptane-1,7-diol

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代醇
• 英文名称: 2,2,3,3,4,4,5,5,6,6-Decafluoroheptane-1,7-diol
• 化学式: C₇H₆F₁₀O₂
• 分子量: 312.1
• InChiKey: VRDPFJAIEGQWCQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  19
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  12

文献信息

• Block copolymer and application thereof
  申请人：Shinoda Hiroshi

  公开号：US20060182678A1

  公开（公告）日：2006-08-17

  The present invention relates to a block copolymer having at least one block having an acid group and at least one block having substantially no acid group, wherein one end group of a repeating unit in at least one block of all blocks is oxygen and/or sulfur, and at least one repeating unit of a block having substantially no acid group contains a halogen atom. The block copolymer of the present invention gives a polymer electrolyte membrane which is excellent not only in heat resistance and proton conductivity but also in water resistance and chemical stability, and is useful as an electrolyte for a proton conducting membrane etc. of a fuel cell.

  本发明涉及一种嵌段共聚物，其具有至少一个具有酸基的块和至少一个基本上没有酸基的块，其中至少一个块的所有块的重复单元的一个端基团是氧和/或硫，并且至少一个基本上没有酸基的块的重复单元包含一个卤素原子。本发明的嵌段共聚物给出了一种聚合物电解质膜，该膜不仅具有优异的耐热性和质子导电性，而且具有良好的耐水性和化学稳定性，可用作燃料电池的质子导体膜等电解质。
• Fluorinated acrylamide silane monomers and polymers
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0529895A1

  公开（公告）日：1993-03-03

  The present invention provides novel fluorinated acrylamide silane monomers which are useful as adhesion promoting agents in optical fiber cladding compositions. Polymerization of the novel monomers, optionally in the presence compatible ethylenically-unsaturated monomers, provides homopolymers and copolymers which are useful as non-wetting agents.

  本发明提供了新型氟化丙烯酰胺硅烷单体，可用作光纤包层组合物中的附着力促进剂。新型单体可在与乙烯不饱和单体相容的情况下进行聚合，从而产生可用作非润湿剂的均聚物和共聚物。
• POLYCARBONATE-BASE POLYMER, PRODUCTION PROCESS, RESIN COATING FLUID PREPARED THEREFROM, AND ELECTROPHOTOGRAPHIC PHOTORECEPTOR PREPARED THEREFROM
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0837085A1

  公开（公告）日：1998-04-22

  A polymer comprising mainly repeating units (1) and/or repeating units (2), containing optionally terminal groups (3) and/or repeating units (4), and having a reduced viscosity [ηsp/c] of 0.2 to 10.0 dl/g as measured in a 0.5 g/dl solution thereof in methylene chloride at 20°C; a resin coating fluid containing the polymer, a charge-transfer substance and a solvent; and an electrophotographic photoreceptor containing the polymer as a binder resin in a photosensitive layer, wherein Rf1 represents a group that is composed of at least carbon atoms and fluorine atoms and bonded directly to the two oxygen atoms of the carbonate linkage in the general formula (1) without any intervening arylene group; and Rf2 represents a group that is composed of at least carbon atoms and fluorine atoms and bonded directly to one of the oxygen atoms of the carbonate linkage in the general formula (3) without any intervening arylene group.

  一种主要由重复单元（1）和/或重复单元（2）组成的聚合物，含有任选的末端基团（3）和/或重复单元（4），在 0.其中 Rf1 代表至少由碳原子和氟原子组成并直接与通式（1）中碳酸酯连接的两个氧原子键合的基团，而没有任何芳基介入；Rf2 代表一个至少由碳原子和氟原子组成的基团，直接与通式（3）中碳酸酯链节的一个氧原子键合，中间不含任何芳烯基。
• Perfluoro group-containing compounds and hardened polymer of the same
  申请人：Kyoeisha Chemical Co., Ltd.

  公开号：EP1036790A1

  公开（公告）日：2000-09-20

  A perfluoro group-containing compound are represented by the following formula (I): -Rf- is a perfluoro group; and -A represents -OH or a group: or -CyF2y+1 or -CzF2z-1 and a perfluoro group-containing polymerizable compound represented by the following formula (II):         R1―O―CH2―CH(OH)―CH2―O―Rf―B     (II) In Formula (II), -Rf- is a perfluoro group; -B is -OH or -O-CH2-CH(OH)-CH2-O-R2, or -CyF2y+1 or -CzF2z-1; and R1 and R2 each is a dehydroxyl residue of a (meth)acryloyl group-containing compound or a vinyl group-containing compound. The hardened polymer from the compound has water-repellency, oil-repellency and adhering ability.

  含全氟基团的化合物由下式(I)表示： -Rf-是全氟基团；-A 代表-OH 或一个基团： 或-CyF2y+1或-CzF2z-1，以及由下式（II）表示的含全氟基团的可聚合化合物： R1-O-CH2-CH(OH)- -O-Rf-B (II) 在式(II)中，-Rf- 是全氟基团；-B 是-OH 或-O- -CH(OH)- -O-R2，或-CyF2y+1 或-CzF2z-1；R1 和 R2 各自是含(甲基)丙烯酰基化合物或含乙烯基化合物的脱羟基残基。由该化合物制成的硬化聚合物具有憎水性、憎油性和粘附能力。
• BLOCK COPOLYMER AND APPLICATION THEREOF
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP1555282A1

  公开（公告）日：2005-07-20

  The present invention relates to a block copolymer having at least one block having an acid group and at least one block having substantially no acid group, wherein one end group of a repeating unit in at least one block of all blocks is oxygen and/or sulfur, and at least one repeating unit of a block having substantially no acid group contains a halogen atom. The block copolymer of the present invention gives a polymer electrolyte membrane which is excellent not only in heat resistance and proton conductivity but also in water resistance and chemical stability, and is useful as an electrolyte for a proton conducting membrane etc. of a fuel cell.

  本发明涉及一种嵌段共聚物，它至少有一个嵌段具有酸基，至少有一个嵌段基本上没有酸基，其中所有嵌段中至少有一个嵌段的重复单元的一个端基是氧和/或硫，而基本上没有酸基的嵌段的至少一个重复单元含有卤素原子。本发明的嵌段共聚物提供了一种聚合物电解质膜，它不仅具有优异的耐热性和质子传导性，还具有优异的耐水性和化学稳定性，可用作燃料电池质子传导膜等的电解质。