2-(tert-butoxy)oxirane | 83584-83-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 环氧化物
• 英文名称: 2-(tert-butoxy)oxirane
• 英文别名: 2-[(2-Methylpropan-2-yl)oxy]oxirane；2-[(2-methylpropan-2-yl)oxy]oxirane
• CAS: 83584-83-2
• 化学式: C₆H₁₂O₂
• 分子量: 116.16
• InChiKey: UVHWTCJCRATVIJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  8
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  21.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-(tert-butoxy)oxirane 在 potassium tert-butylate 、 叔丁醇 作用下， 生成 3,6-Dioxa-4-tert.-butoxymethylen-1,8-octandicarbonsaeure
  参考文献：
  名称：

  羟甲基18-crown-6和羟甲基[2.2.2] cryptand：用于将两个聚醚与亲脂性链和聚合物基质结合的通用衍生物

  摘要：

  羟甲基的存在使18-crown-6和[2.2.2] cryptand的功能化变得容易。因此可获得各种亲脂性和聚合物负载的大环聚醚。它们是高效且易于回收的相转移催化剂。

  DOI：

  10.1016/s0040-4039(01)86788-5

文献信息

• Trinuclear {Co²⁺–M³⁺–Co²⁺} complexes catalyze reduction of nitro compounds
  作者：Sumit Srivastava、Manvender S. Dagur、Afsar Ali、Rajeev Gupta

  DOI：10.1039/c5dt03442f

  日期：——

  characterization of trinuclear Co2+–Co3+–Co2+} and Co2+–Fe3+–Co2+} complexes with accessible peripheral Co(II) ions. Both trinuclear complexes function as efficient reusable heterogeneous catalysts for the selective reduction of assorted nitro compounds to the corresponding amines. The mechanistic investigations suggest the involvement of a Co(II)–Co(I) cycle in the catalysis.

  这项工作介绍了三核Co 2+ –Co 3+ –Co 2+ }和Co 2+ –Fe 3+ –Co 2+ }络合物的合成和表征，这些络合物具有可利用的外围Co（II）离子。两种三核配合物均起着有效的可重复使用的多相催化剂的作用，用于将各种硝基化合物选择性还原为相应的胺。机理研究表明，Co（II）–Co（I）循环参与了催化作用。
• Manganese Complexes of Pyrrole‐ and ­Indolecarboxamide Ligands: Synthesis, Structure, Electrochemistry, and Applications in Oxidative and Lewis‐Acid‐­Assisted Catalysis
  作者：Sunil Yadav、Sushil Kumar、Rajeev Gupta

  DOI：10.1002/ejic.201500773

  日期：2015.11

  N4 coordination sphere about the MnIII ion. The MnIII complexes of pyrrolecarboxamide ligands are square pyramidal with a fifth Cl atom, whereas analogous complexes of indolecarboxamide ligands are essentially square planar. Electrochemical studies reveal highly negative MnIII/II and moderately positive MnIV/III redox potentials. In situ generated Mn4+ species of the pyrrolecarboxamide ligands were

  这项工作展示了由吡咯-和吲哚甲酰胺配体支持的 MnIII 配合物的合成和结构、光谱和电化学性质。在所有情况下，各自的配体构成了围绕 MnIII 离子的 N4 配位球。吡咯甲酰胺配体的 MnIII 配合物是具有第五个 Cl 原子的方锥体，而吲哚甲酰胺配体的类似配合物基本上是方形平面。电化学研究显示高度负的 MnIII/II 和适度正的 MnIV/III 氧化还原电位。原位生成的吡咯甲酰胺配体的 Mn4+ 物种通过吸收和电子顺磁共振光谱进行表征。通过使用PhIO作为氧代转移剂，所有配合物在烯烃环氧化反应中都起到催化剂的作用。所有配合物还充当路易斯酸催化剂，用于各种环氧化物与各种亲核试剂的开环反应。我们还展示了一个一锅、两步的环氧化反应，然后是开环，这说明了本复合物的催化意义。重要的是，发现在配体上带有给电子取代基的 MnIII 配合物是更好的催化剂。
• Three-Dimensional {Co³⁺–Zn²⁺} and {Co³⁺–Cd²⁺} Networks Originated from Carboxylate-rich Building Blocks: Syntheses, Structures, and Heterogeneous Catalysis
  作者：Girijesh Kumar、Rajeev Gupta

  DOI：10.1021/ic400536e

  日期：2013.10.7

  The present work shows the utilization of Co3+ complexes appended with either para- or meta-arylcarboxylic acid groups as the molecular building blocks for the construction of three-dimensional Co3+-Zn2+} and Co3+-Cd2+} heterobimetallic networks. The structural characterizations of these networks show several interesting features including well-defined pores and channels. These networks function as heterogeneous and reusable catalysts for the regio- and stereoselective ring-opening reactions of various epoxides and size-selective cyanation reactions of assorted aldehydes.
• A Metalloligand Appended with Thiazole Rings: Heterometallic {Co ³⁺ –Zn ²⁺ } and {Co ³⁺ –Cd ²⁺ } Complexes and Their Heterogeneous Catalytic Applications
  作者：Deepak Bansal、Geeta Hundal、Rajeev Gupta

  DOI：10.1002/ejic.201403072

  日期：2015.2

  AbstractThis work describes a Co3+‐based metalloligand containing appended thiazole rings and its reactions with secondary metal ions to produce heterometallic Co3+–Zn2+} and Co3+–Cd2+} complexes. Structural studies show that some of the appended thiazole rings from the metalloligand coordinate to secondary metal ions, whereas the remaining ones act as hydrogen‐bond acceptors to metal‐bound CH3OH or H2O molecules. These heterometallic complexes function as reusable heterogeneous catalysts for the ring‐opening reactions of epoxides as well as cyanation and Knoevenagel condensation reactions of aldehydes. The catalytic results illustrate that the microenvironment remains intact during the catalysis and potentially enhances the substrate interaction with the Lewis acidic secondary metal ions.
• US8067526B2
  申请人：——

  公开号：US8067526B2

  公开（公告）日：2011-11-29