5-Hydroxymethyl-bicyclo<2.2.2>oct-2-en | 5019-90-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 5-Hydroxymethyl-bicyclo<2.2.2>oct-2-en
• 英文别名: Bicyclo[2.2.2]oct-5-en-2-ylmethanol；2-bicyclo[2.2.2]oct-5-enylmethanol
• CAS: 5019-90-9
• 化学式: C₉H₁₄O
• mdl: MFCD11055251
• 分子量: 138.21
• InChiKey: KOCJWKFHBTXNJS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.777
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  5-Hydroxymethyl-bicyclo<2.2.2>oct-2-en 在 吡啶 、 sodium iodide 作用下， 生成 5-Cyanmethyl-bicyclo<2.2.2>octen-(2)
  参考文献：
  名称：

  Tricyclo[4.4.0.03,8]decane to adamantane rearrangement

  摘要：

  DOI：

  10.1021/ja01020a028
• 作为产物：
  描述：

  双环[2.2.2]辛-5-烯-2-甲醛 在 lithium aluminium tetrahydride 作用下， 以 乙醚 为溶剂， 生成 5-Hydroxymethyl-bicyclo<2.2.2>oct-2-en
  参考文献：
  名称：

  Persistence of stereoselectivity in the intramolecular Diels-Alder reactions of 5-alkenylcyclohexa-1,3-dienes. Novel route to functionalized bridged tricyclic rings using a regenerable diene

  摘要：

  DOI：

  10.1021/ja00798a035

文献信息

• Novel polymers for photoresist and photoresist compositions using the same
  申请人：Hyundai Electronics Industries Co., Ltd.

  公开号：US20030191259A1

  公开（公告）日：2003-10-09

  The present invention relates to photoresist monomers, polymers formed therefrom and photoresist compositions suitable for photolithography processes employing a DUV light source, such as KrF (249 nm) and ArF(193 nm); EUV; VUV; E-beam; ion-beam; and X-ray. Photoresist monomers of the present invention are represented by the following Chemical Formula 1: 1 wherein, m is 1 or 2. Polymers of the present invention comprise repeating units derived from the comonomer of Chemical Formula 1, preferably together with monomers of the following Chemical Formula 2: 2 wherein, R* is an acid-labile group, and l is 1 or 2.

  本发明涉及光阻单体、由其形成的聚合物和适用于使用DUV光源（如KrF（249 nm）和ArF（193 nm））、EUV、VUV、电子束、离子束和X射线的光刻工艺的光阻组合物。本发明的光阻单体由以下化学式1表示：其中，m为1或2。本发明的聚合物包括由化学式1的共聚单体衍生的重复单元，与以下化学式2的单体一起，其中R*是酸可降解基团，l为1或2。
• NOVEL POLYMERS FOR PHOTORESIST AND PHOTORESIST COMPOSITIONS USING THE SAME
  申请人：——

  公开号：US20020049287A1

  公开（公告）日：2002-04-25

  The present invention relates to photoresist monomers, polymers formed therefrom and photoresist compositions suitable for photolithography processes employing a DUV light source, such as KrF (249 nm) and ArF(193 nm); EUV; VUV; E-beam; ion-beam; and X-ray. Photoresist monomers of the present invention are represented by the following Chemical Formula 1: 1 wherein, m is 1 or 2. Polymers of the present invention comprise repeating units derived from the comonomer of Chemical Formula 1, preferably together with monomers of the following Chemical Formula 2: 2 wherein, R* is an acid-labile group, and l is 1 or 2.

  本发明涉及光阻单体、由其形成的聚合物以及适用于使用DUV光源（如KrF（249 nm）和ArF（193 nm））、EUV、VUV、电子束、离子束和X射线的光刻工艺的光阻组合物。本发明的光阻单体由以下化学式1表示：其中，m为1或2。本发明的聚合物包括由化学式1的共聚单体衍生的重复单元，与以下化学式2的单体一起构成，其中，R*是酸可降解基团，l为1或2。
• Heterotricyclic cage compounds, processes for their production, pharmaceutical compositions containing them, and their use as medicinal antiviral agents
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0040944A1

  公开（公告）日：1981-12-02

  Compounds of the formula: wherein A, is a single bond, a C2-C5 alkylene group or a C1-C5 alkylidene group, A2 is a C2-C3 alkylene group or a C1-C3 alkylidene group, A3 is a C2-C4 alkylene group or a C1-C4 alkylidene group, X is -O- or -SOn- (wherein n is an integer of 0 to 2), R, is a hydrogen atom, a C1-C5 alkyl group, a C3-C5 alkenyl group and R2 is a hydrogen atom, a C1-C5 alkyl group, a C3-C5 alkenyl group, a C2-C5 alkanoyl group, a C2-C5 alkoxycarbonyl group, a benzyloxycarbonyl group, or when taken together with the adjacent nitrogen atom, R, and R2 may form a five or six-membered heterocyclic group, which are useful as antiviral agents.

  式中的化合物： 其中 A 为单键、C2-C5 亚烷基或 C1-C5 亚烷基，A2 为 C2-C3 亚烷基或 C1-C3 亚烷基，A3 为 C2-C4 亚烷基或 C1-C4 亚烷基，X 为 -O- 或 -SOn- （其中 n 为 0 至 2 的整数），R 为氢原子、C1-C5 烷基、C3-C5 烯基，R2 为氢原子、C1-C5 烷基、C3-C5 烯基、C2-C5 烷氧基、C3-C5 烯基、R2是氢原子、C1-C5烷基、C3-C5烯基、C2-C5烷酰基、C2-C5烷氧羰基、苄氧羰基，或者当 R 和 R2 与相邻的氮原子结合在一起时，可形成五元或六元杂环基团，可用作抗病毒剂。
• Allyl terminated macromolecular monomers of polyethers
  申请人：The B.F. GOODRICH Company

  公开号：EP0218079A2

  公开（公告）日：1987-04-15

  A cationic ring-opening polymerization of a cylic ether ("CE") in conjunction with an unsaturated alcohol (propagator) having an allyl double bond, produces a polyether macromer having an allylic group near one end and a hydroxyl group at the other. The polymerization proceeds by polyaddition of the CE to the OH group which is the propagating species. The CE is an alkylene oxide or an aliphatic or aromatic glycidyl ether; the propa­gator is a primary or secondary alcohol which, if cyclic may have a single internal double bond in one ring. The catalyst is a Friedel-Crafts acid, strong protic organic or inorganic acid, oxonium salt, or the like. The macromer formed may be homopolymerized to yield a poly­vinyl homomacromer with pendant chains of polymerized CE; or the CE may be copolymerized with a wide variety of olefinically unsaturated monomers to form a macromer copolymer; or, plural cyclic ethers may be (a) sequenti­ally polymerized to form macromer block copolyethers, or, (b) polymerized randomly to form macromer copoly­ether copolymers. The cationically ring-opened macromer formed always contains a trace of a cyclic oligomer of the CE.

  环状醚（"CE"）与具有烯丙基双键的不饱和醇（促进剂）进行阳离子开环聚合，可产生一种聚醚大分子，其一端附近具有烯丙基，另一端具有羟基。聚合反应是通过 CE 与羟基的加成反应进行的。CE 是环氧亚烷基或脂肪族或芳香族缩水甘油醚；繁殖体是伯醇或仲醇，如果是环状的，可能在一个环上有一个内部双键。催化剂为 Friedel-Crafts 酸、强质子有机酸或无机酸、羰基鎓盐或类似物质。形成的大单体可进行均聚，生成具有聚合 CE 下垂链的聚乙烯均大单体；或将 CE 与多种烯烃不饱和单体共聚，形成大单体共聚物；或将多个环醚 (a) 顺序聚合，形成大单体嵌段共聚物，或 (b) 随机聚合，形成大单体共聚醚共聚物。形成的阳离子开环大单体总是含有微量的 CE 环状低聚物。
• Terminally unsaturated macromolecular monomers of polylactones and copolymers thereof
  申请人：THE B.F. GOODRICH COMPANY

  公开号：EP0291761A2

  公开（公告）日：1988-11-23

  Preparation of a macromolecular monomer of a lactone allows the preparation of copolymers of lactones with commonly available olefinically unsaturated monomers. There is no known method for the preparation of such copolymers. A cationic ring-opening polymerization of a lactone in conjunction with an unsaturated alcohol (propa­gator) having an acryloyl, allyl or styryl double bond, produces a polylactone macromer having an ethylenic double bond at one end and a hydroxyl group at the other. The polymerization proceeds by polyaddition of the lactone to the OH group which is the propagating species. The poly­lactone may include a polymeric or non-polymeric spacer. The propagator is a primary or secondary alcohol which, if cyclic may have a single internal double bond in one ring. The catalyst is an oxonium salt, or etherate of boron trifluoride. The macromer may be copolymerized with a wide variety of olefinically unsaturated monomers to form a macromer copolymer with pendant polylactone chains. In particular, block copolymers of terminally unsaturated macromers of ether-ester, or ester-ether structure may be tailored for specific applications.

  制备内酯大分子单体可以制备内酯与常见烯烃不饱和单体的共聚物。目前还没有制备这种共聚物的已知方法。内酯与具有丙烯酰基、烯丙基或苯乙烯酰基双键的不饱和醇（促进剂）进行阳离子开环聚合，可生成一端具有乙烯基双键、另一端具有羟基的聚内酯大分子。聚合反应是通过内酯与羟基的加成反应进行的，而羟基是聚合反应的传播物质。聚内酯可包括聚合物或非聚合物间隔物。繁殖体是伯醇或仲醇，如果是环状的，在一个环上可能有一个内部双键。催化剂为三氟化硼的羰基盐或醚化物。大色母粒可与多种烯烃不饱和单体共聚，形成具有下垂聚内酯链的大色母粒共聚物。特别是，醚-酯或酯-醚结构的末端不饱和大单体的嵌段共聚物可针对特定应用进行定制。