Spiro-<5.7>-tridecanon-(7) | 4728-92-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Spiro-<5.7>-tridecanon-(7)
• 英文别名: Spiro<5.7>tridecan-7-on；Spiro[5.7]tridecan-13-one
• CAS: 4728-92-1
• 化学式: C₁₃H₂₂O
• 分子量: 194.317
• InChiKey: ZHNRIICUAKEHFL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  Spiro-<5.7>-tridecanon-(7) 在 lithium aluminium tetrahydride 作用下， 生成 Spiro<5.7>tridecan-7-ol
  参考文献：
  名称：

  Ionic reactions in the spiran series. III. Solvolysis of medium-sized-ring spiro compounds

  摘要：

  DOI：

  10.1021/jo01283a021
• 作为产物：
  描述：

  2-氧-1-环辛烷羧酸 在 sodium hydride 作用下， 生成 Spiro-<5.7>-tridecanon-(7)
  参考文献：
  名称：

  Ionic reactions in the spiran series. III. Solvolysis of medium-sized-ring spiro compounds

  摘要：

  DOI：

  10.1021/jo01283a021

文献信息

• Study of I-Strain Relief in the Intermediate When Forming Spiro Ketones from Unsymmetrical Cycloalkylidenecycloalkanes, Their Dibromides, and Their Pinacols
  作者：Richard D. Sands

  DOI：10.1021/jo00081a030

  日期：1994.1

  Three unsymmetrical intercyclic olefins, their dibromides, and their pinacols were prepared, each so the two carbons involved at the functional group were part of a different sized ring. The pinacols were reacted with 25% sulfuric acid and with boron trifluoride etherate, the dibromides with silver nitrate,and the olefins with mercuric acetate and with trifluoroperacetic acid. The predominant spiro ketone found in each product mixture was used to determine which carbon, and hence which size ring, could better undergo the sp(3) to sp(2) or the sp(2) to sp(3) transition. The findings were consistent with Brown's observations on ring strain.
• Ionic reactions in the spiran series. III. Solvolysis of medium-sized-ring spiro compounds
  作者：A. Paul Krapcho、J. Edward McCullough

  DOI：10.1021/jo01283a021

  日期：1967.8