hexyl undecylenate | 290370-66-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: hexyl undecylenate
• 英文别名: Hexyl 10-undecenoate；hexyl undec-10-enoate
• CAS: 290370-66-0
• 化学式: C₁₇H₃₂O₂
• 分子量: 268.44
• InChiKey: LIZMMPXSSWQZSY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.6
• 重原子数：
  19
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.82
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  hexyl undecylenate 在 硫氰酸铵 、 间氯过氧苯甲酸 、 1-methylimidazolium tetrafluoroborate 作用下， 以 水 为溶剂， 反应 23.0h， 生成 hexyl 10,11-epithioundecanoate
  参考文献：
  名称：

  Synthesis, Characterization, and Evaluation of 10-Undecenoic Acid-Based Epithio Derivatives as Multifunctional Additives

  摘要：

  Novel epithio compounds from alkyl epoxy undecanoates (n-alkyl, C-1, C-4, and C-6; isoalkyl, C-3, C-4, and C-8) were synthesized using an ammonium thiocyanate in ionic liquid 1-methylimidazolium tetrafluoroborate/H2O (2:1) solvent system in 8590% yields by gas chromatographic (GC) analysis. The synthesized products were characterized by H-1 and C-13 nuclear magnetic resonance spectroscopy, Fourier transform infrared spectroscopy (FTIR), gas chromatography, and GC mass spectral (GC-MS) analyses and evaluated for their antioxidant, extreme pressure (EP), and antiwear (AW) properties in three different base oils, namely, epoxy jatropha fatty acid n-butyl esters (EJB), di-2-ethylhexyl sebacate (DOS), and mineral oil (S-105). Among the synthesized products, n-butyl epithio undecanoate exhibited superior antioxidant property (229.2 degrees C) compared to butylated hydroxytoluene (BHT, 193.8 degrees C) in base oil DOS and comparable performance in EJB and S-105 base oils. All of the epithio derivatives exhibited significantly enhanced weld point for the base oils EJB and DOS at 2 wt % level and displayed moderate enhancement in S-105 base oil. Methyl epithio undecanoate at 0.6% concentration exhibited considerable improvement in the wear scar of DOS base oil. The synthesized epithio derivatives have potential as multifunctional additives in lubricant formulations.

  DOI：

  10.1021/jf5033558
• 作为产物：
  描述：

  2-十一烯酸 、 正己醇 在 硫酸 作用下， 90.0 ℃ 、20.0 kPa 条件下， 生成 hexyl undecylenate
  参考文献：
  名称：

  CN116143730

  摘要：

  公开号：

文献信息

• Electrostatic inkjet ink composition
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：US20040165050A1

  公开（公告）日：2004-08-26

  An electrostatic inkjet ink composition comprising: a non-aqueous solvent having a dielectric constant of from 1.5 to 20 and a surface tension at 25° C. of from 15 to 60 mN/m; a color material that is insoluble in the non-aqueous solvent; and a charge control agent that is soluble in the non-aqueous solvent, wherein the charge control agent contains a half-aside maleic acid copolymer containing repeating units represented by the formulae (Ia) and (Ib) as defined herein.

  一种静电喷墨油墨组合物，包括：一种具有介电常数为1.5至20和25℃下表面张力为15至60 mN/m的非水溶剂；一种在非水溶剂中不溶的色料；以及一种在非水溶剂中可溶的电荷控制剂，其中电荷控制剂包含半酰基马来酸共聚物，其包含由式(Ia)和(Ib)所定义的重复单元。
• W/O/W EMULSION COMPOSITION
  申请人：KACHI Hisanori

  公开号：US20100099646A1

  公开（公告）日：2010-04-22

  A W/O/W emulsion composition having high emulsion stability, which can be prepared extremely easily and for which the production efficiency of the W/O/W emulsion product is favorable, and a method of producing such a W/O/W emulsion composition. The W/O/W emulsion composition of the present invention includes 0.001 to 60% by mass of a component (A) described below and 0.001 to 10% by mass of a component (B) described below; wherein, a mass ratio between the component (A) and the component (B) is within a range from 1:0.01 to 1:1.4. Component (A): a sugar fatty acid ester composition obtained by esterifying a sugar and a fatty acid of 8 to 28 carbon atoms, in which a hydroxyl value of said sugar fatty acid ester composition is within a range from 20 to 220. Component (B): a nonionic surfactant having an HLB value of not less than 7.

  一种具有高乳液稳定性的W/O/W乳液组合物，可以极其容易地制备，其W/O/W乳液产品的生产效率也是有利的，以及制备这种W/O/W乳液组合物的方法。本发明的W/O/W乳液组合物包括以下组分（A）的0.001至60％质量份和以下组分（B）的0.001至10％质量份；其中，组分（A）和组分（B）之间的质量比在1:0.01至1:1.4的范围内。组分（A）：通过酯化8至28碳原子的脂肪酸和糖获得的糖脂肪酸酯组成，其中所述糖脂肪酸酯组成的羟基值在20至220的范围内。组分（B）：具有不小于7的HLB值的非离子表面活性剂。
• Process for production of stretched moldings
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0356692A2

  公开（公告）日：1990-03-07

  The present invention relates to a process for produc­ing a stretched molding which comprises stretching a straight chain random copolymer having: a repeating unit (A) represented by the formula: CH₂-CH₂ and a repeating unit (B) represented by the formula: the proportion of said repeating unit (B) being 0.01 to 10 mol%; and an intrinsic viscosity [η] as measured at 135°C in decalin of at least 5 dℓ/g. A stretched molding obtained by the present invention has mechanical properties equivalent or superior to those of the conventional super high molecular weight polyethylene stretched molding and is excellent in adhesive properties, dyeability, printability and so on, and thus is greatly useful as an industrial material required to have high strength and further good adhesive properties and printability.

  本发明涉及一种拉伸成型的生产工艺，该工艺包括拉伸直链无规共聚物，直链无规共聚物具有： 由以下式子表示的重复单元 (A) CH₂-CH₂ 和一个重复单元 (B)，其代表式为：CH₂-CH₂： 所述重复单元（B）的比例为 0.01 至 10 摩尔%；以及 在 135°C 的癸醛中测得的固有粘度[η]至少为 5 dℓ/g。 本发明得到的拉伸模塑物具有与传统超高分子量聚乙烯拉伸模塑物同等或更优越的机械性能，并且在粘合性、染色性、印刷性等方面也非常出色，因此作为要求具有高强度、进一步良好的粘合性和印刷性的工业材料非常有用。
• NATURAL PERSONAL CARE COMPOSITIONS BASED ON UNDECYLENATE ESTER
  申请人：Inolex Investment Corporation

  公开号：EP3311792A1

  公开（公告）日：2018-04-25

  A natural ester for topical application to the skin, hair, and/or nails comprising the esterification product of (1) an undecylenic acid derived from a natural source and (2) a vegetable-derived fatty alcohol, and a personal care product that contains this ester is provided. Also disclosed are methods of preparing a natural personal care composition comprising combining an ester and at least one personal care component, wherein the ester comprises the esterification product of (1) an undecylenic acid derived from a natural source and (2) a vegetable-derived fatty alcohol.

  本发明提供了一种用于皮肤、头发和/或指甲局部涂抹的天然酯类，该酯类包括(1)源自天然来源的十一碳烯酸和(2)源自植物的脂肪醇的酯化产物，以及一种含有该酯类的个人护理产品。还公开了制备天然个人护理组合物的方法，该组合物包括酯和至少一种个人护理成分，其中酯包括(1)源自天然来源的十一碳烯酸和(2)源自植物的脂肪醇的酯化产物。
• ESTERS DERIVED FROM NATURAL SOURCES HAVING LOWER VISCOSITY AND HIGHER SPREAD RATE, NATURAL PERSONAL CARE COMPOSITIONS, AND RELATED METHODS
  申请人：Inolex Investment Corporation

  公开号：EP3797758A1

  公开（公告）日：2021-03-31

  A natural ester for topical application to the skin, hair, and/or nails comprising the esterification product of (1) an undecylenic acid derived from a natural source and (2) a vegetable-derived fatty alcohol, and a personal care product that contains this ester is provided. Also disclosed are methods of preparing a natural personal care composition comprising combining an ester and at least one personal care component, wherein the ester comprises the esterification product of (1) an undecylenic acid derived from a natural source and (2) a vegetable-derived fatty alcohol.

  本发明提供了一种用于皮肤、头发和/或指甲局部涂抹的天然酯类，该酯类包括(1)源自天然来源的十一碳烯酸和(2)源自植物的脂肪醇的酯化产物，以及一种含有该酯类的个人护理产品。还公开了制备天然个人护理组合物的方法，该组合物包括酯和至少一种个人护理成分，其中酯包括(1)源自天然来源的十一碳烯酸和(2)源自植物的脂肪醇的酯化产物。