4-(Chloromethyl)-2-cyclopropyl-2-methyl-1,3-dioxolane | 887400-76-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 4-(Chloromethyl)-2-cyclopropyl-2-methyl-1,3-dioxolane
• CAS: 887400-76-2
• 化学式: C₈H₁₃ClO₂
• 分子量: 176.643
• InChiKey: UGAQJABCGAMKCV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  4-(Chloromethyl)-2-cyclopropyl-2-methyl-1,3-dioxolane 、 丙烯酸钾 在 三乙胺 作用下， 反应 3.0h， 生成
  参考文献：
  名称：

  Copolymerization of cyclopropyl-substituted dioxolanylmethyl acrylates with styrene and synthesis of photosensitive copolymers

  摘要：

  Radical copolymerization of new monomers, cyclopropyl-substituted dioxolanylmethyl acrylates, with styrene in benzene solution was studied at low conversions. The copolymer compositions and the relative activity constants and Alfrey-Price constants of cyclopropane-containing dioxolanylmethyl acrylates were determined. The sensitivity of the copolymers obtained to UV radiation was studied, and the possibility of using them as photoresists was revealed.

  DOI：

  10.1134/s1070427210030201

文献信息

• Copolymerization of cyclopropyl-substituted dioxolanylmethyl acrylates with styrene and synthesis of photosensitive copolymers
  作者：G. A. Ramazanov、R. Z. Shakhnazarli、A. M. Guliev

  DOI：10.1134/s1070427210030201

  日期：2010.3

  Radical copolymerization of new monomers, cyclopropyl-substituted dioxolanylmethyl acrylates, with styrene in benzene solution was studied at low conversions. The copolymer compositions and the relative activity constants and Alfrey-Price constants of cyclopropane-containing dioxolanylmethyl acrylates were determined. The sensitivity of the copolymers obtained to UV radiation was studied, and the possibility of using them as photoresists was revealed.