| 184709-03-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• CAS: 184709-03-3
• 化学式: C₇₄H₂₂N₂O₃
• 分子量: 987.0
• InChiKey: YJPGSFIOKIJHGL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  15.6
• 重原子数：
  79
• 可旋转键数：
  10
• 环数：
  34.0
• sp3杂化的碳原子比例：
  0.15
• 拓扑面积：
  43.8
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  、 以 氯仿 为溶剂， 以99%的产率得到
  参考文献：
  名称：

  Synthesis, electrochemistry, Langmuir–Blodgett deposition and photophysics of metal-coordinated fullerene–porphyrin dyads

  摘要：

  A novel fullerene-Ru-porphyrin conjugate (3b) for Langmuir-Blodgett (LB) film deposition has been synthesized. The side polar chain that characterizes the complex is necessary to introduce enough amphiphilicity in these otherwise non-polar moieties. The complex can be deposited on solid substrates via the LB technique and the films obtained show charge separation upon light irradiation. In addition, a careful cyclic voltammetry study of the complex is reported. (C) 2000 Elsevier Science S.A, All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00754-8
• 作为产物：
  描述：

  4-吡啶甲醛 、 足球烯 、 N-(3,6,9-Trioxadecyl)glycine 生成
  参考文献：
  名称：

  Novel Functional Fullerene Materials: Fullerenes as Energy Acceptors

  摘要：

  Fullerene derivatives exhibit absorption throughout the UV/Vis region up to 750 nm. This feature is important for easy excitation. Once excited, fullerenes may become both electron and energy accepters. The distinction between these two pathways depends strongly on the partner involved (donor) and on the conditions employed (solvent, etc.).

  DOI：

  10.1007/s007060170145

文献信息

• Easy Access to Water-Soluble Fullerene Derivatives via 1,3-Dipolar Cycloadditions of Azomethine Ylides to C₆₀
  作者：Tatiana Da Ros、Maurizio Prato、Fabiola Novello、Michele Maggini、Elena Banfi

  DOI：10.1021/jo961522t

  日期：1996.1.1
• Novel Functional Fullerene Materials: Fullerenes as Energy Acceptors
  作者：Konstantinos Kordatos、Tatiana Da Ros、Maurizio Prato、Chuping Luo、Dirk Guldi

  DOI：10.1007/s007060170145

  日期：2001.1.30

  Fullerene derivatives exhibit absorption throughout the UV/Vis region up to 750 nm. This feature is important for easy excitation. Once excited, fullerenes may become both electron and energy accepters. The distinction between these two pathways depends strongly on the partner involved (donor) and on the conditions employed (solvent, etc.).
• Synthesis, electrochemistry, Langmuir–Blodgett deposition and photophysics of metal-coordinated fullerene–porphyrin dyads
  作者：Tatiana Da Ros、Maurizio Prato*、Maurizio Carano、Paola Ceroni、Francesco Paolucci*、Sergio Roffia、Lodovico Valli*、DirkM Guldi*

  DOI：10.1016/s0022-328x(99)00754-8

  日期：2000.4

  A novel fullerene-Ru-porphyrin conjugate (3b) for Langmuir-Blodgett (LB) film deposition has been synthesized. The side polar chain that characterizes the complex is necessary to introduce enough amphiphilicity in these otherwise non-polar moieties. The complex can be deposited on solid substrates via the LB technique and the films obtained show charge separation upon light irradiation. In addition, a careful cyclic voltammetry study of the complex is reported. (C) 2000 Elsevier Science S.A, All rights reserved.