3-methyl-5-thiahexan-2-ol | 79190-70-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3-methyl-5-thiahexan-2-ol
• 英文别名: 3-Methyl-4-(methylsulfanyl)butan-2-ol；3-methyl-4-methylsulfanylbutan-2-ol
• CAS: 79190-70-8
• 化学式: C₆H₁₄OS
• 分子量: 134.243
• InChiKey: KIHMBHOENAOANZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  8
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  45.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  3-methyl-5-thiahexan-2-one 在 sodium tetrahydroborate 作用下， 以 乙醇 为溶剂， 以82%的产率得到3-methyl-5-thiahexan-2-ol
  参考文献：
  名称：

  Synthesis of γ-ketosulfide derivatives from natural mercaptans

  摘要：

  gamma-Ketosulfides and their derivatives gamma-hydroxysulfides, sulfoxides, sulfur-containing 1,3-dioxolanes, and alkylthiooximes were obtained on the basis of natural mercaptans. It was found that gamma-hydroxy- and dihydroxysulfoxides are more stable than the corresponding gamma-keto and diketosufoxides.

  DOI：

  10.1134/s0965544106020101

文献信息

• Synthesis of γ-ketosulfide derivatives from natural mercaptans
  作者：A. D. Ulendeeva、L. A. Baeva、O. R. Valiullin、T. S. Nikitina、D. D. Arslanova、L. V. Spirikhin、N. K. Lyapina

  DOI：10.1134/s0965544106020101

  日期：2006.3

  gamma-Ketosulfides and their derivatives gamma-hydroxysulfides, sulfoxides, sulfur-containing 1,3-dioxolanes, and alkylthiooximes were obtained on the basis of natural mercaptans. It was found that gamma-hydroxy- and dihydroxysulfoxides are more stable than the corresponding gamma-keto and diketosufoxides.