2-(2-Methylprop-2-enoyloxy)ethyl 2-methyl-2-[2-methyl-1-[2-(2-methylprop-2-enoyloxy)ethoxy]-1-oxopropan-2-yl]sulfanylcarbothioylsulfanylpropanoate | 1221504-58-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 2-(2-Methylprop-2-enoyloxy)ethyl 2-methyl-2-[2-methyl-1-[2-(2-methylprop-2-enoyloxy)ethoxy]-1-oxopropan-2-yl]sulfanylcarbothioylsulfanylpropanoate
• 英文别名: 2-(2-methylprop-2-enoyloxy)ethyl 2-methyl-2-[2-methyl-1-[2-(2-methylprop-2-enoyloxy)ethoxy]-1-oxopropan-2-yl]sulfanylcarbothioylsulfanylpropanoate
• CAS: 1221504-58-0
• 化学式: C₂₁H₃₀O₈S₃
• 分子量: 506.662
• InChiKey: CESZAWFOBMVPHE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  32
• 可旋转键数：
  18
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  188
• 氢给体数：
  0
• 氢受体数：
  11

反应信息

• 作为产物：
  描述：

  2,2'-[硫代羰酰双(硫)]双[2-甲基丙酸] 、 甲基丙烯酸羟乙酯 在 三苯基膦 、 偶氮二甲酸二乙酯 作用下， 以 四氢呋喃 为溶剂， 以56%的产率得到2-(2-Methylprop-2-enoyloxy)ethyl 2-methyl-2-[2-methyl-1-[2-(2-methylprop-2-enoyloxy)ethoxy]-1-oxopropan-2-yl]sulfanylcarbothioylsulfanylpropanoate
  参考文献：
  名称：

  SYNTHESIS OF TRITHIOCARBONATES AND ALLYL SULFIDES AND THEIR APPLICATION INTO ADVANCES IN COVALENT ADAPTABLE NETWORKS

  摘要：

  揭示了具有C-B-A-B-C结构的单体，其中A是三硫代碳酸酯和烯丙基硫化物的核心，B是连接单元，C是末端单元。末端单元可能包括丙烯酸酯、甲基丙烯酸酯、醇、胺和炔等。连接单元可能包括烷烃、烯烃、苯、二苯基或苄基等。还揭示了合成这种化合物的方法。

  公开号：

  US20140303391A1

文献信息

• Responsive Gels Based on a Dynamic Covalent Trithiocarbonate Cross-Linker
  作者：Renaud Nicolaÿ、Jun Kamada、Abigail Van Wassen、Krzysztof Matyjaszewski

  DOI：10.1021/ma100378r

  日期：2010.5.11

  Dimethacrylate trithiocarbonate was synthesized and used as a dynamic covalent cross-linker to prepare PMMA and PSt gels via radical polymerization. The swelling properties of the PMMA gels were studied and showed that in the presence of radicals the gels reorganize to accommodate forces generated by the swelling processes. This reshuffling of the cross-link network yields an increase in the swelling ratio (up to 300% increase) of the PMMA gels. Two different radical generators, a thermal initiator and a Cu-1/L complex, were successfully used to trigger the reorganization of the gels. To illustrate the broad utility of the procedure, three discrete pieces of gels were fused into one single piece to demonstrate that dynamic covalent cross-linkers can be used to prepare materials that can be reprocessed and/or undergo self-repair.
• POLYMER ELECTROLYTE AND MANUFACTURING METHOD THEREFOR
  申请人：LG CHEM, LTD.

  公开号：US20210028488A1

  公开（公告）日：2021-01-28

  A polymer electrolyte and a method for manufacturing the same are disclosed. More specifically, a polymer electrolyte membrane having excellent ionic conductivity and low crosslinking degree can be prepared using a crosslinkable reversible addition fragmentation chain transfer polymerization agent (RAFT agent).
• US9193682B2
  申请人：——

  公开号：US9193682B2

  公开（公告）日：2015-11-24