9-(2-fluorophenyl)anthracene | 737-24-6

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物 - 芳基萘木脂素
• 英文名称: 9-(2-fluorophenyl)anthracene
• 英文别名: 9-<2-Fluor-phenyl>-anthracen；9-(2-Fluor-phenyl)-anthracen
• CAS: 737-24-6
• 化学式: C₂₀H₁₃F
• 分子量: 272.322
• InChiKey: JAZSKWGLHUQQEB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  21
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  9-(2-fluorophenyl)anthracene 在 dimethyldimesitylsilane 作用下， 以 氯苯 为溶剂， 反应 8.0h， 以51%的产率得到苯并(A)荧蒽
  参考文献：
  名称：

  氟芳烃的质子催化、硅烷驱动的 Friedel-Crafts 偶联

  摘要：

  在Friedel-Crafts 中加入F Friedel-Crafts 类反应是有机化学中最古老和应用最广泛的反应之一，它在芳环和各种非芳族取代基（如烷基）之间形成碳-碳键。通常，金属络合物用于活化这些取代基的氯化或溴化前体，但通过使用基于硅的试剂来活化氟化前体，Allemann 等人。(p. 574) 将反应扩展到两个不同芳香位点的偶联，从而有效地形成复杂的多环结构。该方法依赖于硅-氟键的异常强度作为驱动力。硅-氟键的形成扩大了可用于形成碳-碳键的反应的化合物范围。古老的 Friedel-Crafts 反应通过通常由路易斯酸生成的烷基或酰基阳离子等价物将烷基或酰基附加到芳环上。我们表明，由其他不反应的芳基氟化物产生的苯基阳离子等价物允许将 Friedel-Crafts 反应扩展到分子内芳基偶联。该反应的启动特征是碳-氟交换为硅-氟键焓；该反应由中间体甲硅烷基阳离子激活。催化量的质子或甲硅

  DOI：

  10.1126/science.1202432
• 作为产物：
  描述：

  2'-Fluor-2-benzyl-benzophenon 在 氢溴酸 、 溶剂黄146 作用下， 生成 9-(2-fluorophenyl)anthracene
  参考文献：
  名称：

  The Synthesis and Cyclization of Some 2'-Substituted 2-Benzylbenzophenones^1,2

  摘要：

  DOI：

  10.1021/jo01082a005

文献信息

• Chromium- and Cobalt-Catalyzed, Regiocontrolled Hydrogenation of Polycyclic Aromatic Hydrocarbons: A Combined Experimental and Theoretical Study
  作者：Bo Han、Pengchen Ma、Xuefeng Cong、Hui Chen、Xiaoming Zeng

  DOI：10.1021/jacs.9b03328

  日期：2019.6.5

  Polycyclic aromatic hydrocarbons are difficult substrates for hydrogenation because of the thermodynamic stability caused by aromaticity. We report here the first chromium- and cobalt-catalyzed, regiocontrolled hydrogenation of polycyclic aromatic hydrocarbons at ambient temperature. These reactions were promoted by low-cost chromium or cobalt salts combined with diimino/carbene ligand and methylmagnesium

  由于芳香性引起的热力学稳定性，多环芳烃是难以加氢的底物。我们在这里报告了在环境温度下多环芳烃的第一个铬和钴催化的区域控制加氢。这些反应由低成本的铬或钴盐与二亚氨基/卡宾配体和甲基溴化镁结合促进，具有高区域选择性和扩大的底物范围，包括并四苯、四苯、并五苯和苝，它们很少被还原。该方法提供了一种具有成本效益的氢化催化方案，具有可扩展性，可用于通过氢化产物的功能化合成四溴和羧基取代的基序。
• Polymeric organic nanoparticles with enhanced emission
  申请人：Sony Corporation

  公开号：US11230663B2

  公开（公告）日：2022-01-25

  The present disclosure relates to luminescent including photon up-conversion nanoparticles. These nanoparticles include a polymeric organic matrix, at least one light emitter distributed within this matrix, a stabilizing agent, and at least one metal particle enclosed within the matrix, wherein the metal particles are plasmonic nanoparticles. The present disclosure further relates to methods of manufacture and to uses of such nanoparticles.

  本公开涉及包括光子上转换在内的发光纳米粒子。这些纳米粒子包括聚合物有机基体、分布在该基体中的至少一种发光体、稳定剂以及封闭在该基体中的至少一种金属粒子，其中金属粒子是等离子体纳米粒子。本公开进一步涉及此类纳米粒子的制造方法和用途。
• POLYMERIC ORGANIC NANOPARTICLES WITH ENHANCED EMISSION
  申请人：Sony Corporation

  公开号：US20190085237A1

  公开（公告）日：2019-03-21

  The present disclosure relates to luminescent including photon up-conversion nanoparticles. These nanoparticles dude a polymeric organic matrix, at least one light emitter distributed within this matrix, a stabilizing agent, and at least one metal particle enclosed within the matrix, wherein the metal particles are plasmonic nanoparticles. The present disclosure further relates to methods of manufacture and to uses of such nanoparticles.
• SENSOR FOR THE DETECTION OF BIOMOLECULES
  申请人：Sony Corporation

  公开号：US20200166502A1

  公开（公告）日：2020-05-28

  The present disclosure relates to a sensor for the detection of analytes, in particular for the detection of biomolecules. The sensor includes a (bio)compatible sensing layer including a polymer matrix or gel matrix, particularly a polymer gel matrix, organic nanoparticles and, optionally, one or several cell adhesion layer(s). The cell adhesion layer(s) can be varied depending on the type of cells. In the presence of the analytes, the organic nanoparticles are capable of photon up-conversion emission. The sensor further optionally includes plasmonic metal nanoparticles. The present disclosure further relates to methods of producing such a sensor and to uses of such a sensor.
• [EN] POLYMERIC ORGANIC NANOPARTICLES WITH ENHANCED EMISSION<br/>[FR] NANOPARTICULES ORGANIQUES POLYMÈRES À ÉMISSION AMÉLIORÉE
  申请人：SONY CORP

  公开号：WO2017167631A1

  公开（公告）日：2017-10-05

  The present disclosure relates to luminescent including photon up-conversion nanoparticles. These nanoparticles include a polymeric organic matrix, at least one light emitter distributed within this matrix, a stabilizing agent, and at least one metal particle enclosed within the matrix, wherein the metal particles are plasmonic nanoparticles. The present disclosure further relates to methods of manufacture and to uses of such nanoparticles.