(3R,4R,5S,6R)-5-[(2R,3R,4R,5S,6R)-3,4-Dihydroxy-5-((1S,2R,4R,5R,6S)-5-hydroxy-4-hydroxymethyl-3,7-dioxa-bicyclo[4.1.0]hept-2-yloxy)-6-hydroxymethyl-tetrahydro-pyran-2-yloxy]-6-hydroxymethyl-tetrahydro-pyran-2,3,4-triol

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (3R,4R,5S,6R)-5-[(2R,3R,4R,5S,6R)-3,4-Dihydroxy-5-((1S,2R,4R,5R,6S)-5-hydroxy-4-hydroxymethyl-3,7-dioxa-bicyclo[4.1.0]hept-2-yloxy)-6-hydroxymethyl-tetrahydro-pyran-2-yloxy]-6-hydroxymethyl-tetrahydro-pyran-2,3,4-triol
• 英文别名: (3R,4R,5S,6R)-5-[(2R,3R,4R,5S,6R)-3,4-dihydroxy-5-[[(1S,2R,4R,5R,6S)-5-hydroxy-4-(hydroxymethyl)-3,7-dioxabicyclo[4.1.0]heptan-2-yl]oxy]-6-(hydroxymethyl)oxan-2-yl]oxy-6-(hydroxymethyl)oxane-2,3,4-triol
• 化学式: C₁₈H₃₀O₁₅
• 分子量: 486.427
• InChiKey: XTFTTYOWNRJHOC-QGGWIHCJSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -5.9
• 重原子数：
  33
• 可旋转键数：
  7
• 环数：
  4.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  241
• 氢给体数：
  9
• 氢受体数：
  15

反应信息

• 作为产物：
  描述：

  2"-O-(p-tosyl)maltotriose 在 sodium hydroxide 作用下， 反应 3.0h， 以86.5%的产率得到(3R,4R,5S,6R)-5-[(2R,3R,4R,5S,6R)-3,4-Dihydroxy-5-((1S,2R,4R,5R,6S)-5-hydroxy-4-hydroxymethyl-3,7-dioxa-bicyclo[4.1.0]hept-2-yloxy)-6-hydroxymethyl-tetrahydro-pyran-2-yloxy]-6-hydroxymethyl-tetrahydro-pyran-2,3,4-triol
  参考文献：
  名称：

  Synthesis of specifically modified maltooligosaccharides by enzymic degradation of cyclodextrin derivatives. Substrate-based investigation of the active site of Taka-amylase

  摘要：

  DOI：

  10.1021/jo00380a026