(+/-)-10ac-chloro-9.10-dioxo-2.3-dimethyl-(4arH)-1.4.4a.9.10.10a-hexahydro-phenanthrene | 21715-73-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: (+/-)-10ac-chloro-9.10-dioxo-2.3-dimethyl-(4arH)-1.4.4a.9.10.10a-hexahydro-phenanthrene
• 英文别名: (+/-)-10ac-Chlor-9.10-dioxo-2.3-dimethyl-(4arH)-1.4.4a.9.10.10a-hexahydro-phenanthren；(4aS,10aR)-10a-chloro-2,3-dimethyl-4,4a-dihydro-1H-phenanthrene-9,10-dione
• CAS: 21715-73-1
• 化学式: C₁₆H₁₅ClO₂
• 分子量: 274.747
• InChiKey: MBKAPLWDLNFMIA-XJKSGUPXSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.64
• 重原子数：
  19.0
• 可旋转键数：
  0.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  34.14
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  (+/-)-10ac-chloro-9.10-dioxo-2.3-dimethyl-(4arH)-1.4.4a.9.10.10a-hexahydro-phenanthrene 在 乙醇 、 sodium acetate 作用下， 生成 2,3-dimethyl-phenanthrene-9,10-dione
  参考文献：
  名称：

  Mentally disordered parricide and stranger killers admitted to high-security care. 1: A descriptive comparison

  摘要：

  Parricide is an uncommon crime, so that many of the descriptive studies suffer from methodological shortcomings of small sample sizes and a non-representative ascertainment. We describe a consecutive series of mentally disordered offenders convicted of parricide who were admitted to high-security care and we compare their index characteristics with a group convicted of killing one or more strangers. The main findings were that the parricides were more likely to suffer from schizophrenia but less likely to have had a disrupted childhood and criminal history, as compared with those who had killed a stranger. Those in the parricide group had made a previous attack on their victim in 40% of cases. Overall, the study confirmed some of the differences that one might expect between these two groups of homicides, which had entirely different relationships to their victims.

  DOI：

  10.1080/09585180122057
• 作为产物：
  描述：

  3-氯萘-1,2-二酮 、 2,3-二甲基-1,3-丁二烯 在 氯仿 作用下， 生成 (+/-)-10ac-chloro-9.10-dioxo-2.3-dimethyl-(4arH)-1.4.4a.9.10.10a-hexahydro-phenanthrene
  参考文献：
  名称：

  Mentally disordered parricide and stranger killers admitted to high-security care. 1: A descriptive comparison

  摘要：

  Parricide is an uncommon crime, so that many of the descriptive studies suffer from methodological shortcomings of small sample sizes and a non-representative ascertainment. We describe a consecutive series of mentally disordered offenders convicted of parricide who were admitted to high-security care and we compare their index characteristics with a group convicted of killing one or more strangers. The main findings were that the parricides were more likely to suffer from schizophrenia but less likely to have had a disrupted childhood and criminal history, as compared with those who had killed a stranger. Those in the parricide group had made a previous attack on their victim in 40% of cases. Overall, the study confirmed some of the differences that one might expect between these two groups of homicides, which had entirely different relationships to their victims.

  DOI：

  10.1080/09585180122057

文献信息

• Mentally disordered parricide and stranger killers admitted to high-security care. 1: A descriptive comparison
  作者：Helen Baxter、Conor Duggan、Emmet Larkin、Christopher Cordess、Kim Page

  DOI：10.1080/09585180122057

  日期：2001.1

  Parricide is an uncommon crime, so that many of the descriptive studies suffer from methodological shortcomings of small sample sizes and a non-representative ascertainment. We describe a consecutive series of mentally disordered offenders convicted of parricide who were admitted to high-security care and we compare their index characteristics with a group convicted of killing one or more strangers. The main findings were that the parricides were more likely to suffer from schizophrenia but less likely to have had a disrupted childhood and criminal history, as compared with those who had killed a stranger. Those in the parricide group had made a previous attack on their victim in 40% of cases. Overall, the study confirmed some of the differences that one might expect between these two groups of homicides, which had entirely different relationships to their victims.