2,3-dimethyl-phenanthrene-9,10-dione | 25282-86-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 2,3-dimethyl-phenanthrene-9,10-dione
• 英文别名: 2,3-Dimethyl-phenanthren-9,10-dion；2,3-Dimethyl-phenanthrenchinon-(9,10)；2,3-Dimethyl-9,10-phenanthren-chinon；2,3-Dimethylphenanthren-9,10-chinon；2,3-Dimethylphenanthrene-9,10-dione
• CAS: 25282-86-4
• 化学式: C₁₆H₁₂O₂
• 分子量: 236.27
• InChiKey: DSJFEUJXVBYMHL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  18
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2,3-dimethyl-phenanthrene-9,10-dione 、 邻苯二胺 生成 2,3-dimethyl-dibenzo[a,c]phenazine
  参考文献：
  名称：

  The Synthesis of Phenanthrene and Hydrophenanthrene Derivatives. II. The Hydrocarbon Synthesis¹

  摘要：

  DOI：

  10.1021/ja01314a047
• 作为产物：
  描述：

  3-氯萘-1,2-二酮 在 乙醇 、 氯仿 、 sodium acetate 作用下， 生成 2,3-dimethyl-phenanthrene-9,10-dione
  参考文献：
  名称：

  Mentally disordered parricide and stranger killers admitted to high-security care. 1: A descriptive comparison

  摘要：

  Parricide is an uncommon crime, so that many of the descriptive studies suffer from methodological shortcomings of small sample sizes and a non-representative ascertainment. We describe a consecutive series of mentally disordered offenders convicted of parricide who were admitted to high-security care and we compare their index characteristics with a group convicted of killing one or more strangers. The main findings were that the parricides were more likely to suffer from schizophrenia but less likely to have had a disrupted childhood and criminal history, as compared with those who had killed a stranger. Those in the parricide group had made a previous attack on their victim in 40% of cases. Overall, the study confirmed some of the differences that one might expect between these two groups of homicides, which had entirely different relationships to their victims.

  DOI：

  10.1080/09585180122057

文献信息

• The reactions of some ortho-naphthoquinones with 2,3-dimethylbutadiene
  作者：M. F. Ansell、R. A. Murray

  DOI：10.1039/j39710001429

  日期：——

  The reactions of dimethylbutadiene with 1,2-naphthoquinones are shown to involve either addition to the 3,4-double bond [substituents 3-chloro-, 4-cyano-, 3-methoxycarbonyl, 3-nitro-, and 3-methoxy-(partially)] or to the 2-carbonyl group [substituents 4-chloro-, 4-bromo-, 3,4-dichloro-, 3-methoxy-(partially)]. The adduct from 3-chloro-1,2-naphthoquinone is shown to eliminate hydrogen chloride to yield

  已显示二甲基丁二烯与1,2-萘醌的反应涉及3,4-双键的任何一种加成[取代基3-氯-，4-氰基-，3-甲氧羰基，3-硝基和3-甲氧基- （部分）]或2-羰基[取代基4-氯-，4-溴-，3,4-二氯-，3-甲氧基-（部分）]。显示了3-氯-1,2-萘醌的加合物消除了氯化氢，生成了菲-9,10-二醇，然后进行了酸催化的二甲基丁二烯加成，生成了羟基菲咯酮。
• 106. Synthesis of alkylphenanthrenes. Part VI. Attempts to synthesise the hydrocarbon “C₁₆H₁₄'” derived from strophanthidin
  作者：Robert Downs Haworth、Cecil Robert Mavin、George Sheldrick

  DOI：10.1039/jr9340000454

  日期：——
• Mentally disordered parricide and stranger killers admitted to high-security care. 1: A descriptive comparison
  作者：Helen Baxter、Conor Duggan、Emmet Larkin、Christopher Cordess、Kim Page

  DOI：10.1080/09585180122057

  日期：2001.1

  Parricide is an uncommon crime, so that many of the descriptive studies suffer from methodological shortcomings of small sample sizes and a non-representative ascertainment. We describe a consecutive series of mentally disordered offenders convicted of parricide who were admitted to high-security care and we compare their index characteristics with a group convicted of killing one or more strangers. The main findings were that the parricides were more likely to suffer from schizophrenia but less likely to have had a disrupted childhood and criminal history, as compared with those who had killed a stranger. Those in the parricide group had made a previous attack on their victim in 40% of cases. Overall, the study confirmed some of the differences that one might expect between these two groups of homicides, which had entirely different relationships to their victims.
• The Synthesis of Phenanthrene and Hydrophenanthrene Derivatives. II. The Hydrocarbon Synthesis¹
  作者：Louis F. Fieser、Emanuel B. Hershberg

  DOI：10.1021/ja01314a047

  日期：1935.11