1-mercapto-13-hydroxy-5,8,11-trioxatridecane | 1098124-10-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-mercapto-13-hydroxy-5,8,11-trioxatridecane
• 英文别名: tri(ethylene glycol)-1-butanethiol；EGC4SH；2-[2-[2-(4-Sulfanylbutoxy)ethoxy]ethoxy]ethanol；2-[2-[2-(4-sulfanylbutoxy)ethoxy]ethoxy]ethanol
• CAS: 1098124-10-7
• 化学式: C₁₀H₂₂O₄S
• 分子量: 238.348
• InChiKey: ZSGOKBPRCOZZCB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.2
• 重原子数：
  15
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  48.9
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  tri(ethylene glycol)-1-butanethioacetate 在 盐酸 作用下， 以 甲醇 为溶剂， 反应 5.0h， 以91.5%的产率得到1-mercapto-13-hydroxy-5,8,11-trioxatridecane
  参考文献：
  名称：

  Supramolecular gold nanoparticle–polymer composites formed in water with cucurbit[8]uril

  摘要：

  利用葫芦[8]脲作为超分子 "手铐"，在水中制备了一种金纳米粒子与聚合物的复合材料，将病毒官能化的金纳米粒子和萘酚官能化的丙烯酰胺共聚物固定在一起。

  DOI：

  10.1039/c0cc03250f

文献信息

• Recognition of lectin with a high signal to noise ratio: carbohydrate-tri(ethylene glycol)-alkanethiol co-adsorbed monolayer
  作者：Yukari Sato、Kyoko Yoshioka、Mutsuo Tanaka、Teiichi Murakami、Miho Neide Ishida、Osamu Niwa

  DOI：10.1039/b809481k

  日期：——

  Densely packed co-adsorbed ultrathin mono molecular layers of short tri(ethylene glycol)-alkanethiolate (for repelling proteins) and maltoside terminated alkanethiolate (for capturing lectin) provided an extremely high signal to noise ratio surface: the repelling molecules, which had two different functions (highly flexible-hydrophilic arm and rigid packing tail group), worked as “nano barriers” in the recognition monolayer.

  密集排列的双吸附超薄单分子层，由短的三乙二醇硫醇（排斥蛋白质）和麦芽糖终止的硫醇（捕获凝集素）组成，提供了极高的信噪比表面。排斥分子具有两种不同功能（高度柔性的亲水臂和刚性的排列尾部基团），在识别单层中充当“纳米屏障”。
• SUPRAMOLECULAR CAPSULES
  申请人：Scherman Oren Alexander

  公开号：US20140170214A1

  公开（公告）日：2014-06-19

  Provided is a capsule having a shell of material that is a supramolecular cross-linked network. The network is formed from a host-guest complexation of cucurbituril (the host) and one or more building blocks comprising suitable guest functionality. The complex non-covalently crosslinks the building block and/or non-covalently links the building block to another building block thereby forming the supramolecular cross-linked network. The capsules are obtained or obtainable by the complexation of a composition comprising cucurbituril and one or more building blocks having suitable cucurbituril guest functionality thereby to form a supramolecular cross-linked network.
• US9439868B2
  申请人：——

  公开号：US9439868B2

  公开（公告）日：2016-09-13
• Supramolecular gold nanoparticle–polymer composites formed in water with cucurbit[8]uril
  作者：Roger J. Coulston、Samuel T. Jones、Tung-Chun Lee、Eric A. Appel、Oren A. Scherman

  DOI：10.1039/c0cc03250f

  日期：——

  A gold nanoparticle–polymer composite material has been prepared in water using cucurbit[8]uril as a supramolecular “handcuff” to hold together viologen-functionalised gold nanoparticles and a naphthol-functionalised acrylamide copolymer.

  利用葫芦[8]脲作为超分子 "手铐"，在水中制备了一种金纳米粒子与聚合物的复合材料，将病毒官能化的金纳米粒子和萘酚官能化的丙烯酰胺共聚物固定在一起。