1,3-dihydro-1,3-bis(p-tert-butylphenyl)naphtho[2,3-c]-furan-1-ol | 894808-82-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 萘并呋喃类
• 英文名称: 1,3-dihydro-1,3-bis(p-tert-butylphenyl)naphtho[2,3-c]-furan-1-ol
• 英文别名: 1,3-bis(4-tert-butylphenyl)-1H-benzo[f][2]benzofuran-3-ol
• CAS: 894808-82-3
• 化学式: C₃₂H₃₄O₂
• 分子量: 450.621
• InChiKey: VIXLAJRUHRUNMB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.4
• 重原子数：
  34
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,3-dihydro-1,3-bis(p-tert-butylphenyl)naphtho[2,3-c]-furan-1-ol 在 溶剂黄146 作用下， 生成 1,3-Bis-(4-tert-butyl-phenyl)-naphtho[2,3-c]furan
  参考文献：
  名称：

  Synthesis and Photophysical Properties of Dihydroheptacenes:  New Blue-Emitting Materials

  摘要：

  7,16-Dihydroheptacenes (1-3) substituted at the 6, 8, 15, and 17 positions are synthesized as blue emitters potentially useful in organic light emitting diodes (OLEDs). The photophysical properties of 1 - 3 ( lambda(max) = 424- 428 nm, Phi(F) = 0.15- 0.21, tau(F) = 2.35 - 2.67 ns in CH2Cl2) are discussed. They are shown to be stable and efficient blue emitters in the solid state (Phi(F) = 0.37 - 0.44). The X-ray crystal structure of 1 is reported.

  DOI：

  10.1021/jo0601314
• 作为产物：
  描述：

  2,3-萘二羧酸 在 sodium hydroxide 、 sodium tetrahydroborate 、 三氯化铝 作用下， 以 四氢呋喃 、 乙醚 、 水 为溶剂， 反应 70.0h， 生成 1,3-dihydro-1,3-bis(p-tert-butylphenyl)naphtho[2,3-c]-furan-1-ol
  参考文献：
  名称：

  Synthesis and Photophysical Properties of Dihydroheptacenes:  New Blue-Emitting Materials

  摘要：

  7,16-Dihydroheptacenes (1-3) substituted at the 6, 8, 15, and 17 positions are synthesized as blue emitters potentially useful in organic light emitting diodes (OLEDs). The photophysical properties of 1 - 3 ( lambda(max) = 424- 428 nm, Phi(F) = 0.15- 0.21, tau(F) = 2.35 - 2.67 ns in CH2Cl2) are discussed. They are shown to be stable and efficient blue emitters in the solid state (Phi(F) = 0.37 - 0.44). The X-ray crystal structure of 1 is reported.

  DOI：

  10.1021/jo0601314

文献信息

• Synthesis and Photophysical Properties of Dihydroheptacenes:  New Blue-Emitting Materials
  作者：Rajib Mondal、Bipin K. Shah、Douglas C. Neckers

  DOI：10.1021/jo0601314

  日期：2006.5.1

  7,16-Dihydroheptacenes (1-3) substituted at the 6, 8, 15, and 17 positions are synthesized as blue emitters potentially useful in organic light emitting diodes (OLEDs). The photophysical properties of 1 - 3 ( lambda(max) = 424- 428 nm, Phi(F) = 0.15- 0.21, tau(F) = 2.35 - 2.67 ns in CH2Cl2) are discussed. They are shown to be stable and efficient blue emitters in the solid state (Phi(F) = 0.37 - 0.44). The X-ray crystal structure of 1 is reported.