2,9-dimethyl-9H-pyrido[2,3-b]indole | 51916-80-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 2,9-dimethyl-9H-pyrido[2,3-b]indole
• 英文别名: 2,9-Dimethyl-9H-pyrido[2,3-b]indol；2,9-Dimethylpyrido[2,3-b]indole
• CAS: 51916-80-4
• 化学式: C₁₃H₁₂N₂
• mdl: MFCD18803934
• 分子量: 196.252
• InChiKey: GMHFAIHIDCYXRY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  15
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.153
• 拓扑面积：
  17.8
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2,9-Dimethyl-4,9-dihydro-3H-pyrido[2,3-b]indole 在 四氯苯醌 作用下， 以 二氯甲烷 为溶剂， 生成 2,9-dimethyl-9H-pyrido[2,3-b]indole
  参考文献：
  名称：

  铜催化β-(3-吲哚基)酮O-五氟苯甲酰肟自由基环化合成α-咔啉

  摘要：

  通过在 1,2-二氯乙烷中用催化量的铜粉处理 β-(3-吲哚基) 酮 O-五氟苯甲酰肟的自由基环化反应生成 3,4-二氢-α-咔啉，...

  DOI：

  10.1246/bcsj.78.1659

文献信息

• TETRADENTATE AND OCTAHEDRAL METAL COMPLEXES CONTAINING NAPHTHYRIDINOCARBAZOLE AND ITS ANALOGUES
  申请人：Arizona Board of Regents on behalf of Arizona State University

  公开号：US20160359125A1

  公开（公告）日：2016-12-08

  Tetradentate and octahedral metal complexes suitable for use as phosphorescent or delayed fluorescent and phosphorescent emitters in display and lighting applications.

  四齿和八面体金属配合物，适用于显示和照明应用中的磷光或延迟荧光和磷光发射体。
• ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES
  申请人：Universal Display Corporation

  公开号：US20150266863A1

  公开（公告）日：2015-09-24

  A compound having the structure of Formula I, A-L-B-M-D, is disclosed. In the structure of Formula I: A is selected from L is a linker selected from a single bond, an aryl group, a heteroaryl group, and combinations thereof, and may be further substituted; L-B-M has the structure: M is selected from an aryl group, a heteroaryl group, and combinations thereof, and may be further substituted; D has the structure: X is O, S, Se, or CR′R″; X 1 -X 8 , Y 1 -Y 12 , Z 1 , Z 3 -Z 8 , and Z 11 -Z 18 are each independently N or CR; each R, R′, and R″ are selected from a wide variety of substituents; where adjacent R substituents can form a fused ring; and R′ and R″ can form a ring. Formulations and devices, such as an OLEDs, that include the compound of Formula I are also described.

  揭示了具有Formula I结构的化合物A-L-B-M-D。在Formula I的结构中：A是从中选择的L是从单键、芳基、杂环基和它们的组合中选择的连接剂，并且可能进一步取代；L-B-M具有结构：M是从芳基、杂环基和它们的组合中选择的，并且可能进一步取代；D具有结构：X是O、S、Se或CR′R″；X1-X8、Y1-Y12、Z1、Z3-Z8和Z11-Z18分别独立地为N或CR；每个R、R′和R″从各种不同的取代基中选择；相邻的R取代基可以形成融合环；而R′和R″可以形成环。还描述了包括Formula I化合物的制剂和器件，如OLEDs。
• Novel α-Carboline Synthesis Using Tandem aza-Wittig-Electrocyclization Reaction of Indol-2-yl Phosphorane with Enone
  作者：Maria Funicello、Carlo Bonini、Piero Spagnolo

  DOI：10.1055/s-2006-944182

  日期：2006.6

  Mild thermal reaction of indol-2-yl triphenyl- and methyldiphenyl-phosphorane derived from 2-azido-1-methylindole with enones provides a novel entry to 9-methyl-9H-pyrido[2,3-b]indoles through a tandem aza-Wittig-electrocyclization process.

  衍生自 2-叠氮基-1-甲基吲哚的吲哚-2-基三苯基-和甲基二苯基-正膦与烯酮的温和热反应提供了通过串联氮杂进入 9-甲基-9H-吡啶并[2,3-b]吲哚的新途径-Wittig-电环化过程。
• TETRADENTATE METAL COMPLEXES WITH CARBON GROUP BRIDGING LIGANDS
  申请人：Arizona Board of Regents on behalf of Arizona State University

  公开号：US20160133862A1

  公开（公告）日：2016-05-12

  Platinum, palladium, and gold complexes suitable for use as phosphorescent emitters or as delayed fluorescent and phosphorescent emitters having one of the following structures:

  适用于用作磷光发射剂或延迟荧光和磷光发射剂的铂、钯和金络合物，具有以下结构之一：
• Organic electroluminescent materials and devices
  申请人：Universal Display Corporation

  公开号：US10208026B2

  公开（公告）日：2019-02-19

  A compound having the structure of Formula I, A-L-B-M-D, is disclosed. In the structure of Formula I: A is selected from L is a linker selected from a single bond, an aryl group, a heteroaryl group, and combinations thereof, and may be further substituted; L-B-M has the structure: M is selected from an aryl group, a heteroaryl group, and combinations thereof, and may be further substituted; D has the structure: X is O, S, Se, or CR′R″; X1-X8, Y1-Y12, Z1, Z3-Z8, and Z11-Z18 are each independently N or CR; each R, R′, and R″ are selected from a wide variety of substituents; where adjacent R substituents can form a fused ring; and R′ and R″ can form a ring. Formulations and devices, such as an OLEDs, that include the compound of Formula I are also described.

  本发明公开了一种具有式 I（A-L-B-M-D）结构的化合物。在式 I 的结构中 A 选自 L 是选自单键、芳基、杂芳基及其组合的连接体，可被进一步取代； L-B-M 的结构如下 M 选自芳基、杂芳基及其组合，并可被进一步取代； D 具有以下结构 X为O、S、Se或CR′R″；X1-X8、Y1-Y12、Z1、Z3-Z8和Z11-Z18各自独立地为N或CR；各R、R′和R″选自多种取代基；其中相邻的R取代基可形成融合环；R′和R″可形成环。还描述了包括式 I 化合物的制剂和设备，如 OLED。