9-(4,6-二苯基-1,3,5-三嗪-2-基)-9'-苯基-3,3'-联咔唑 | 1266389-01-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 中文名称: 9-(4,6-二苯基-1,3,5-三嗪-2-基)-9'-苯基-3,3'-联咔唑
• 英文名称: PCCzTzn
• 英文别名: 9-(4,6-diphenyl-1,3,5-triazin-2-yl)-9'-phenyl-3,3'-bicarbazole；9-(4,6-diphenyl-1,3,5-triazin-2-yl)-3-(9-phenyl-9H-carbazol-3-yl)-9H-carbazole；3-[9-(4,6-diphenyl-1,3,5-triazin-2-yl)carbazol-3-yl]-9-phenylcarbazole
• CAS: 1266389-01-8
• 化学式: C₄₅H₂₉N₅
• 分子量: 639.759
• InChiKey: KYYFFLQBMZRHNB-UHFFFAOYSA-N

物化性质

• 熔点：
  267℃

计算性质

• 辛醇/水分配系数(LogP)：
  11.4
• 重原子数：
  50
• 可旋转键数：
  5
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  48.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  N-苯基-3-咔唑硼酸 在 四(三苯基膦)钯 、 sodium hydride 、 potassium carbonate 作用下， 以 乙醇 、 N,N-二甲基甲酰胺 、 甲苯 、 mineral oil 为溶剂， 反应 15.0h， 生成 9-(4,6-二苯基-1,3,5-三嗪-2-基)-9'-苯基-3,3'-联咔唑
  参考文献：
  名称：

  [EN] A NOVEL COMBINATION OF A HOST COMPOUND AND A DOPANT COMPOUND AND AN ORGANIC ELECTROLUMINESCENCE DEVICE COMPRISING THE SAME
  [FR] NOUVELLE COMBINAISON D'UN COMPOSÉ HÔTE ET D'UN COMPOSÉ DOPANT ET DISPOSITIF ÉLECTROLUMINESCENT ORGANIQUE LA COMPRENANT

  摘要：

  本发明涉及一种特定的掺杂物化合物和基质化合物的组合，以及包括该组合的有机电致发光器件。与使用传统发光材料的器件相比，本发明的有机电致发光器件具有优异的发光特性，并且具有更低的驱动电压。

  公开号：

  WO2014003440A1

文献信息

• Organic electroluminescent element and material for organic electroluminescent elements
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US09711732B2

  公开（公告）日：2017-07-18

  An organic electroluminescence device includes: a cathode; an anode; and an organic thin-film layer having one or more layers and provided between the anode and the cathode, in which the organic layer includes an emitting layer. The emitting layer includes a first host material, a second host material and a phosphorescent dopant material. The first host material is a compound represented by a formula (1A). The second host material is a compound represented by a formula (2A).

  一种有机电致发光器件包括：阴极；阳极；以及具有一个或多个层的有机薄膜层，设置在阳极和阴极之间，其中有机层包括一个发光层。发光层包括第一主体材料、第二主体材料和磷光掺杂材料。第一主体材料是由式（1A）表示的化合物。第二主体材料是由式（2A）表示的化合物。
• COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE SAME
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US20200270283A1

  公开（公告）日：2020-08-27

  Provided is a compound represented by Formula 1 and an organic light-emitting device including the same. The organic light-emitting device includes: a first electrode; a second electrode facing the first electrode; and an organic layer between the first electrode and the second electrode, the organic layer including an emission layer and the compound represented by Formula 1.

  提供的是由公式1表示的化合物以及包括该化合物的有机发光设备。所述有机发光设备包括：第一电极；与第一电极相对的第二电极；以及位于第一电极和第二电极之间的有机层，所述有机层包括发射层和由公式1表示的化合物。
• Light-Emitting Device Material, Electron-Transport Layer Material, Organic Compound, Light-Emitting Device, Light-Emitting Apparatus, Electronic Device, and Lighting Device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US20210336151A1

  公开（公告）日：2021-10-28

  A light-emitting device material with a low refractive index is provided. The light-emitting device material contains an organic compound which has a pyridine skeleton, a diazine skeleton, or a triazine skeleton and in which the proportion of carbon atoms forming a bond by sp 3 hybrid orbitals is within a certain range. The light-emitting device material contains an organic compound including at least one six-membered heteroaromatic ring having 1 to 3 nitrogen atoms and a plurality of aromatic hydrocarbon rings each having 6 to 14 carbon atoms in a ring. At least two of the plurality of aromatic hydrocarbon rings are benzene rings. The organic compound has a plurality of hydrocarbon groups forming a bond by the sp 3 hybrid orbitals. The ordinary refractive index of a layer containing the organic compound with respect to light with a wavelength in the range from 455 nm to 465 nm is 1.5 to 1.75.

  提供了一种低折射率的发光设备材料。该发光设备材料含有一种有机化合物，该有机化合物具有吡啶骨架、嘧啶骨架或三嗪骨架，并且其中通过sp3杂化轨道形成键的碳原子比例在一定的范围内。发光设备材料含有至少一个六元杂环芳族环，该六元杂环芳族环具有1至3个氮原子和多个六至十四个碳原子的芳香烃环。至少两个上述多个芳香烃环是苯环。该有机化合物具有多个通过sp3杂化轨道形成键的碳氢化合物基团。含有该有机化合物的层相对于波长在455纳米至465纳米范围内的光的普通折射率为1.5至1.75。
• MATERIAL FOR HOLE-TRANSPORT LAYER, MATERIAL FOR HOLE-INJECTION LAYER, ORGANIC COMPOUND, LIGHT-EMITTING DEVICE, LIGHT-EMITTING APPARATUS, ELECTRONIC DEVICE, AND LIGHTING DEVICE
  申请人：SEMICONDUCTOR ENERGY LABORATORY CO., LTD.

  公开号：US20210005814A1

  公开（公告）日：2021-01-07

  A material for a hole-transport layer includes a monoamine compound. The first aromatic group, the second aromatic group, and the third aromatic group are bonded to the nitrogen atom of the monoamine compound. The first and second aromatic groups each independently include 1 to 3 benzene rings. One or both of the first and second aromatic groups have one or more hydrocarbon groups each having 1 to 12 carbon atoms each forming a bond only by the sp 3 hybrid orbitals. The total number of the carbon atoms in the hydrocarbon group in the first or second aromatic group is 6 or more. The total number of the carbon atoms in all of the hydrocarbon groups in the first and second aromatic groups is 8 or more. The third aromatic group is a substituted or unsubstituted monocyclic condensed ring or a substituted or unsubstituted bicyclic or tricyclic condensed ring.

  一种用于空穴传输层的材料包括单胺化合物。第一个芳基团、第二个芳基团和第三个芳基团均连接到单胺化合物的氮原子上。第一个和第二个芳基团每个独立地包括1到3个苯环。第一个和第二个芳基团中的一个或两个具有一个或多个各自具有1到12个碳原子的烃基团，这些烃基团仅通过sp3杂化轨道形成键。第一或第二芳基团中的烃基团中的碳原子总数为6个或更多。第一和第二芳基团中的所有烃基团中的碳原子总数为8个或更多。第三个芳基团是取代的或未取代的单环稠环，或是取代的或未取代的双环或三环稠环。
• ARYLAMINE COMPOUND, HOLE-TRANSPORT LAYER MATERIAL, HOLE-INJECTION LAYER MATERIAL, LIGHT-EMITTING DEVICE, LIGHT-EMITTING APPARATUS, ELECTRONIC APPARATUS, AND LIGHTING DEVICE
  申请人：SEMICONDUCTOR ENERGY LABORATORY CO., LTD.

  公开号：US20210317069A1

  公开（公告）日：2021-10-14

  To provide a novel arylamine compound with a low refractive index. The provided arylamine compound includes at least one aromatic group. The aromatic group includes a first benzene ring, a second benzene ring, a third benzene ring, and at least three alkyl groups. The first benzene ring, the second benzene ring, and the third benzene ring are directly bonded in this order. The first benzene ring is bonded to nitrogen of amine. The first benzene ring may further include a substituted or unsubstituted phenyl group. The second benzene ring or the third benzene ring may further include an alkylated phenyl group. Each of first positions and third positions of two or more of the first to third benzene rings is independently bonded to another benzene ring, a benzene ring of the alkylated phenyl group, any of the at least three alkyl groups, or the nitrogen of the amine.

  提供一种低折射率的新型芳胺化合物。所提供的芳胺化合物包括至少一个芳香族基团。该芳香族基团包括第一苯环、第二苯环、第三苯环和至少三个烷基团。第一苯环、第二苯环和第三苯环按此顺序直接键合。第一苯环与胺的氮原子键合。第一苯环可进一步包括取代的或未取代的苯基团。第二苯环或第三苯环可进一步包括烷基化的苯基团。第一至第三苯环中的两个或多个第一位置和第三位置独立地键合到另一个苯环、烷基化苯基团的苯环、至少三个烷基团中的任一个或胺的氮原子。