9-甲基-9H-咔唑-3,6-二胺 | 46498-17-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 中文名称: 9-甲基-9H-咔唑-3,6-二胺
• 英文名称: 9-methyl-9H-carbazole-3,6-diamine
• 英文别名: 9-methylcarbazole-3,6-diamine
• CAS: 46498-17-3
• 化学式: C₁₃H₁₃N₃
• 分子量: 211.266
• InChiKey: KPIAHQAOODFLBZ-UHFFFAOYSA-N

物化性质

• 沸点：
  493.6±38.0 °C(Predicted)
• 密度：
  1.32±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  57
• 氢给体数：
  2
• 氢受体数：
  2

安全信息

• 海关编码：
  2933990090

反应信息

• 作为反应物：
  描述：

  9-甲基-9H-咔唑-3,6-二胺 以20%的产率得到
  参考文献：
  名称：

  BARANOVA N. I.; SHISHKINA V. I., IZV. VYSSH. UCHEB. ZAVEDENIJ. XIMIYA I

  摘要：

  DOI：

文献信息

• Asymmetric Diamine Compounds Containing Two Functional Groups and Polymers Therefrom
  申请人：KOREA ADVANCED INSTITUTE OF SCIENCE AND TECHNOLOGY

  公开号：US20150045481A1

  公开（公告）日：2015-02-12

  The present invention relates to a novel diamine compound, wherein two substituents R and R′ are introduced asymmetrically, and a polymer thereof. The polymer may have excellent solubility in the organic solvent and allows for easy processibility after imidization, thus giving proper film maintaining superior properties, such as thermal, mechanical, and optical properties for applications in electrical, electronic, or optical materials.

  本发明涉及一种新型二胺化合物，其中引入了两个不对称的取代基R和R'，以及其聚合物。该聚合物在有机溶剂中具有出色的溶解性，并在酰亚胺化后易于加工，从而形成具有优越热性能、机械性能和光学性能的适用于电气、电子或光学材料的适当薄膜。
• NOVEL MACROCYCLE WITH REPEATING TRAZOLE-CARBAZOLE UNITS
  申请人：INDIANA UNIVERSITY RESEARCH & TECHNOLOGY CORPORATION

  公开号：US20160347758A1

  公开（公告）日：2016-12-01

  Disclosed herein are compositions of tricarbazole triazolophane (tricarb) of Formulas (I), (II) and (III): wherein R of Formula (I) is selected from a group consisting of alkyl (for example, C 6 -C 18 ), alkyl-substituted phenyl derivatives, and substituted glycol derivatives, among others, or a combination thereof, and R , R ′ and R ″ of Formulas (II) and (III) are independently selected from a group consisting of alkyl (for example, C 6 to C 18 ), alkyl-substituted phenyl derivatives, and substituted glycol derivatives, or a combination thereof. The disclosure presents examples of thin films composed of the same as well as methods of binding anions from the same.

  本文公开了三噻唑酮三唑环（tricarb）的化合物，其化学式分别为（I）、（II）和（III）：其中化学式（I）的R选自包括烷基（例如，C6-C18）、烷基取代的苯衍生物和取代的乙二醇衍生物等的群体中，或其组合物；化学式（II）和（III）的R、R'和R"分别选自包括烷基（例如，C6到C18）、烷基取代的苯衍生物和取代的乙二醇衍生物等的群体中，或其组合物。本文还提供了由此组成的薄膜的示例，以及从中结合阴离子的方法。
• Keratin dyeing compounds, keratin dyeing compositions containing them, and use thereof
  申请人：Glenn Wayne Robert

  公开号：US20050217038A1

  公开（公告）日：2005-10-06

  Compositions for the oxidative dyeing of keratin fibers, comprising a medium suitable for dyeing and one or more tricyclic fused 6-5-6 heteroaromatic keratin dyeing compounds having one heteroatom. A method for oxidative dyeing of keratin fibers, comprising applying such compositions in the presence of an oxidizing agent, for a period sufficient to develop the desired coloration.

  这段话的中文翻译如下： 本发明涉及一种用于氧化染色角蛋白纤维的组合物，包括适合染色的介质和一种或多种三环融合的6-5-6杂环角蛋白染料化合物，其中含有一个杂原子。一种氧化染色角蛋白纤维的方法，包括在氧化剂的存在下应用这种组合物，以便在足够的时间内发展所需的颜色。
• Keratin Dyeing Compounds, Keratin Dyeing Compositions Containing Them, And Use Thereof
  申请人：Glenn Wayne Robert

  公开号：US20080098535A1

  公开（公告）日：2008-05-01

  Compositions for the oxidative dyeing of keratin fibers, comprising a medium suitable for dyeing and one or more tricyclic fused 6-5-6 heteroaromatic keratin dyeing compounds having one heteroatom. A method for oxidative dyeing of keratin fibers, comprising applying such compositions in the presence of an oxidizing agent, for a period sufficient to develop the desired coloration.

  含氧化染料的角蛋白纤维氧化染色组合物，包括适于染色的介质和一个或多个三环融合6-5-6杂环角蛋白染料化合物，其中含有一个杂原子。一种氧化染色角蛋白纤维的方法，包括在氧化剂存在下应用这种组合物，以达到所需的着色时间。
• NOVEL POLYAMIDEIMIDE HAVING LOW THERMAL EXPANSION COEFFICIENT
  申请人：KOREA ADVANCED INSTITUTE OF SCIENCE AND TECHNOLOGY

  公开号：US20160194449A1

  公开（公告）日：2016-07-07

  The present invention relates to a polyamideimide comprising an asymmetric dicarboxylic acid derivative wherein, from among a cyclic group A and a cyclic group B, two substitutents groups R and R′ are bonded only to the cyclic group A on one side. A polymer produced by means of the present invention can have adequate solubility with respect to organic solvents, high thermal stability, a high glass transition temperature, high transparency and a low thermal expansion coefficient, and is able not only to satisfy requirements for core substrate materials of flexible displays but also to be used as a material for various soft electronic data devices.

  本发明涉及一种聚酰胺酰亚胺，其包括一种不对称二羧酸衍生物，其中，从环状基团A和环状基团B中选择，两个取代基R和R'仅在一侧与环状基团A相结合。通过本发明手段生产的聚合物可以在有机溶剂中具有足够的溶解性，具有高热稳定性，高玻璃化转变温度，高透明度和低热膨胀系数，并且不仅能够满足柔性显示器的核心基板材料的要求，还可以用作各种软性电子数据设备的材料。