ethyl (E)-2-tributylstannyl-2-pentenoate | 146984-84-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: ethyl (E)-2-tributylstannyl-2-pentenoate
• CAS: 146984-84-1
• 化学式: C₁₉H₃₈O₂Sn
• 分子量: 417.22
• InChiKey: BVBSXSWYVGGGAR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.27
• 重原子数：
  22
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.84
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-戊炔酸乙酯 、 三正丁基氢锡 在 四(三苯基膦)钯 作用下， 以 四氢呋喃 为溶剂， 生成 ethyl (E)-2-tributylstannyl-2-pentenoate 、 ethyl (E)-3-(tri-n-butylstannyl)-2-pentenoate
  参考文献：
  名称：

  Synthetic Applications of Alkyl (E)-2-Tributylstannyl-2-alkenoates: Selective Synthesis of (S)-1-Methylbutyl (E)-2-Methyl-2-pentenoate, an Aggregation Pheromone Component ofRhyzopertha dominicaandProstephanus truncatus

  摘要：

  Stereoisomerically pure (S)-1-methylbutyl (E)-2-methyl-2-pentenoate (dominicalure-1), (S)(E)-11, an aggregation pheromone component for the lesser and the greater grain borers, has been efficiently synthesized from the main product of the palladium-catalyzed reaction between ethyl 2-pentynoate, 1a, and Bu3SnH, i.e. ethyl (E)-2-tributylstannyl-2-pentenoate, (E)-2a.

  DOI：

  10.1080/00397919308009761

文献信息

• Synthetic Applications of Alkyl (E)-2-Tributylstannyl-2-alkenoates: Selective Synthesis of (S)-1-Methylbutyl (E)-2-Methyl-2-pentenoate, an Aggregation Pheromone Component of<i>Rhyzopertha dominica</i>and<i>Prostephanus truncatus</i>
  作者：Renzo Rossi、Adriano Carpita、Paolo Cossi

  DOI：10.1080/00397919308009761

  日期：1993.1

  Stereoisomerically pure (S)-1-methylbutyl (E)-2-methyl-2-pentenoate (dominicalure-1), (S)(E)-11, an aggregation pheromone component for the lesser and the greater grain borers, has been efficiently synthesized from the main product of the palladium-catalyzed reaction between ethyl 2-pentynoate, 1a, and Bu3SnH, i.e. ethyl (E)-2-tributylstannyl-2-pentenoate, (E)-2a.