Tricyclo(4.2.1.0(2,5))non-7-ene-3,4-diol

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Tricyclo(4.2.1.0(2,5))non-7-ene-3,4-diol
• 英文别名: tricyclo[4.2.1.02,5]non-7-ene-3,4-diol
• 化学式: C₉H₁₂O₂
• mdl: MFCD03931665
• 分子量: 152.19
• InChiKey: AYFITXXXKCZALT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.3
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.777
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

文献信息

• Method for functionalising a thermoset, crosslinked isocyanate-based polymeric solid material.
  申请人：Recticel

  公开号：EP2522685A2

  公开（公告）日：2012-11-14

  The invention relates to a method for functionalising a thermoset, crosslinked isocyanate-based polymeric solid material which is made of isocyanate and isocyanate reactive components, at least one of which comprises an anchor component which has at least one anchor group. The anchor groups on the solid material are formed by terminal alkene and/or alkyne groups. To functionalise this polymeric solid material it is brought in contact with a solution which contains at least one functional component. This functional component comprises at least one thiol group and is allowed to bind covalently to the polymeric solid material by a free-radical addition reaction between the thiol groups on the functional component and the terminal alkene and/or alkyne anchor groups on the undissolved solid material. An effective functionalisation of the polymeric material can thus be achieved notwithstanding the heterogeneous reaction conditions.

  本发明涉及一种对热固性交联异氰酸酯基聚合物固体材料进行功能化的方法，该固 体材料由异氰酸酯和异氰酸酯反应组分组成，其中至少一种组分包括一个锚定组分，该 锚定组分具有至少一个锚定基团。固体材料上的锚基由端烯基和/或炔基形成。为了使这种聚合固体材料功能化，需要将其与含有至少一种功能成分的溶液接触。这种官能团至少包含一个硫醇基团，通过官能团上的硫醇基团与未溶解固体材料上的末端烯基和/或炔基锚基团之间的自由基加成反应，使其与聚合物固体材料共价结合。因此，尽管存在异构反应条件，但仍可实现聚合物材料的有效官能化。
• Method for functionalising a thermoset isocyanate-based polymeric solid material.
  申请人：Recticel

  公开号：EP2522684A1

  公开（公告）日：2012-11-14

  The invention relates to a method for functionalising a thermoset isocyanate-based polymeric solid material which is made of isocyanate and isocyanate reactive components, at least one of which comprises an anchor component which has at least one anchor group. The anchor groups on the solid material are formed by terminal alkene and/or alkyne groups. To functionalise this polymeric solid material it is brought in contact with a solution which contains at least one functional component. This functional component comprises at least one thiol group and is allowed to bind covalently to the polymeric solid material by a free-radical addition reaction between the thiol groups on the functional component and the terminal alkene and/or alkyne anchor groups on the solid material. An effective functionalisation of the polymeric material can thus be achieved notwithstanding the heterogeneous reaction conditions.

  本发明涉及一种热固性异氰酸酯基聚合物固体材料的功能化方法，该固体材料由异氰酸酯和异氰酸酯反应组分组成，其中至少一种组分包括一个锚定组分，该锚定组分具有至少一个锚定基团。固体材料上的锚基由端烯基和/或炔基形成。为了使这种聚合固体材料功能化，需要将其与含有至少一种功能成分的溶液接触。这种官能团至少包含一个硫醇基团，并通过官能团上的硫醇基团与固体材料上的末端烯基和/或炔基锚基团之间的自由基加成反应，与聚合物固体材料共价结合。因此，尽管存在异构反应条件，但仍可实现聚合物材料的有效官能化。
• METHOD FOR FUNCTIONALISING A THERMOSET, CROSSLINKED ISOCYANATE-BASED POLYMERIC SOLID MATERIAL
  申请人：JONCKHEERE Laura

  公开号：US20120289621A1

  公开（公告）日：2012-11-15

  The invention relates to a method for functionalising a thermoset, crosslinked isocyanate-based polymeric solid material which is made of isocyanate and isocyanate reactive components, at least one of which comprises an anchor component which has at least one anchor group. The anchor groups on the solid material are formed by terminal alkene and/or alkyne groups. To functionalise this polymeric solid material it is brought in contact with a solution which contains at least one functional component. This functional component comprises at least one thiol group and is allowed to bind covalently to the polymeric solid material by a free-radical addition reaction between the thiol groups on the functional component and the terminal alkene and/or alkyne anchor groups on the undissolved solid material. An effective functionalisation of the polymeric material can thus be achieved notwithstanding the heterogeneous reaction conditions.
• US8901180B2
  申请人：——

  公开号：US8901180B2

  公开（公告）日：2014-12-02