7-Octyl-oxepan-2-one | 3041-18-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 内酯类
• 英文名称: 7-Octyl-oxepan-2-one
• 英文别名: 7-Octyloxepan-2-one
• CAS: 3041-18-7
• 化学式: C₁₄H₂₆O₂
• 分子量: 226.359
• InChiKey: VOYLUCBYLUFRDL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  16
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.93
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  7-Octyl-oxepan-2-one 生成 (S)-7-Octyl-oxepan-2-one
  参考文献：
  名称：

  Resolution of racemic ε-lactones

  摘要：

  Kinetic resolution of racemic epsilon-lactones by Pig Liver Esterase give optically active R (+) epsilon-lactones. When alkyl group is higher than propyl, Horse Liver Esterase leads to the destruction of the opposite enantiomer. Enantiomeric excess is easily evaluated by G.C. on a chiral stationary phase.

  DOI：

  10.1016/s0957-4166(00)86202-3
• 作为产物：
  描述：

  2-辛基环己酮 在 单过氧邻苯二甲酸 作用下， 以 乙醚 为溶剂， 生成 7-Octyl-oxepan-2-one
  参考文献：
  名称：

  Resolution of racemic ε-lactones

  摘要：

  Kinetic resolution of racemic epsilon-lactones by Pig Liver Esterase give optically active R (+) epsilon-lactones. When alkyl group is higher than propyl, Horse Liver Esterase leads to the destruction of the opposite enantiomer. Enantiomeric excess is easily evaluated by G.C. on a chiral stationary phase.

  DOI：

  10.1016/s0957-4166(00)86202-3

文献信息

• Verfahren zur Herstellung von stabilisiertem Polyamid 6
  申请人：Zimmer AG

  公开号：EP1333049B1

  公开（公告）日：2006-03-15
• COMPOSITION AND POLYMER
  申请人：Asahi Kasei Kabushiki Kaisha

  公开号：EP2735581B1

  公开（公告）日：2021-07-14
• SYNTHESIS OF CYCLOHEXANE ESTER DERIVATIVES USEFUL AS SENSATES IN CONSUMER PRODUCTS
  申请人：The Procter & Gamble Company

  公开号：EP3390352A1

  公开（公告）日：2018-10-24
• Composition and Polymer
  申请人：Nakamura Akitake

  公开号：US20140121293A1

  公开（公告）日：2014-05-01

  Disclosed is a composition comprising (A) at least one compound selected from the group consisting of an ether compound having two or more ether groups, a trivalent phosphorus compound, and a ketone compound, (B) a boron trihalide, and (C) an episulfide compound.
• SYNTHESIS OF ARYL CYCLOHEXANE ESTER DERIVATIVES USEFUL AS SENSATES IN CONSUMER PRODUCTS
  申请人：The Procter & Gamble Company

  公开号：US20190276389A1

  公开（公告）日：2019-09-12

  Personal care compositions, such as oral care and skin care compositions containing a flavor/perfume system comprising one or more coolants. The pleasant cool sensation provided by a coolant is enhanced in terms of quicker onset, greater intensity, impact or longer duration, which improves appeal and acceptability of the compositions to consumers.