2-(t-butyl)-9,10-diphenylanthracene | 596803-33-7

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物 - 芳基萘木脂素
• 英文名称: 2-(t-butyl)-9,10-diphenylanthracene
• 英文别名: 2-tert-butyl-9,10-diphenylanthracene
• CAS: 596803-33-7
• 化学式: C₃₀H₂₆
• 分子量: 386.536
• InChiKey: VVJKFZOOFYHKRU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.1
• 重原子数：
  30
• 可旋转键数：
  3
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  2-叔丁基蒽醌 在 正丁基锂 、 次磷酸钠一水合物 、 potassium iodide 作用下， 以 四氢呋喃 、 正己烷 、 溶剂黄146 为溶剂， 反应 6.0h， 生成 2-(t-butyl)-9,10-diphenylanthracene
  参考文献：
  名称：

  Blue Organic Light-Emitting Diodes Containing Anthracene Derivatives With End-Capping Phenyl Group

  摘要：

  We have synthesized and characterized new blue host materials for OLEDs; 9,10-di-o-tolylanthracene (1), 2-tert-butyl-9,10-diphenylanthracene (2), 10,10'-diphenyl-9,9'-bianthracene (3), and 1,4-bis(10-phenylanthracen-9-yl)benzene (4). To explore electroluminescent properties of these materials, multilayered OLEDs with the configuration of ITO/NPB (50 nm)/Blue emitters (1-4) (30 nm)/Liq (2 nm)/Al (100 nm) were fabricated. Among those non-doped devices, the device 4a employing 4 as an emitter showed high efficiencies of 4.11 cd/A, 3.31 lm/W, and 2.35%, respectively. The device 2b employing 2 as host material for PFVtPh blue dopant material exhibited excellent efficiencies with 5.64 cd/A, 4.14 lm/W, and 4.54%.

  DOI：

  10.1080/15421406.2012.689157

文献信息

• Synthesis process
  申请人：Coggan A. Jennifer

  公开号：US20070020481A1

  公开（公告）日：2007-01-25

  A process for preparing a substituted or unsubstituted 9,10-diarylanthracene including reacting an organometallic substituted or unsubstituted aryl compound with a substituted or unsubstituted anthraquinone to yield a substituted or unsubstituted diol; and reacting the substituted or unsubstituted diol with a reducing agent to yield the substituted or unsubstituted 9,10-diarylanthracene is disclosed. An electroluminescent device comprising a light-emitting layer comprising the substituted or unsubstituted 9,10-diarylanthracene is also disclosed.

  本发明公开了一种制备取代或未取代的9,10-二芳基蒽的方法，包括将有机金属取代或未取代的芳基化合物与取代或未取代的蒽醌反应，得到取代或未取代的二醇；然后将取代或未取代的二醇与还原剂反应，得到取代或未取代的9,10-二芳基蒽。同时，本发明还公开了一种包括含有取代或未取代的9,10-二芳基蒽的发光层的电致发光装置。
• Synthesis of t-butylated diphenylanthracene derivatives as blue host materials for OLED applications
  作者：Banumathy Balaganesan、Wen-Jian Shen、Chin H. Chen

  DOI：10.1016/s0040-4039(03)01300-5

  日期：2003.7

  This paper describes the cost-effective synthesis and the photoluminescence of diphenylanthracene derivatives, which are found to be potential blue host materials for organic light emitting diode (OLED) technology. (C) 2003 Elsevier Ltd. All rights reserved.
• Blue Organic Light-Emitting Diodes Containing Anthracene Derivatives With End-Capping Phenyl Group
  作者：Heung Soo Jang、Kum Hee Lee、Seok Jae Lee、Young Kwan Kim、Seung Soo Yoon

  DOI：10.1080/15421406.2012.689157

  日期：2012.9.5

  We have synthesized and characterized new blue host materials for OLEDs; 9,10-di-o-tolylanthracene (1), 2-tert-butyl-9,10-diphenylanthracene (2), 10,10'-diphenyl-9,9'-bianthracene (3), and 1,4-bis(10-phenylanthracen-9-yl)benzene (4). To explore electroluminescent properties of these materials, multilayered OLEDs with the configuration of ITO/NPB (50 nm)/Blue emitters (1-4) (30 nm)/Liq (2 nm)/Al (100 nm) were fabricated. Among those non-doped devices, the device 4a employing 4 as an emitter showed high efficiencies of 4.11 cd/A, 3.31 lm/W, and 2.35%, respectively. The device 2b employing 2 as host material for PFVtPh blue dopant material exhibited excellent efficiencies with 5.64 cd/A, 4.14 lm/W, and 4.54%.