香豆素545T | 155306-71-1

• 物质功能分类: 医药中间体 - OLED材料中间体
• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 香豆素及其衍生物
• 中文名称: 香豆素545T
• 中文别名: 10-(2-苯并噻唑基)-2,3,6,7-四氢-1,1,7,7-四甲基-1H,5H,11H-[1]苯并吡喃[6,7,8-ij]喹啉嗪-11-酮
• 英文名称: C-545T
• 英文别名: 2,3,6,7-tetrahydro-1,1,7,7,-tetramethyl-1H,5H,11H-10-(2-benzothiazolyl)quinolizino-[9,9a,1gh]coumarin；Coumarin 545T；5-(1,3-benzothiazol-2-yl)-10,10,16,16-tetramethyl-3-oxa-13-azatetracyclo[7.7.1.02,7.013,17]heptadeca-1,5,7,9(17)-tetraen-4-one
• CAS: 155306-71-1
• 化学式: C₂₆H₂₆N₂O₂S
• 分子量: 430.571
• InChiKey: MSDMPJCOOXURQD-UHFFFAOYSA-N

物化性质

• 熔点：
  230-232°C
• 沸点：
  615.3±65.0 °C(Predicted)
• 密度：
  1.33±0.1 g/cm3(Predicted)
• 稳定性/保质期：
  在常温常压下保持稳定，应避免与强氧化剂接触。

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  31
• 可旋转键数：
  1
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  70.7
• 氢给体数：
  0
• 氢受体数：
  5

安全信息

• 安全说明：
  S22,S24/25
• 海关编码：
  29349990

反应信息

• 作为反应物：
  描述：

  香豆素545T 在 硫酸 作用下， 以80%的产率得到2-(10,10,16,16-Tetramethyl-4-oxo-3-oxa-13-azatetracyclo[7.7.1.02,7.013,17]heptadeca-1,5,7,9(17)-tetraen-5-yl)-1,3-benzothiazole-6-sulfonic acid
  参考文献：
  名称：

  AMINOCOUMARIN COMPOUND, AND AMINOCOUMARIN COMPOUND-CONTAINING RESIN PARTICLES

  摘要：

  The present invention provides: an aminocoumarin compound having a structure represented by the following formula (1); and an aminocoumarin compound-containing resin particle containing the aminocoumarin compound and a resin particle containing the aminocoumarin compound. In formula (1), Rs each independently represent a hydrogen atom or a methyl group, Q represents a sulfur atom, an oxygen atom, or N—R 1 , and R 1 represents a hydrogen atom or a methyl group. The aminocoumarin compound of the present invention is a fluorescent dye that has a longer excitation wavelength than a conventionally known sulfonated coumarin-based compound and is effectively excited at a wavelength of 475 nm or more, particularly at a wavelength around 500 nm. The aminocoumarin compound of the present invention is a fluorescent dye that is excited, for example, at a wavelength of 475 to 510 nm and can be observed in a green light emission region of 510 to 540 nm using the wavelength characteristic, and can be expected to be suitably utilized in immunostaining or the like.

  公开号：

  US20210277250A1
• 作为产物：
  描述：

  2-(2-苯并噻唑)乙酸乙酯 、 9-醛基-8-羟基-1,1,7,7-四甲基久洛尼定 、 哌啶 在 乙腈 作用下， 以 乙腈 为溶剂， 反应 15.0h， 以to give 19 g (79% yield) of pure dye C-545T的产率得到香豆素545T
  参考文献：
  名称：

  Green organic electroluminescent devices

  摘要：

  一种有机EL器件，包括阳极和阴极，以及至少一种含有下式化合物的有机发光层：##STR1## 其中：X = S或O，R1和R2分别为1至20个碳原子的烷基，芳基或碳环系统；R3和R4分别为1至10个碳原子的烷基，或连接到R1，R2的分支或非分支5或6成员取代环；R5和R6分别为1至20个碳原子的烷基，分支或非分支。

  公开号：

  US06020078A1

文献信息

• ORGANIC COMPOUND AND ORGANIC LIGHT EMITTING DEVICE USING THE SAME
  申请人：KIM Kong Kyeom

  公开号：US20140077165A1

  公开（公告）日：2014-03-20

  The present invention provides an organic light emitting device comprising a first electrode, at least one organic layer and a second electrode, laminated successively, in which at least one layer of the organic layer has a polycyclic aromatic hydrocarbon as a core and comprises at least one of a derivative in which a substituted or unsubstituted C 2-30 cycloalkane, or a substituted or unsubstituted C 5-50 polycycloalkane is directly fused to the core or fused to a substituent of the core; and a new organic compound usable in the organic light emitting device. Furthermore, the present invention provides a charge carrier extracting, injecting or transporting material which has a polycyclic aromatic hydrocarbon as a core and comprises a derivative in which a substituted or unsubstituted C 2-30 cycloalkane, or a substituted or unsubstituted C 5-50 polycycloalkane is directly fused to the core or fused to a substituent of the core.

  本发明提供了一种有机发光器件，包括依次层叠的第一电极、至少一个有机层和第二电极，其中有机层中的至少一层具有多环芳烃作为核心，并包括以下至少一种衍生物：其中取代或未取代的C2-30环烷烃，或取代或未取代的C5-50多环烷烃直接与核心融合，或与核心的取代基融合；以及一种新的可用于有机发光器件的有机化合物。此外，本发明提供了一种具有多环芳烃作为核心的电荷载体提取、注入或传输材料，包括以下衍生物：其中取代或未取代的C2-30环烷烃，或取代或未取代的C5-50多环烷烃直接与核心融合，或与核心的取代基融合。
• COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE SAME
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US20200270283A1

  公开（公告）日：2020-08-27

  Provided is a compound represented by Formula 1 and an organic light-emitting device including the same. The organic light-emitting device includes: a first electrode; a second electrode facing the first electrode; and an organic layer between the first electrode and the second electrode, the organic layer including an emission layer and the compound represented by Formula 1.

  提供的是由公式1表示的化合物以及包括该化合物的有机发光设备。所述有机发光设备包括：第一电极；与第一电极相对的第二电极；以及位于第一电极和第二电极之间的有机层，所述有机层包括发射层和由公式1表示的化合物。
• ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：GUANGDONG AGLAIA OPTOELECTRONIC MATERIALS CO., LTD.

  公开号：US20190263735A1

  公开（公告）日：2019-08-29

  This invention relates to an OLED, comprising an anode, a cathode, and an organic layer, the organic layer at least contains one or more layers containing light emitting layer from the hole injection layer, hole transport layer, electron injection layer, electron transport layer, light emitting layer; the light emitting layer is a host guest doping system composed of host materials and guest materials. The light-emitting zone of the light emitting layer is 490-750 nm, and the host material has a structure with the formula (I). The OLED can emit red or green light, with the advantages of excellent light emitting efficiency, excellent color purity and long lifetime.

  这项发明涉及一种有机发光二极管（OLED），包括阳极、阴极和有机层，该有机层至少包含一个或多个层，从空穴注入层、空穴传输层、电子注入层、电子传输层、发光层中至少包含一个或多个层；发光层是由主体材料和客体材料组成的主客体掺杂系统。发光层的发光区域为490-750纳米，主体材料具有结构式（I）。该OLED可以发出红光或绿光，具有优异的发光效率、优异的色彩纯度和长寿命的优点。
• Tetradentate platinum and palladium complex emitters containing phenyl-pyrazole and its analogues
  申请人：ARIZONA BOARD OF REGENTS ON BEHALF OF ARIZONA STATE UNIVERSITY

  公开号：US10020455B2

  公开（公告）日：2018-07-10

  A phosphorescent emitter or delayed fluorescent and phosphorescent emitters represented by Formula 1 or Formula II, where M is platinum or palladium.

  根据您的要求，翻译结果如下： 一个磷光发射器或延迟荧光和磷光发射器，由公式1或公式II表示，其中M是铂或钯。
• Tetradentate Platinum And Palladium Complex Emitters Containing Phenyl-Pyrazole And Its Analogues
  申请人：Li Jian

  公开号：US20150194616A1

  公开（公告）日：2015-07-09

  A phosphorescent emitter or delayed fluorescent and phosphorescent emitters represented by Formula 1 or Formula II, where M is platiunum or palladium.

  一个磷光发射器或延迟荧光和磷光发射器，由公式1或公式II表示，其中M是铂或钯。