11-Methyl-tricyclo[6.3.0.0^4,11]undecan-5-one | 137123-96-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 11-Methyl-tricyclo[6.3.0.0^4,11]undecan-5-one
• 英文别名: 11-Methyltricyclo[6.3.0.04,11]undecan-5-one；11-methyltricyclo[6.3.0.04,11]undecan-5-one
• CAS: 137123-96-7
• 化学式: C₁₂H₁₈O
• 分子量: 178.274
• InChiKey: CSLTUYMDSCWJCS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  13
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  (2aS,5aR,8R,8aR)-8-Methyl-octahydro-cyclobuta[d]inden-3-one 在 三氯化铝 作用下， 以3%的产率得到(1R^*,5S^*,8R^*,9S^*)-9-Methyltricyclo<6.3.0.0^1,5>undecan-4-one
  参考文献：
  名称：

  A novel method for the synthesis of bicyclo[4.2.1]nonanes by acid-catalyzed rearrangement of 6-substituted bicyclo[4.2.0]octanones

  摘要：

  A novel and highly-efficient method for the synthesis of the bicyclo[4.2.1]nonane ring system by acid-catalyzed rearrangement of 6-substituted bicyclo-[4.2.0]octan-2-ones was developed.

  DOI：

  10.1021/jo00024a007

文献信息

• A novel method for the synthesis of bicyclo[4.2.1]nonanes by acid-catalyzed rearrangement of 6-substituted bicyclo[4.2.0]octanones
  作者：Kiyomi Kakiuchi、Keisuke Fukunaga、Fumiyuki Matsuo、Yutaka Ohnishi、Yoshito Tobe

  DOI：10.1021/jo00024a007

  日期：1991.11

  A novel and highly-efficient method for the synthesis of the bicyclo[4.2.1]nonane ring system by acid-catalyzed rearrangement of 6-substituted bicyclo-[4.2.0]octan-2-ones was developed.