3-phenyl-9-[4-(5-phenyl-1,3,4-oxadiazol-2-yl)phenyl]-9H-carbazole | 1215232-06-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 3-phenyl-9-[4-(5-phenyl-1,3,4-oxadiazol-2-yl)phenyl]-9H-carbazole
• 英文别名: 2-Phenyl-5-[4-(3-phenylcarbazol-9-yl)phenyl]-1,3,4-oxadiazole
• CAS: 1215232-06-6
• 化学式: C₃₂H₂₁N₃O
• 分子量: 463.538
• InChiKey: QYXZXNJCGONVOW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.8
• 重原子数：
  36
• 可旋转键数：
  4
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  43.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  3-苯基-9H-咔唑 、 2-(4-iodophenyl)-5-phenyl-1,3,4-oxadiazole 在 三叔丁基膦 、 bis(dibenzylideneacetone)-palladium⁽⁰⁾ sodium t-butanolate 作用下， 以 正己烷 、 甲苯 为溶剂， 反应 15.0h， 以64%的产率得到3-phenyl-9-[4-(5-phenyl-1,3,4-oxadiazol-2-yl)phenyl]-9H-carbazole
  参考文献：
  名称：

  [EN] FLUORENE DERIVATIVE, LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, ELECTRONIC DEVICE, AND LIGHTING DEVICE
  [FR] DÉRIVÉ DE FLUORÈNE, ÉLÉMENT ÉMETTEUR DE LUMIÈRE, DISPOSITIF ÉMETTEUR DE LUMIÈRE, DISPOSITIF ÉLECTRONIQUE ET DISPOSITIF D'ÉCLAIRAGE

  摘要：

  本发明的目的是通过提供如下所示的通式（G1）所代表的新型芴衍生物，提供具有高发光效率的发光元件。在该式中，R1至R8独立地表示氢原子、具有1至6个碳原子的烷基基团、取代或未取代的苯基团，或取代或未取代的联苯基团中的任何一种。此外，α1至α4独立地表示具有6至12个碳原子的取代或未取代的芳基基团中的任何一种。此外，Ar1和Ar2独立地表示环中具有6至13个碳原子的芳基基团中的任何一种，Ar3表示具有1至6个碳原子的烷基基团或具有6至12个碳原子的取代或未取代的芳基基团。J、k、m和n各自独立地表示0或1。

  公开号：

  WO2010137601A1

文献信息

• Carbazole Compound, Light-Emitting Element, Light-Emitting Device, Electronic Device, and Lighting Device
  申请人：Osaka Harue

  公开号：US20120302762A1

  公开（公告）日：2012-11-29

  A carbazole compound represented by General Formula (G1) is provided. In the formula, α represents a phenylene group, Ar 1 represents an alkyl group having 1 to 6 carbon atoms, a substituted or unsubstituted phenyl group, a substituted or unsubstituted naphthyl group, or a substituted or unsubstituted phenanthryl group, Ar 2 represents hydrogen, a substituted or unsubstituted phenyl group, a substituted or unsubstituted naphthyl group, or a substituted or unsubstituted phenanthryl group, Ar 3 represents a substituted or unsubstituted phenyl group, a substituted or unsubstituted naphthyl group, or a substituted or unsubstituted phenanthryl group, and R 1 represents hydrogen, an alkyl group having 1 to 6 carbon atoms, or a substituted or unsubstituted phenyl group. Further, n is 0 or 1.

  提供一种由一般式（G1）表示的咔唑化合物。在该式中，α代表苯基，Ar1代表具有1至6个碳原子的烷基基团、取代或未取代的苯基、取代或未取代的萘基团或取代或未取代的菲基团，Ar2代表氢、取代或未取代的苯基、取代或未取代的萘基团或取代或未取代的菲基团，Ar3代表取代或未取代的苯基、取代或未取代的萘基团或取代或未取代的菲基团，R1代表氢、具有1至6个碳原子的烷基基团或取代或未取代的苯基。此外，n为0或1。
• Light-Emitting Element, Light-Emitting Device, Display Device, Lighting Device, and Electonic Device
  申请人：Ohsawa Nobuharu

  公开号：US20130009139A1

  公开（公告）日：2013-01-10

  A light-emitting element is disclosed where a host material and a hole-transport material each consist of a carbazole skeleton and another skeleton other than the carbazole skeleton. Both the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO) of the hole-transport material are distributed over the carbazole skeleton, while the HOMO of the host material is distributed over the carbazole skeleton and the LUMO thereof is distributed over the skeleton other than the carbazole skeleton. This combination of the hole-transport material and the host material allows the fabrication of a light-emitting element with high emission efficiency and low driving voltage.

  公开了一种发光元件，其中主体材料和空穴传输材料均由咔唑骨架和咔唑骨架以外的另一种骨架组成。空穴传输材料的最高占据分子轨道（HOMO）和最低未占据分子轨道（LUMO）均分布在咔唑骨架上，而主体材料的HOMO分布在咔唑骨架上，其LUMO分布在咔唑骨架以外的骨架上。这种空穴传输材料和主体材料的组合使得可以制造出发光效率高、驱动电压低的发光元件。
• FLUORENE DERIVATIVE, LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, ELECTRONIC DEVICE, AND LIGHTING DEVICE
  申请人：SEMICONDUCTOR ENERGY LABORATORY CO., LTD.

  公开号：US20150270484A1

  公开（公告）日：2015-09-24

  An object is to provide a light-emitting element having high light-emission efficiency by provision of a novel fluorene derivative as represented by General. Formula (G1) below. In the formula, R 1 to R 8 independently represent any of a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, a substituted or unsubstituted phenyl group, or a substituted or unsubstituted biphenyl group. Further, α 1 to α 4 independently represent any of a substituted or unsubstituted arylene group having 6 to 12 carbon atoms. Furthermore, Ar 1 and Ar 2 independently represent any of an aryl group having 6 to 13 carbon atoms in a ring and Ar 3 represents an alkyl group having 1 to 6 carbon atoms or a substituted or unsubstituted aryl group having 6 to 12 carbon atoms. J, k, m, and n each independently represent 0 or 1.

  本发明旨在通过提供一种新的荧光烯衍生物，如下所示的通用式（G1），来提供具有高光发射效率的发光元件。在公式中，R1至R8独立地表示氢原子，具有1至6个碳原子的烷基，取代或未取代的苯基或取代或未取代的联苯基中的任何一种。此外，α1至α4独立地表示具有6至12个碳原子的取代或未取代的芳基烃基。此外，Ar1和Ar2独立地表示具有6至13个碳原子的环中的芳基基团，而Ar3表示具有1至6个碳原子的烷基或具有6至12个碳原子的取代或未取代的芳基基团。J，k，m和n各自独立地表示0或1。
• Fluorene derivative, light-emitting elements, light-emitting device, electronic device, and lighting device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US10553797B2

  公开（公告）日：2020-02-04

  An object is to provide a light-emitting element having high light-emission efficiency by provision of a novel fluorene derivative as represented by General Formula (G1) below. In the formula, R1 to R8 independently represent any of a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, a substituted or unsubstituted phenyl group, or a substituted or unsubstituted biphenyl group. Further, α1 to α4 independently represent any of a substituted or unsubstituted arylene group having 6 to 12 carbon atoms. Furthermore, Ar1 and Ar2 independently represent any of an aryl group having 6 to 13 carbon atoms in a ring and Ar3 represents an alkyl group having 1 to 6 carbon atoms or a substituted or unsubstituted aryl group having 6 to 12 carbon atoms. J, k, m, and n each independently represent 0 or 1.

  目的是通过提供一种新型芴衍生物，如下文通式 (G1) 所示，提供一种具有高发光效率的发光元件。 式中，R1 至 R8 独立地代表氢原子、具有 1 至 6 个碳原子的烷基、取代或未取代的苯基、取代或未取代的联苯基中的任意一种。此外，α1 至 α4 独立地代表具有 6 至 12 个碳原子的取代或未取代的芳烯基团中的任一个。此外，Ar1 和 Ar2 独立地代表在环上具有 6 至 13 个碳原子的芳基，Ar3 代表具有 1 至 6 个碳原子的烷基或具有 6 至 12 个碳原子的取代或未取代的芳基。J、k、m 和 n 各自独立地代表 0 或 1。
• Fluorene derivative, light-emitting element, light-emitting device, electronic device, and lighting device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US10862042B2

  公开（公告）日：2020-12-08

  An object is to provide a light-emitting element having high light-emission efficiency by provision of a novel fluorene derivative as represented by General Formula (G1) below In the formula, R1 to R8 independently represent any of a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, a substituted or unsubstituted phenyl group, or a substituted or unsubstituted biphenyl group. Further, α1 to α4 independently represent any of a substituted or unsubstituted arylene group having 6 to 12 carbon atoms. Furthermore, Ar1 and Ar2 independently represent any of an aryl group having 6 to 13 carbon atoms in a ring and Ar3 represents an alkyl group having 1 to 6 carbon atoms or a substituted or unsubstituted aryl group having 6 to 12 carbon atoms. J, k, m, and n each independently represent 0 or 1.

  目的是提供一种新型芴衍生物，如下文通式 (G1) 所示，从而提供一种具有高发光效率的发光元件 式中，R1 至 R8 独立地代表氢原子、具有 1 至 6 个碳原子的烷基、取代或未取代的苯基或取代或未取代的联苯基中的任一个。此外，α1 至 α4 独立地代表具有 6 至 12 个碳原子的取代或未取代的芳烯基团中的任一个。此外，Ar1 和 Ar2 独立地代表在环上具有 6 至 13 个碳原子的芳基，Ar3 代表具有 1 至 6 个碳原子的烷基或具有 6 至 12 个碳原子的取代或未取代的芳基。J、k、m 和 n 各自独立地代表 0 或 1。