N,N-双(水杨基)乙二胺铁(II) | 14167-12-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: N,N-双(水杨基)乙二胺铁(II)
• 中文别名: N,N'-双(水杨醛缩)乙二胺铁(II)；二水杨醛缩乙二胺铁；N,N'-双(水杨醛缩)乙二胺铁；N,N'-二水杨醛缩乙二胺铁(II)
• 英文名称: N,N'-bis(salicylidene)ethylenediamine iron(II)
• 英文别名: Fe(salen)；Fe(Salen)；N,N'-disalicyliden-ethylenediamine; iron (II)-salt；N,N'-Disalicyliden-aethylendiamin; Eisen(II)-Salz；N,N'-Bis(salicylidene)ethylenediamineIron(II)；iron(2+);2-[2-[(2-oxidophenyl)methylideneamino]ethyliminomethyl]phenolate
• CAS: 14167-12-5；578710-63-1
• 化学式: C₁₆H₁₄N₂O₂*Fe
• 分子量: 322.146
• InChiKey: AAJGISIJWYVWOG-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  1.37
• 重原子数：
  21
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  70.8
• 氢给体数：
  0
• 氢受体数：
  4

SDS

N,N'-Bis(salicylidene)ethylenediamine Iron(II) Revision number: 5
SAFETY DATA SHEET

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Section 1. IDENTIFICATION
Product name: N,N'-Bis(salicylidene)ethylenediamine Iron(II)

Revision number: 5

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Section 2. HAZARDS IDENTIFICATION
GHS classification
PHYSICAL HAZARDS Not classified
Not classified
HEALTH HAZARDS
ENVIRONMENTAL HAZARDS Not classified
GHS label elements, including precautionary statements
Pictograms or hazard symbols None
No signal word
Signal word
Hazard statements None
None
Precautionary statements:

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Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance/mixture: Substance
Components: N,N'-Bis(salicylidene)ethylenediamine Iron(II)
Percent: >95.0%(T)
CAS Number: 14167-12-5
Synonyms: N,N'-Disalicylalethylenediamine Iron(II) , N,N'-Ethylenebis(salicylideneiminato)iron(II)
Chemical Formula: C16H14FeN2O2

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Section 4. FIRST AID MEASURES
Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Get medical advice/attention if you feel unwell.
Skin contact: Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower. If skin irritation or rash occurs: Get medical advice/attention.
Eye contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice/attention.
Ingestion: Get medical advice/attention if you feel unwell. Rinse mouth.
Protection of first-aiders: A rescuer should wear personal protective equipment, such as rubber gloves and air-
tight goggles.

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Section 5. FIRE-FIGHTING MEASURES
Suitable extinguishing Dry chemical, foam, water spray, carbon dioxide.
media:
Specific hazards arising Take care as it may decompose upon combustion or in high temperatures to
from the chemical: generate poisonous fume.

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Section 5. FIRE-FIGHTING MEASURES
Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
method according to the surrounding situation is used. Uninvolved persons should
evacuate to a safe place. In case of fire in the surroundings: Remove movable
containers if safe to do so.
Special protective When extinguishing fire, be sure to wear personal protective equipment.
equipment for firefighters:

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Section 6. ACCIDENTAL RELEASE MEASURES
Use personal protective equipment. Keep people away from and upwind of spill/leak.
Personal precautions,
protective equipment and Entry to non-involved personnel should be controlled around the leakage area by
emergency procedures: roping off, etc.
Environmental precautions: Prevent product from entering drains.
Methods and materials for Sweep dust to collect it into an airtight container, taking care not to disperse it.
containment and cleaning Adhered or collected material should be promptly disposed of, in accordance with
up: appropriate laws and regulations.

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Section 7. HANDLING AND STORAGE
Precautions for safe handling
Handling is performed in a well ventilated place. Wear suitable protective equipment.
Technical measures:
Prevent dispersion of dust. Wash hands and face thoroughly after handling.
Use a local exhaust if dust or aerosol will be generated.
Advice on safe handling: Avoid contact with skin, eyes and clothing.
Conditions for safe storage, including any
incompatibilities
Storage conditions: Keep container tightly closed. Store in a cool and dark place.
Store away from incompatible materials such as oxidizing agents.
Packaging material: Comply with laws.

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Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Install a closed system or local exhaust as possible so that workers should not be
Engineering controls:
exposed directly. Also install safety shower and eye bath.
Personal protective equipment
Respiratory protection: Dust respirator. Follow local and national regulations.
Hand protection: Protective gloves.
Eye protection: Safety glasses. A face-shield, if the situation requires.
Skin and body protection: Protective clothing. Protective boots, if the situation requires.

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Section 9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state (20°C): Solid
Form: Crystal- Powder
Colour: Yellow - Deep yellow red
Odour: No data available
pH: No data available
Melting point/freezing point:No data available
No data available
Boiling point/range:
Flash point: No data available
Flammability or explosive
limits:
No data available
Lower:
Upper: No data available
No data available
Relative density:
Solubility(ies):
No data available
[Water]
[Other solvents] No data available

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Section 10. STABILITY AND REACTIVITY
Chemical stability: Stable under proper conditions.
Possibility of hazardous No special reactivity has been reported.
reactions:
Incompatible materials: Oxidizing agents
Hazardous decomposition Carbon monoxide, Carbon dioxide, Nitrogen oxides (NOx)
products:

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Section 11. TOXICOLOGICAL INFORMATION
No data available
Acute Toxicity:
Skin corrosion/irritation: No data available
No data available
Serious eye
damage/irritation:
Germ cell mutagenicity: No data available
Carcinogenicity:
IARC = No data available
NTP = No data available
No data available
Reproductive toxicity:

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Section 12. ECOLOGICAL INFORMATION
Ecotoxicity:
No data available
Fish:
Crustacea: No data available
Algae: No data available
Persistence / degradability: No data available
Bioaccumulative No data available
potential(BCF):
Mobility in soil
Log Pow: No data available
No data available
Soil adsorption (Koc):
Henry's Law No data available
constant(PaM3/mol):

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Section 13. DISPOSAL CONSIDERATIONS
Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material
with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system.
Observe all federal, state and local regulations when disposing of the substance.

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Section 14. TRANSPORT INFORMATION
Hazards Class: Does not correspond to the classification standard of the United Nations
Not listed
UN-No:

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Section 15. REGULATORY INFORMATION
Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002
and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport,
loading and unloading were prescribed.

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SECTION 16 - ADDITIONAL INFORMATION
N/A

反应信息

• 作为反应物：
  描述：

  N,N-双(水杨基)乙二胺铁(II) 、 乙硫醇钠 以 乙腈 为溶剂， 以30-40的产率得到Na{Fe(salen)(SEt)}
  参考文献：
  名称：

  Mukherjee; Abrahamson; Patterson, Inorganic Chemistry, 1988, vol. 27, # 12, p. 2137 - 2144

  摘要：

  DOI：
• 作为产物：
  描述：

  di-(n-butylsalicylaldimino)nickel(II) 以 吡啶 、 氯仿 为溶剂， 生成 N,N-双(水杨基)乙二胺铁(II)
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ni: MVol.C2, 7.6, page 689 - 698

  摘要：

  DOI：
• 作为试剂：
  描述：

  环己烯 在 叔丁基过氧化氢 、 N,N-双(水杨基)乙二胺铁(II) 作用下， 以 苯 为溶剂， 反应 6.0h， 生成 2-环己烯-1-酮 、 氧化环己烯 、 2-环己烯醇
  参考文献：
  名称：

  Synthesis, characterization and catalytic activity of Fe(Salen) intercalated α-zirconium phosphate for the oxidation of cyclohexene

  摘要：

  Iron(III)-Salen intercalated et-zirconium phosphate. abbreviated as {alpha-ZrP center dot Fe(Salen)} was synthesized in situ by the flexible ligand method. The resulting compound was characterized by BET surface area. X-ray diffraction, scanning electron microscopy, energy dispersive X-ray analysis, Fourier transform infrared. Mossbauer and atomic absorption spectroscopy. The catalytic activity of alpha-ZrP center dot Fe(Salen) with dry tert-butylhydroperoxide (TBHP) as an oxidant was studied for oxidation of cyclohexene. In the oxidation reaction, cyclohexene was oxidized to cyclohexene oxide. cyclohexenol and cyclohexenone. A maximum conversion of 18.04% for the oxidation of cyclohexene was observed after 5 h of reaction when concentrations of the catalyst, the substrate and the oxidant were 0.20, 20 and 4 mmol respectively. The catalyst. alpha-ZrP center dot Fe(Salen) was recycled for eight cycles. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2011.05.005

文献信息

• Formation in solution, synthesis, and electrochemical study of oxalato complexes of N,N′-ethylenebis(salicylideneiminato)-chromium(<scp>III</scp>) and -iron(<scp>III</scp>): crystal structures of piperidinium [N,N′-ethylenebis(salicylideneiminato)](oxalato-O¹O²)-chromate(<scp>III</scp>) and ferrate(<scp>III</scp>)
  作者：Francesc Lloret、Miguel Julve、Miquel Mollar、Isabel Castro、Julio Latorre、Juan Faus、Xavier Solans、Irène Morgenstern-Badarau

  DOI：10.1039/dt9890000729

  日期：——

  Both structures consist of [M (salen)(ox)]– mononuclear anions and piperidinium cations. The presence of the bidentate oxalate ligand in both complexes forces the salen ligand to adopt the non-planar cis-β configuration. The metal ions exhibit distorted octahedral geometry with the two co-ordinated oxygen atoms of the oxalate ligand and an oxygen and a nitrogen atom from the salen defining the best

  两种新的式[Hpip] [M（salen）（ox）] [M = Cr III（1）或Fe III（2）]和双核[Fe 2（salen）2（ox）]·H 2的单核络合物O，（3），其中Hpip ＝哌啶鎓，salen ＝N，N′-亚乙基双（水杨基亚硝酸根）和ox ＝草酸酯。化合物（1）和（2）是等结构的单斜空间群P 2 1 / n，Z = 4，其中a = 24.425（3），b = 6.847（1），c对于（1）和a = 24.363（4），b = 6.991（2），c = 14.105（3）Å，β= 98.76（2）° ，= 14.271（2）Å，β= 100.95（2）°为（2）。的结构（1）通过直接法解析，而该的（2）通过从（所述坐标同晶置换解决1）。两种结构均由[M（salen）（ox）] –单核阴离子和哌啶鎓阳离子组成。两个复合物中二齿草酸盐配体的存在迫使salen配体采用非平面顺式
• Pfeiffer, P.; Thielert, H.; Glaser, H., 1939, vol. 152, p. 145 - 156
  作者：Pfeiffer, P.、Thielert, H.、Glaser, H.

  DOI：——

  日期：——
• Dailey, Gregory C.; Horwitz, Colin P., Inorganic Chemistry, 1992, vol. 31, # 18, p. 3693 - 3694
  作者：Dailey, Gregory C.、Horwitz, Colin P.

  DOI：——

  日期：——
• Dailey, Gregory C.; Horwitz, Colin P., Inorganic Chemistry, <hi>1992</hi>, vol. 31, # 18, p. 3693 - 3694
  作者：Dailey, Gregory C.、Horwitz, Colin P.

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ni: MVol.C2, 7.6, page 689 - 698
  作者：

  DOI：——

  日期：——