bis(2-(diisobutylphosphino)phenyl)amine | 848309-76-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(2-(diisobutylphosphino)phenyl)amine
• 英文别名: bis(2-(diisobutykphosphino)phenyl)amine；2-[bis(2-methylpropyl)phosphanyl]-N-[2-[bis(2-methylpropyl)phosphanyl]phenyl]aniline
• CAS: 848309-76-2
• 化学式: C₂₈H₄₅NP₂
• 分子量: 457.62
• InChiKey: SAEVULJJIOKHAB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.9
• 重原子数：
  31
• 可旋转键数：
  12
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  mesitylcopper(I) 、 bis(2-(diisobutylphosphino)phenyl)amine 以 not given 为溶剂， 生成 [Cu(bis(2-diisobutylphosphinophenyl)amide)]2
  参考文献：
  名称：

  A Highly Emissive Cu₂N₂ Diamond Core Complex Supported by a [PNP]^- Ligand

  摘要：

  A Cu2N2 diamond core structure, {(PNP)CuI}2 (2), supported by a [PNP]- ligand (1) ([PNP]- = bis(2-(diisobutylphosphino)phenyl)amide) has been prepared. 2 is highly emissive at ambient temperature in both the solid and solution states and is characterized by a relatively long-lived excited state (tau > 10 mus) and an unusually high quantum yield (phi > 0.65). These observations are consistent with a low degree of structural reorganization between the ground state of 2 and its excited state *2, and also with a high degree of steric protection of the two copper centers of 2 afforded by the bulky [PNP]- ligand. An estimate for the excited-state reduction potential of *2 (ca. -3.2 V vs Fc+/Fc), and the availability of two well-separated and reversible ground-state redox processes, suggests that bimetallic copper systems of these types may be interesting candidates to consider for photochemically driving multielectron redox transformations.

  DOI：

  10.1021/ja043092r
• 作为产物：
  描述：

  二异丁基膦 在 正丁基锂 作用下， 以 四氢呋喃 、 正己烷 、 Petroleum ether 为溶剂， 反应 120.25h， 生成 bis(2-(diisobutylphosphino)phenyl)amine
  参考文献：
  名称：

  A Highly Emissive Cu₂N₂ Diamond Core Complex Supported by a [PNP]^- Ligand

  摘要：

  A Cu2N2 diamond core structure, {(PNP)CuI}2 (2), supported by a [PNP]- ligand (1) ([PNP]- = bis(2-(diisobutylphosphino)phenyl)amide) has been prepared. 2 is highly emissive at ambient temperature in both the solid and solution states and is characterized by a relatively long-lived excited state (tau > 10 mus) and an unusually high quantum yield (phi > 0.65). These observations are consistent with a low degree of structural reorganization between the ground state of 2 and its excited state *2, and also with a high degree of steric protection of the two copper centers of 2 afforded by the bulky [PNP]- ligand. An estimate for the excited-state reduction potential of *2 (ca. -3.2 V vs Fc+/Fc), and the availability of two well-separated and reversible ground-state redox processes, suggests that bimetallic copper systems of these types may be interesting candidates to consider for photochemically driving multielectron redox transformations.

  DOI：

  10.1021/ja043092r

文献信息

• ORGANIC LIGHT EMITTING DEVICES WITH DINUCLEAR COPPER COMPOUNDS
  申请人：Eastman Kodak Company

  公开号：EP1948756A1

  公开（公告）日：2008-07-30
• Oled devices with dinuclear copper compounds
  申请人：Deaton C. Joseph

  公开号：US20070111026A1

  公开（公告）日：2007-05-17

  An OLED device comprises an anode, a cathode and therebetween a light emitting layer containing a compound represented by Formula I below: wherein: each A is independently selected from N and P; each E is independently selected from N, P, and As; each Z is a radical independently selected from each R is an independently selected substituent; and each R′ is independently selected from H and a substituent; provided that two substituent groups can join to form a ring.
• US7462406B2
  申请人：——

  公开号：US7462406B2

  公开（公告）日：2008-12-09
• [EN] ORGANIC LIGHT EMITTING DEVICES WITH DINUCLEAR COPPER COMPOUNDS<br/>[FR] DISPOSITIFS A DIODES ELECTROLUMINESCENTES ORGANIQUES (OLED) PRESENTANT DES COMPOSES DE CUIVRE DINUCLEAIRES
  申请人：EASTMAN KODAK CO

  公开号：WO2007059024A1

  公开（公告）日：2007-05-24

  [EN] An OLED device comprises an anode, a cathode and therebetween a light emitting layer containing a compound represented by Formula (I) below: wherein: each A is independently selected from N and P; each E is independently selected from N, P, and As; each Z is a radical independently selected from Formula (AA) and Formula (BB); each R is an independently selected substituent; and each R' is independently selected from H and a substituent; provided that two substituent groups can join to form a ring.
  [FR] L'invention concerne un dispositif OLED comprenant une anode, une cathode, et une couche électroluminescente située entre l'anode et la cathode, laquelle couche contenant un composé de formule (I). Dans cette formule, chaque A est indépendamment sélectionné parmi N et P; chaque E est indépendamment sélectionné parmi N, P et As; chaque Z désigne un radical indépendamment sélectionné parmi la formule (AA) et la formule (BB); chaque R désigne un substituant indépendamment sélectionné; et chaque R' est indépendamment sélectionné parmi H et un substituant; à condition que deux groupes de substitution puissent se joindre pour former un anneau.
• A Highly Emissive Cu₂N₂ Diamond Core Complex Supported by a [PNP]^- Ligand
  作者：Seth B. Harkins、Jonas C. Peters

  DOI：10.1021/ja043092r

  日期：2005.2.1

  A Cu2N2 diamond core structure, (PNP)CuI}2 (2), supported by a [PNP]- ligand (1) ([PNP]- = bis(2-(diisobutylphosphino)phenyl)amide) has been prepared. 2 is highly emissive at ambient temperature in both the solid and solution states and is characterized by a relatively long-lived excited state (tau > 10 mus) and an unusually high quantum yield (phi > 0.65). These observations are consistent with a low degree of structural reorganization between the ground state of 2 and its excited state *2, and also with a high degree of steric protection of the two copper centers of 2 afforded by the bulky [PNP]- ligand. An estimate for the excited-state reduction potential of *2 (ca. -3.2 V vs Fc+/Fc), and the availability of two well-separated and reversible ground-state redox processes, suggests that bimetallic copper systems of these types may be interesting candidates to consider for photochemically driving multielectron redox transformations.