8-ethyl-3-hydroxy-N-(2-methoxy-1-methylethyl)-2-oxo-1,2,3,4-tetrahydroquinolinen | 65513-63-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 8-ethyl-3-hydroxy-N-(2-methoxy-1-methylethyl)-2-oxo-1,2,3,4-tetrahydroquinolinen
• 英文别名: 8-Ethyl-3-hydroxy-1-(1-methoxypropan-2-yl)-3,4-dihydroquinolin-2-one；8-ethyl-3-hydroxy-1-(1-methoxypropan-2-yl)-3,4-dihydroquinolin-2-one
• CAS: 65513-63-5
• 化学式: C₁₅H₂₁NO₃
• 分子量: 263.337
• InChiKey: RHYZCIHCYCZSPP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  19
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.53
• 拓扑面积：
  49.8
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  异丙甲草胺 在 kaolin 、 水 作用下， 反应 2.0h， 以54.7%的产率得到4-(2-乙基-6-甲基苯基)-5-甲基吗啉-3-酮
  参考文献：
  名称：

  Photodegradation of Metolachlor in Water in the Presence of Soil Mineral and Organic Constituents

  摘要：

  Photodegradation of metolachlor [2-chloro-N-(2-ethyl-6-methylphenyl)-N-(2-methoxy-1-methylethyl)--acetamide] at 253.7 nm was carried out in water containing soil minerals (kaolinite, montmorillonite, and goethite) and fulvic acid under two different pH conditions. The rate of photolysis was dependent on the nature of the soil constituents and the initial pH of the medium. Based on the regression analysis, it was shown that the photodegradation followed the first-order kinetics with respect to the metolachlor concentration, and the half-life of the herbicide under UV irradiation was longer in the absence of soil constituents. Hydroxylation, dehalogenation, oxoquinoline formation, and demethylation were the main processes observed during the photolysis of metolachlor. More degradation products were formed in the presence of kaolinite, montmorillonite, and goethite than with fulvic acid and water alone. The major degradation product formed under UV irradiation in all the treatments was identified as 4-(2-ethyl-6-methylphenyl)-5-methyl-3-morpholine.

  DOI：

  10.1021/jf960123w

文献信息

• Photodegradation of Metolachlor in Water in the Presence of Soil Mineral and Organic Constituents
  作者：Regi Mathew、Shahamat U. Khan

  DOI：10.1021/jf960123w

  日期：1996.1.1

  Photodegradation of metolachlor [2-chloro-N-(2-ethyl-6-methylphenyl)-N-(2-methoxy-1-methylethyl)--acetamide] at 253.7 nm was carried out in water containing soil minerals (kaolinite, montmorillonite, and goethite) and fulvic acid under two different pH conditions. The rate of photolysis was dependent on the nature of the soil constituents and the initial pH of the medium. Based on the regression analysis, it was shown that the photodegradation followed the first-order kinetics with respect to the metolachlor concentration, and the half-life of the herbicide under UV irradiation was longer in the absence of soil constituents. Hydroxylation, dehalogenation, oxoquinoline formation, and demethylation were the main processes observed during the photolysis of metolachlor. More degradation products were formed in the presence of kaolinite, montmorillonite, and goethite than with fulvic acid and water alone. The major degradation product formed under UV irradiation in all the treatments was identified as 4-(2-ethyl-6-methylphenyl)-5-methyl-3-morpholine.