N-(2-甲氧基苯基)-2-苯基苯胺 | 118987-68-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: N-(2-甲氧基苯基)-2-苯基苯胺
• 英文名称: 2-o-anisidinobiphenyl
• 英文别名: 2-methoxy-2'-phenyldiphenylamine；N-(2-Methoxyphenyl)[1,1'-biphenyl]-2-amine；N-(2-methoxyphenyl)-2-phenylaniline
• CAS: 118987-68-1
• 化学式: C₁₉H₁₇NO
• 分子量: 275.35
• InChiKey: OVAXUXVHYUERAA-UHFFFAOYSA-N

物化性质

• 沸点：
  417.9±38.0 °C(Predicted)
• 密度：
  1.124±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  21
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  21.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-溴苯甲醚 、 2-氨基联苯 在 palladium diacetate 、 P(i-BuNCH₂CH₂)3N 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 以93%的产率得到N-(2-甲氧基苯基)-2-苯基苯胺
  参考文献：
  名称：

  P（i-BuNCH2CH2）3N：钯催化的芳基溴化物和碘化物胺化反应中的有效配体。

  摘要：

  结果表明，双环三氨基膦P（i-BuNCH2CH2）3N可作为钯催化的各种芳基溴化物和碘化物的胺化反应的有效配体。其他双环或无环三氨基膦，甚至那些具有相似碱度和/或体积的三氨基膦也较差。

  DOI：

  10.1021/jo0205309

文献信息

• The reaction of ortho-substituted aromatic azides with boron trichloride or trifluoride
  作者：Piero Spagnolo、Paolo Zanirato

  DOI：10.1039/p19880002615

  日期：——

  The reaction of boron trichloride or trifuoride with ortho-aryl, -diazoaryl, and -arylazoaryl phenyl azides in benzene at room temperature generally gives fused azoles in high yields. Treatment of 2-nitrophenyl azide with boron trichloride mainly affords chlorinated nitroanilines, whereas with boron trifluoride it gives N-o-nitrophenylaniline. In aromatic solvents at 60 °C in the presence of boron trifluoride–diethyl

  在室温下，三氯化硼或三氟硼化物与邻-芳基，-重氮芳基和-芳基偶氮芳基苯基叠氮化物在苯中的反应通常以高收率得到稠合的唑。用三氯化硼2-硝基苯基叠氮化物的治疗主要得到氯化硝基苯胺，而用三氟化硼它给ñ - Ö -nitrophenylaniline。在60°C的芳族溶剂中，在三氟化硼-乙醚的存在下，2-叠氮基联苯形成咔唑和2-（芳基氨基）联苯，其形成很大程度上取决于所用溶剂的亲核性。然而，它的伪一级分解率是在苯比在甲苯或稍大米二甲苯。在相同条件下，苯叠氮化物形成二芳基胺。
• TRANSITION METAL CATALYTIC SYSTEMS AND METHODS FOR PREPARING ETHYLENE HOMOPOLYMERS OR COPOLYMERS OF ETHYLENE AND OLEFINS USING THE SAME
  申请人：Ok Myung Ahn

  公开号：US20100048840A1

  公开（公告）日：2010-02-25

  Disclosed herein is a group IV transition metal catalyst for producing an ethylene homopolymer or an ethylene-olefin copolymers, having high catalytic activity, which includes a cyclopentadiene derivative and one or more anionic ligands having an aryl group substituted with an aryl derivative at an ortho-position thereof around a transition metal, the ligands not being crosslinked to each other, a catalyst system including the group IV transition metal catalyst and an aluminoxane cocatalyst or a boron compound cocatalyst, and a method of producing ethylene homopolymers or ethylene-olefin copolymers using the catalyst system.

  本文披露了一种用于生产乙烯均聚物或乙烯-烯烃共聚物的IV族过渡金属催化剂，具有高催化活性，包括一种环戊二烯衍生物和一个或多个带有芳基取代物的阴离子配体，其在过渡金属周围的邻位处与芳基衍生物进行取代，这些配体之间没有交联，一个包括IV族过渡金属催化剂和氧化铝烷共催化剂或硼化合物共催化剂的催化剂系统，以及使用该催化剂系统生产乙烯均聚物或乙烯-烯烃共聚物的方法。
• Transition metal catalytic systems and methods for preparing ethylene homopolymers or copolymers of ethylene and olefins using the same
  申请人：Ok Myung Ahn

  公开号：US08742043B2

  公开（公告）日：2014-06-03

  Disclosed herein is a group IV transition metal catalyst for producing an ethylene homopolymer or an ethylene-olefin copolymers, having high catalytic activity, which includes a cyclopentadiene derivative and one or more anionic ligands having an aryl group substituted with an aryl derivative at an ortho-position thereof around a transition metal, the ligands not being crosslinked to each other, a catalyst system including the group IV transition metal catalyst and an aluminoxane cocatalyst or a boron compound cocatalyst, and a method of producing ethylene homopolymers or ethylene-olefin copolymers using the catalyst system.

  本文公开了一种IV族过渡金属催化剂，用于生产具有高催化活性的乙烯均聚物或乙烯-烯烃共聚物，包括一个环戊二烯衍生物和一个或多个阴离子配体，其在过渡金属周围的芳基团上取代了一个芳基衍生物，配体之间不交联，催化剂体系包括IV族过渡金属催化剂和氧化铝烷协同催化剂或硼化合物协同催化剂，以及使用该催化剂体系生产乙烯均聚物或乙烯-烯烃共聚物的方法。
• A Fully Integrated High-Throughput Screening Methodology for the Discovery of New Polyolefin Catalysts:  Discovery of a New Class of High Temperature Single-Site Group (IV) Copolymerization Catalysts
  作者：Thomas R. Boussie、Gary M. Diamond、Christopher Goh、Keith A. Hall、Anne M. LaPointe、Margarete Leclerc、Cheryl Lund、Vince Murphy、James A. W. Shoemaker、Ursula Tracht、Howard Turner、Jessica Zhang、Tetsuo Uno、Robert K. Rosen、James C. Stevens

  DOI：10.1021/ja020868k

  日期：2003.4.1

  For the first time, new catalysts for olefin polymerization have been discovered through the application of fully integrated high-throughput primary and secondary screening techniques supported by rapid polymer characterization methods. Microscale 1-octene primary screening polymerization experiments combining arrays of ligands with reactive metal complexes M(CH2Ph)(4) (M = Zr, Hf) and multiple activation conditions represent a new high-throughput technique for discovering novel group (IV) polymerization catalysts. The primary screening methods described here have been validated using a commercially relevant polyolefin catalyst, and implemented rapidly to discover the new amide-ether based hafnium catalyst [eta(2)-(N,O)-(2-MeO-C6H4)(2,4,6-Me3C6H2)N]Hf(CH2Ph)(3) (1), which is capable of polymerizing 1-octene to high conversion. The molecular structure of I has been determined by X-ray diffraction. Larger scale secondary screening experiments performed on a focused 96-member amine-ether library demonstrated the versatile high temperature ethylene-1-octene copolymerization capabilities of this catalyst class, and led to significant performance improvements over the initial primary screening discovery. Conventional one gallon batch reactor copolymerizations performed using selected amide-ether hafnium compounds confirmed the performance features of this new catalyst class, serving to fully validate the experimental results from the high-throughput approaches described herein.
• SPAGNOLO, PIERO;ZANIRATO, PAOLO, J. CHEM. SOC. PERKIN TRANS. PT I,(1988) N 9, C. 2615-2620
  作者：SPAGNOLO, PIERO、ZANIRATO, PAOLO

  DOI：——

  日期：——