2-benzoyl-1,3-cyclopentanedione | 73599-72-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-benzoyl-1,3-cyclopentanedione
• 英文别名: 2-benzoylcyclopentane-1,3-dione；2-benzoyl-1,3-cyclopentanedion
• CAS: 73599-72-1
• 化学式: C₁₂H₁₀O₃
• 分子量: 202.21
• InChiKey: JRIKYQQBGJNJMP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  51.2
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-benzoyl-1,3-cyclopentanedione 在 草酰氯 作用下， 以 氯仿 为溶剂， 反应 2.0h， 生成 2-benzoyl-3-(4-fluorobenzylamino)-2-cyclopenten-1-one
  参考文献：
  名称：

  Preparation of fluorine-containing exo- and endocyclic enamine derivatives of 2-acylcyclopentane-1,3-diones

  摘要：

  The interaction of aromatic amines (4-fluorinebenzylamine, 3-trifluoromethylbenzylamine, 4-fluoroaniline, or 3,4-difluoroaniline) with either 2-acylcyclopentane-1,3-diones (fluorine-substituted or fluorine-free) or their enol derivatives (chlorovinyldiketones) has led to fluorine-containing exo- or endocyclic enamine derivatives of 2-acylcyclopentane-1,3-diones.

  DOI：

  10.1134/s1070363214030098
• 作为产物：
  描述：

  1,3-环戊二酮 在 吡啶 、 三乙胺 、 丙酮氰醇 作用下， 以 氯仿 、 乙腈 为溶剂， 反应 16.0h， 生成 2-benzoyl-1,3-cyclopentanedione
  参考文献：
  名称：

  Preparation of fluorine-containing exo- and endocyclic enamine derivatives of 2-acylcyclopentane-1,3-diones

  摘要：

  The interaction of aromatic amines (4-fluorinebenzylamine, 3-trifluoromethylbenzylamine, 4-fluoroaniline, or 3,4-difluoroaniline) with either 2-acylcyclopentane-1,3-diones (fluorine-substituted or fluorine-free) or their enol derivatives (chlorovinyldiketones) has led to fluorine-containing exo- or endocyclic enamine derivatives of 2-acylcyclopentane-1,3-diones.

  DOI：

  10.1134/s1070363214030098

文献信息

• Lakhvich, F. A.; Khlebnikova, T. S.; Akhrem, A. A., Journal of Organic Chemistry USSR (English Translation), 1989, vol. 25, # 12.1, p. 2280 - 2286
  作者：Lakhvich, F. A.、Khlebnikova, T. S.、Akhrem, A. A.

  DOI：——

  日期：——
• Platinum(II) cationic complexes with derivatives of 2-acyl-1,3-cyclopentanedions
  作者：T. S. Khlebnikova、I. V. Merkushin、F. A. Lakhvich

  DOI：10.1134/s107036320605001x

  日期：2006.5

  cis-Diammineplatinum(II) complexes containing 2-acyl-1,3-cyclopentadion fragments as a bidentate acido ligand were prepared by the transformation of cis-diamminediiodoplatinum(II) to cis-diamminesulfatoplatinum(II) under the action of silver sulfate with the subsequent treatment of the resulting complex by barium hydroxide and by the reaction of the synthesized base with a twofold amount of 2-acyl-1,3-cyclopentanedion. The products are the cationic complexes of cis-diammineplatinum(II) and contain 2-acyl-1,3-cyclopentanedionate as a bidentate acido ligand, which chelates platinum atom by the carbonyl groups of side acyl chain and one group connected with five-membered cycle, whereas a 2-acyl-1,3-cyclopentadion enolate anion forms counter ion.
• LAXVICH, F. A.;XLEBNIKOVA, T. S.;AXREM, A. A., ZH. ORGAN. XIMII, 25,(1989) N2, S. 2541-2549
  作者：LAXVICH, F. A.、XLEBNIKOVA, T. S.、AXREM, A. A.

  DOI：——

  日期：——