marliolide | 111900-39-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 内酯类
• 英文名称: marliolide
• 英文别名: (3E,4R,5R)-4-hydroxy-5-methyl-3-tetradecylideneoxolan-2-one
• CAS: 111900-39-1
• 化学式: C₁₉H₃₄O₃
• 分子量: 310.477
• InChiKey: KBHLNNQHHPFDSG-VTGIHGMASA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  22
• 可旋转键数：
  12
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.84
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  marliolide 在 (R)-methoxytrifluoromethylphenylacetyl chloride 、 水 作用下， 以93%的产率得到2-hydroxy-5-methyl-3-[1-tridecanol]-furan
  参考文献：
  名称：

  Chemical constituents of two Mollinedia species

  摘要：

  A butanolide, marliolide, was isolated from the hexane extract of leaves of Mollinedia marliae (Monimiacae) along with the long chain fatty alcohol hexacosanol. Phytol and a mixture of sitosterol and stigmasterol were also isolated from leaves of both M. marliae and M. gilgiana, trans-N-Feruloyltyramine, a ferulic acid derivative, is the major constituent of the stems of M. gilgiana. (C) 2000 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0031-9422(00)00294-6
• 作为产物：
  描述：

  (3E,4R,5R)-4-[(4-methoxyphenyl)methoxy]-5-methyl-3-tetradecylideneoxolan-2-one 生成 marliolide
  参考文献：
  名称：

  WOOD, WILLIAM W.;WATSON, GRAHAM M., J. CHEM. SOC. PERKIN TRANS., 1,(1987) N 12, 2681-2688

  摘要：

  DOI：

文献信息

• WOOD, WILLIAM W.;WATSON, GRAHAM M., J. CHEM. SOC. PERKIN TRANS., 1,(1987) N 12, 2681-2688
  作者：WOOD, WILLIAM W.、WATSON, GRAHAM M.

  DOI：——

  日期：——
• Chemical constituents of two Mollinedia species
  作者：Boris M.G Claros、Antonio J.R da Silva、Mario L.A.A Vasconcellos、Ana Paula P de Brito、Gilda G Leitão

  DOI：10.1016/s0031-9422(00)00294-6

  日期：2000.12

  A butanolide, marliolide, was isolated from the hexane extract of leaves of Mollinedia marliae (Monimiacae) along with the long chain fatty alcohol hexacosanol. Phytol and a mixture of sitosterol and stigmasterol were also isolated from leaves of both M. marliae and M. gilgiana, trans-N-Feruloyltyramine, a ferulic acid derivative, is the major constituent of the stems of M. gilgiana. (C) 2000 Elsevier Science Ltd. All rights reserved.