(E)-5-chloro-4-nonene | 78074-79-0

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: (E)-5-chloro-4-nonene
• 英文别名: (E)-5-chloronon-4-ene
• CAS: 78074-79-0
• 化学式: C₉H₁₇Cl
• 分子量: 160.687
• InChiKey: CESRKUUAXLWZHZ-VQHVLOKHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  10
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  (E)-5-chloro-4-nonene 、 ethyl N-{[(4-nitrobenzene)sulfonyl]oxy}carbamate 生成 ethyl (2R,3R)-2-butyl-2-chloro-3-propylaziridine-1-carboxylate
  参考文献：
  名称：

  PELLACANI L.; PERSIA F.; TARDELLA P. A., TETRAHEDRON LETT., 1980, 21, NO 51, 4967-4970

  摘要：

  DOI：
• 作为产物：
  描述：

  5-trifluoromethanesulfonyloxy-4-nonene 在 [Cp*Ru(CH3CN)3]OTf 、 lithium chloride 作用下， 以 四氢呋喃 为溶剂， 反应 1.5h， 以96%的产率得到(E)-5-chloro-4-nonene
  参考文献：
  名称：

  Ruthenium-Catalyzed Transformation of Aryl and Alkenyl Triflates to Halides

  摘要：

  Aryl triflates were transformed to aryl bromides/iodides simply by treating them with LiBr/NaI and [Cp*Ru(MeCN)(3)]OTf. The ruthenium complex also catalyzed the transformation of alkenyl sulfonates and phosphates to alkenyl halides under mild conditions. Aryl and alkenyl triflates undergo oxidative addition to a ruthenium(II) complex to form eta(1)-arylruthenium and 1-ruthenacyclopropene intermediates, respectively, which are transformed to the corresponding halides.

  DOI：

  10.1021/ja307771d

文献信息

• Ethoxycarbonylnitrene addition to vinyl chlorides. Synthesis and thermal rearrangement of α-chloroaziridines
  作者：Lucio Pellacani、Franca Persia、Paolo A. Tardella

  DOI：10.1016/s0040-4039(00)71167-1

  日期：1980.1

  The addition of ethoxycarbonylnitrene to vinyl chlorides gives N-ethoxycarbonyl-α-chloroaziridines which undergo an easy rearrangement mainly or exclusively to N-ethoxycarbonyl-2-chloro-2-alkenylamines.

  将乙氧基羰基氮烯加到氯乙烯中得到的N-乙氧基羰基-α-氯氮丙啶主要或仅容易地重排成N-乙氧基羰基-2-氯-2-链烯基胺。
• Ruthenium-Catalyzed Transformation of Aryl and Alkenyl Triflates to Halides
  作者：Yusuke Imazaki、Eiji Shirakawa、Ryota Ueno、Tamio Hayashi

  DOI：10.1021/ja307771d

  日期：2012.9.12

  Aryl triflates were transformed to aryl bromides/iodides simply by treating them with LiBr/NaI and [Cp*Ru(MeCN)(3)]OTf. The ruthenium complex also catalyzed the transformation of alkenyl sulfonates and phosphates to alkenyl halides under mild conditions. Aryl and alkenyl triflates undergo oxidative addition to a ruthenium(II) complex to form eta(1)-arylruthenium and 1-ruthenacyclopropene intermediates, respectively, which are transformed to the corresponding halides.
• PELLACANI L.; PERSIA F.; TARDELLA P. A., TETRAHEDRON LETT., 1980, 21, NO 51, 4967-4970
  作者：PELLACANI L.、 PERSIA F.、 TARDELLA P. A.

  DOI：——

  日期：——