1-phenyl-11H-benzo[a]chryseno[5,6-c]carbazole | 1337901-85-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 1-phenyl-11H-benzo[a]chryseno[5,6-c]carbazole
• 英文别名: 10-Phenyl-26-azaoctacyclo[16.15.0.02,11.03,8.012,17.019,27.020,25.028,33]tritriaconta-1(18),2(11),3,5,7,9,12,14,16,19(27),20,22,24,28,30,32-hexadecaene
• CAS: 1337901-85-5
• 化学式: C₃₈H₂₃N
• 分子量: 493.607
• InChiKey: BZUQDQOCFGOEKG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.3
• 重原子数：
  39
• 可旋转键数：
  1
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  15.8
• 氢给体数：
  1
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  2-[(2-ethynylphenyl)ethynyl]aniline 在 bis-triphenylphosphine-palladium(II) chloride 、 copper(l) iodide 、 silver tetrafluoroborate 、 氯[2-二环己基(2',4',6'-三异丙基联苯基)膦]金(I) 、 四丁基氟化铵 、 三乙胺 作用下， 以 四氢呋喃 、 乙醇 为溶剂， 反应 10.5h， 生成 1-phenyl-11H-benzo[a]chryseno[5,6-c]carbazole
  参考文献：
  名称：

  Gold(I)-Catalyzed Polycyclizations of Polyenyne-Type Anilines Based on Hydroamination and Consecutive Hydroarylation Cascade

  摘要：

  A hydroamination-double hydroarylation cascade using aniline derivatives bearing a trienyne moiety as the substrate was efficiently promoted by a gold(I) catalyst to produce benzo[a]naphtho [2,1-c]carbazole derivatives in good yields. This reaction is applicable to various substituted trienyne-type anilines, including 2,3-diethynylthiophene derivatives. The reaction of anilines bearing a tetraenyne and pentaenyne moiety allows direct construction of highly fused carbazoles by tetra- and pentacyclization, respectively, through hydroamination and consecutive hydroarylation without producing any theoretical waste products from the substrates.

  DOI：

  10.1021/jo2018119

文献信息

• [EN] NITROGEN-CONTAINING HETEROCYCLIC COMPOUNDS AND ORGANIC ELECTROLUMINESCENCE DEVICES CONTAINING THEM<br/>[FR] COMPOSÉS HÉTÉROCYCLIQUES AZOTÉS ET DISPOSITIFS ÉLECTROLUMINESCENTS ORGANIQUES CONTENANT CEUX-CI
  申请人：IDEMITSU KOSAN CO

  公开号：WO2017109722A1

  公开（公告）日：2017-06-29

  The present invention relates to compounds of the general formula (11), to a material for an organic electroluminescence device comprising ot least one of these compounds, to an organic electroluminescence device comprising at least one of these compounds, and to the use of a compound according to general formula (11) in an organic electroluminescence device as a host material or an electron transporting material.

  本发明涉及通式（11）的化合物，涉及包含至少其中一种化合物的有机电致发光器件材料，涉及包含至少其中一种化合物的有机电致发光器件，以及涉及将通式（11）的化合物用作有机电致发光器件中的主体材料或电子传输材料。
• ORGANIC LIGHT EMITTING DEVICE AND COMPOUNDS FOR USE IN SAME
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：US20200227652A1

  公开（公告）日：2020-07-16

  Specific polycyclic compounds of the general formula (I) and a process for its preparation, an electronic device comprising at least one of these compounds, an emitting layer, preferably present in an electronic device, comprising at least one compound of general formula (I) and the use of compounds according to general formula (I) in an electronic device as a host material, a charge transporting material, charge and/or exciton blocking material, preferably as a host material or an electron transporting material.

  本发明涉及一种通式（I）的特定多环化合物及其制备方法，包括至少一种这些化合物的电子器件，包括至少一种通式（I）的化合物的发射层，通常存在于电子器件中，以化合物通式（I）在电子器件中作为主体材料、电荷传输材料、电荷和/或激子阻挡材料的用途，通常作为主体材料或电子传输材料。
• NITROGEN-CONTAINING HETEROCYCLIC COMPOUNDS AND ORGANIC ELECTROLUMINESCENCE DEVICES CONTAINING THEM
  申请人：Idemitsu Kosan Co., Ltd

  公开号：US20190006601A1

  公开（公告）日：2019-01-03

  The present invention relates to compounds of the general formula (11), to a material for an organic electroluminescence device comprising of least one of these compounds, to an organic electroluminescence device comprising at least one of these compounds, and to the use of a compound according to general formula (11) in an organic electroluminescence device as a host material or an electron transporting material.
• Gold(I)-Catalyzed Polycyclizations of Polyenyne-Type Anilines Based on Hydroamination and Consecutive Hydroarylation Cascade
  作者：Kimio Hirano、Yusuke Inaba、Kiyosei Takasu、Shinya Oishi、Yoshiji Takemoto、Nobutaka Fujii、Hiroaki Ohno

  DOI：10.1021/jo2018119

  日期：2011.11.4

  A hydroamination-double hydroarylation cascade using aniline derivatives bearing a trienyne moiety as the substrate was efficiently promoted by a gold(I) catalyst to produce benzo[a]naphtho [2,1-c]carbazole derivatives in good yields. This reaction is applicable to various substituted trienyne-type anilines, including 2,3-diethynylthiophene derivatives. The reaction of anilines bearing a tetraenyne and pentaenyne moiety allows direct construction of highly fused carbazoles by tetra- and pentacyclization, respectively, through hydroamination and consecutive hydroarylation without producing any theoretical waste products from the substrates.