(2-propyl)-3,4,6-tri-O-acetyl-2-allyloxycarbonylamino-2-deoxy-α-D-glucopyranoside | 142544-00-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (2-propyl)-3,4,6-tri-O-acetyl-2-allyloxycarbonylamino-2-deoxy-α-D-glucopyranoside
• 英文别名: [(2R,3S,4R,5R,6S)-3,4-diacetyloxy-6-propan-2-yloxy-5-(prop-2-enoxycarbonylamino)oxan-2-yl]methyl acetate
• CAS: 142544-00-1
• 化学式: C₁₉H₂₉NO₁₀
• 分子量: 431.44
• InChiKey: SXGJTCXDMSKVMG-ZKXLYKBJSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1
• 重原子数：
  30
• 可旋转键数：
  13
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.68
• 拓扑面积：
  136
• 氢给体数：
  1
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  1,3,4,6-tetra-O-acetyl-2-deoxy-2-(allyloxycarbonylamino)-β-D-glucopyranose 、 异丙醇 在 三氟甲磺酸三甲基硅酯 作用下， 以 硝基甲烷 为溶剂， 反应 1.0h， 以3%的产率得到1-methylethyl 3,4,6-tri-O-acetyl-2-allyloxycarbonylamino-2-deoxy-β-D-glucopyranoside
  参考文献：
  名称：

  Glycosylations with tetra-O-acetyl-N-allyloxycarbonylamino-2-deoxy-β-D-glucose in polar solvents

  摘要：

  Glycosylations with the title compound were performed in dimethylformamide, acetonitrile, and nitromethane. The latter solvent was found to give good results whereas DMF caused 1-O-deacetylation.

  DOI：

  10.1016/s0040-4020(01)92269-0

文献信息

• Glycosylations with tetra-O-acetyl-N-allyloxycarbonylamino-2-deoxy-β-D-glucose in polar solvents
  作者：Frauke Heinemann、Monika Hiegemann、Peter Welzel

  DOI：10.1016/s0040-4020(01)92269-0

  日期：——

  Glycosylations with the title compound were performed in dimethylformamide, acetonitrile, and nitromethane. The latter solvent was found to give good results whereas DMF caused 1-O-deacetylation.