dimethyl 1-nonyl-1H-1,2,3-triazole-4,5-dicarboxylate | 1222558-92-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: dimethyl 1-nonyl-1H-1,2,3-triazole-4,5-dicarboxylate
• 英文别名: Dimethyl 1-nonyltriazole-4,5-dicarboxylate；dimethyl 1-nonyltriazole-4,5-dicarboxylate
• CAS: 1222558-92-0
• 化学式: C₁₅H₂₅N₃O₄
• 分子量: 311.381
• InChiKey: XCENQHRRRIRTQC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  22
• 可旋转键数：
  12
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  83.3
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  1-azidononane 、 丁炔二酸二甲酯 在 polymer-supported terpyridine-copper(I) complex 作用下， 以 水 为溶剂， 反应 6.0h， 以54%的产率得到dimethyl 1-nonyl-1H-1,2,3-triazole-4,5-dicarboxylate
  参考文献：
  名称：

  Reusable Polymer-Supported Terpyridine Copper Complex for [3+2] Huisgen Cycloaddition in Water

  摘要：

  A polymer-supported terpyridine copper(I) complex was prepared and found to promote the Huisgen [3+2] cycloaddition reaction between azides and alkynes in water to give the corresponding triazoles with up to 87% isolated yield. This catalyst was recovered and reused several times without any loss in catalytic activity.

  DOI：

  10.3987/com-09-11872

文献信息

• Reusable Polymer-Supported Terpyridine Copper Complex for [3+2] Huisgen Cycloaddition in Water
  作者：Toshimasa Suzuka、Kazumasa Ooshiro、Ken’yu Kina

  DOI：10.3987/com-09-11872

  日期：——

  A polymer-supported terpyridine copper(I) complex was prepared and found to promote the Huisgen [3+2] cycloaddition reaction between azides and alkynes in water to give the corresponding triazoles with up to 87% isolated yield. This catalyst was recovered and reused several times without any loss in catalytic activity.