2-(2-(hexyloxy)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolan | 921937-74-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 2-(2-(hexyloxy)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolan
• 英文别名: 2-[2-(Hexyloxy)phenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane；2-(2-hexoxyphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
• CAS: 921937-74-8
• 化学式: C₁₈H₂₉BO₃
• 分子量: 304.237
• InChiKey: DRQYKONTWMGDGX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.94
• 重原子数：
  22
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-(2-(hexyloxy)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolan 在 四(三苯基膦)钯 、 palladium on activated charcoal 、 氢气 、 potassium carbonate 作用下， 以 四氢呋喃 、 乙二醇二甲醚 为溶剂， 生成 9-hexyl-6-(2-(hexyloxy)phenyl)-9H-carbazol-3-amine
  参考文献：
  名称：

  Novel Triphenylamine Donors with Carbazole Moieties for Organic Sensitizers toward Cobalt(II/III) Redox Mediators

  摘要：

  A series of D-π-A organic dyes, X72-75, containing novel triarylamine electron donors have been synthesized for dye-sensitized solar cells (DSCs). The superiority of the asymmetric design of the triphenylamine electron donor over the symmetrical triphenylamine when applied in organic dyes for cobalt cells has been observed. Using X72 with the cobalt(II/III) redox shuttle resulted in an overall power conversion efficiency (PCE) of 9.18%, outperforming the state-of-the-art dye C218 under the same conditions.

  DOI：

  10.1021/ol5018036

文献信息

• Novel Triphenylamine Donors with Carbazole Moieties for Organic Sensitizers toward Cobalt(II/III) Redox Mediators
  作者：Yulin Tan、Mao Liang、Ziyi Lu、Yequan Zheng、Xinli Tong、Zhe Sun、Song Xue

  DOI：10.1021/ol5018036

  日期：2014.8.1

  A series of D-π-A organic dyes, X72-75, containing novel triarylamine electron donors have been synthesized for dye-sensitized solar cells (DSCs). The superiority of the asymmetric design of the triphenylamine electron donor over the symmetrical triphenylamine when applied in organic dyes for cobalt cells has been observed. Using X72 with the cobalt(II/III) redox shuttle resulted in an overall power conversion efficiency (PCE) of 9.18%, outperforming the state-of-the-art dye C218 under the same conditions.