3-phenyl-5,6,7,8-tetrahydro-1,2,4-triazolo<4,3-a>pyridine | 89569-61-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 3-phenyl-5,6,7,8-tetrahydro-1,2,4-triazolo<4,3-a>pyridine
• 英文别名: 3-phenyl-5,6,7,8-tetrahydro-4H-1,2,4-triazolo[4,3-a]pyridine；3-Phenyl-5,6,7,8-tetrahydro[1,2,4]triazolo[4,3-a]pyridine；3-phenyl-5,6,7,8-tetrahydro-[1,2,4]triazolo[4,3-a]pyridine
• CAS: 89569-61-9
• 化学式: C₁₂H₁₃N₃
• mdl: MFCD01936285
• 分子量: 199.255
• InChiKey: YAFWREOXXLJOQZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  15
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.333
• 拓扑面积：
  30.7
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  3-苯基-1,2,4-三唑并[4,3-a]吡啶 在 palladium on activated charcoal 氢气 作用下， 以 盐酸 、 乙醇 为溶剂， 以8 g的产率得到3-phenyl-5,6,7,8-tetrahydro-1,2,4-triazolo<4,3-a>pyridine
  参考文献：
  名称：

  Bonanomi, Michele; Baiocchi, Leandro, Journal of Heterocyclic Chemistry, 1983, vol. 20, p. 1657 - 1660

  摘要：

  DOI：

文献信息

• Organometallic Complex, Light-Emitting Element, Light-Emitting Device, Electronic Device, and Lighting Device
  申请人：Inoue Hideko

  公开号：US20130002131A1

  公开（公告）日：2013-01-03

  An organometallic complex emitting blue phosphorescence which can be manufactured inexpensively is provided. An organometallic complex in which nitrogen at the 1-position of a 5-aryl-4H-1,2,4-triazole derivative is coordinated to a Group 9 metal or a Group 10 metal, the aryl group is bonded to the Group 9 metal or the Group 10 metal, and the 5-aryl-4H-1,2,4-triazole derivative is a 3-aryl-5,6,7,8-tetrahydro-4H-[1,2,4]triazolo[4,3-a]pyridine derivative is provided. The organometallic complex emits green to blue phosphorescence and has a cost advantage.

  提供了一种能够廉价制造的有机金属配合物，其发出蓝色荧光。该有机金属配合物中，5-芳基-4H-1,2,4-三唑衍生物的1位氮原子配位于第9族金属或第10族金属上，芳基基团与第9族金属或第10族金属键合，5-芳基-4H-1,2,4-三唑衍生物是3-芳基-5,6,7,8-四氢-4H-[1,2,4]三唑并[4,3-a]吡啶衍生物。该有机金属配合物发出绿色到蓝色荧光，并具有成本优势。
• BONANOMI, M.;BAIOCCHI, L., J. HETEROCYC. CHEM., 1983, 20, N 6, 1657-1660
  作者：BONANOMI, M.、BAIOCCHI, L.

  DOI：——

  日期：——
• Light-Emitting Element, Light-Emitting Device, Electronic Device, and Lighting Device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US20140175413A1

  公开（公告）日：2014-06-26

  An organometallic complex which can be provided at low cost and which emits blue phosphorescence is provided. An organometallic complex in which nitrogen at the 1-position of a 5-aryl-4H-1,2,4-triazole derivative is coordinated to a Group 9 metal or a Group 10 metal, the aryl group is bonded to the Group 9 metal or the Group 10 metal, and the 5-aryl-4H-1,2,4-triazole derivative is a 3-aryl-5,6,7,8-tetrahydro-4H-[1,2,4]triazolo[4,3-a]pyridine derivative is provided. The organometallic complex emits green to blue phosphorescence and is also advantageous in terms of cost.
• US9273079B2
  申请人：——

  公开号：US9273079B2

  公开（公告）日：2016-03-01
• US9741946B2
  申请人：——

  公开号：US9741946B2

  公开（公告）日：2017-08-22