bis[bis(phenylthio)methyl]dimethylsilane | 1266779-29-6

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: bis[bis(phenylthio)methyl]dimethylsilane
• 英文别名: Bis[bis(phenylsulfanyl)methyl]-dimethylsilane；bis[bis(phenylsulfanyl)methyl]-dimethylsilane
• CAS: 1266779-29-6
• 化学式: C₂₈H₂₈S₄Si
• 分子量: 520.88
• InChiKey: WRBIMABRWBKTOT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.59
• 重原子数：
  33
• 可旋转键数：
  10
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  101
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  bis[bis(phenylthio)methyl]dimethylsilane 在 二氯二茂钛 、 magnesium 、 亚磷酸三乙酯 、 溶剂黄146 作用下， 以 四氢呋喃 、 水 为溶剂， 25.0 ℃ 、399.97 Pa 条件下， 反应 15.0h， 以45%的产率得到dimethylbis<(phenylthio)methyl>silane
  参考文献：
  名称：

  Stereoselective formation of phenylthio groups substituted 1-metalla-3-titanacyclobutanes

  摘要：

  Desulfurizative titanation of group 14 metal compounds bearing two or four bis(phenylthio)methyl groups with the low-valent titanium reagent Cp2Ti[P(OEt)(3)](2) produced phenylthio groups substituted 1-metalla-3-titanacyclobutanes stereoselectively. The molecular structures of the titanacycles were unambiguously confirmed by X-ray diffraction analysis. (c) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.09.080
• 作为产物：
  描述：

  双(苯硫基)甲烷 、 二氯二甲基硅烷 在 正丁基锂 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 1.0h， 以83%的产率得到bis[bis(phenylthio)methyl]dimethylsilane
  参考文献：
  名称：

  Stereoselective formation of phenylthio groups substituted 1-metalla-3-titanacyclobutanes

  摘要：

  Desulfurizative titanation of group 14 metal compounds bearing two or four bis(phenylthio)methyl groups with the low-valent titanium reagent Cp2Ti[P(OEt)(3)](2) produced phenylthio groups substituted 1-metalla-3-titanacyclobutanes stereoselectively. The molecular structures of the titanacycles were unambiguously confirmed by X-ray diffraction analysis. (c) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.09.080

文献信息

• Stereoselective formation of phenylthio groups substituted 1-metalla-3-titanacyclobutanes
  作者：Shigeki Oishi、Akira Tsubouchi、Takeshi Takeda

  DOI：10.1016/j.jorganchem.2010.09.080

  日期：2011.1

  Desulfurizative titanation of group 14 metal compounds bearing two or four bis(phenylthio)methyl groups with the low-valent titanium reagent Cp2Ti[P(OEt)(3)](2) produced phenylthio groups substituted 1-metalla-3-titanacyclobutanes stereoselectively. The molecular structures of the titanacycles were unambiguously confirmed by X-ray diffraction analysis. (c) 2010 Elsevier B.V. All rights reserved.