5,5'-carbonylbis(2-fluorobenzene-1-sulfonylchloride) | 923943-76-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 5,5'-carbonylbis(2-fluorobenzene-1-sulfonylchloride)
• 英文别名: 5-(3-Chlorosulfonyl-4-fluorobenzoyl)-2-fluorobenzenesulfonyl chloride；5-(3-chlorosulfonyl-4-fluorobenzoyl)-2-fluorobenzenesulfonyl chloride
• CAS: 923943-76-4
• 化学式: C₁₃H₆Cl₂F₂O₅S₂
• 分子量: 415.222
• InChiKey: GZPAFWKSDYPRJG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  24
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  102
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  4-[4-(cyanophenyl)azo]phenol 、 5,5'-carbonylbis(2-fluorobenzene-1-sulfonylchloride) 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 12.0h， 以88%的产率得到bis(4-((4-cyanophenyl)diazenyl)phenyl)5,5'-carbonylbis(2-fluorobenzenesulfonate)
  参考文献：
  名称：

  Synthesis and photoresponsive behaviors of novel poly(arylene ether)s with di-azobenzene pendants

  摘要：

  Novel poly(arylene ether)s containing di-azobenzene moieties (diazo-PAEs) were synthesized from a new di-azobenzene monomer, bis(4-((4-cyanophenyl)diazenyl)phenyl)5,5'-carbonylbis(2-fluorobenzenesulfonate). These polymers show good thermal stability, with glass transition temperatures and 5% weight-loss temperatures above 160 degrees C and 406 degrees C, respectively. Upon irradiation with a 532 nm neodymium dope yttrium aluminum garnet (Nd:YAG) laser beam, these polymers present a high remnant value, and no fatigue phenomena were observed after several cycles of inscription-erasure-inscription sequences. By exposing diazo-PAE films to an interference pattern of laser beams (355 nm) at modest intensity (approximately 80 mW/cm(2)), stable surface relief gratings (SRGs) can be formed. (c) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.reactfunctpolym.2011.01.011
• 作为产物：
  描述：

  sodium 5,5'-carbonylbis(2-fluorobenzene-sulfonate) 在 氯磺酸 作用下， 反应 4.0h， 以75%的产率得到5,5'-carbonylbis(2-fluorobenzene-1-sulfonylchloride)
  参考文献：
  名称：

  Synthesis and photoresponsive behaviors of novel poly(arylene ether)s with di-azobenzene pendants

  摘要：

  Novel poly(arylene ether)s containing di-azobenzene moieties (diazo-PAEs) were synthesized from a new di-azobenzene monomer, bis(4-((4-cyanophenyl)diazenyl)phenyl)5,5'-carbonylbis(2-fluorobenzenesulfonate). These polymers show good thermal stability, with glass transition temperatures and 5% weight-loss temperatures above 160 degrees C and 406 degrees C, respectively. Upon irradiation with a 532 nm neodymium dope yttrium aluminum garnet (Nd:YAG) laser beam, these polymers present a high remnant value, and no fatigue phenomena were observed after several cycles of inscription-erasure-inscription sequences. By exposing diazo-PAE films to an interference pattern of laser beams (355 nm) at modest intensity (approximately 80 mW/cm(2)), stable surface relief gratings (SRGs) can be formed. (c) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.reactfunctpolym.2011.01.011

文献信息

• BIS(ARYL)SULFONIMIDE FUNCTIONALIZED ION CONDUCTING POLYMERS
  申请人：Olmeijer David

  公开号：US20080286626A1

  公开（公告）日：2008-11-20

  The invention provides ion conducting copolymers containing pendant bis(aryl)sulfonimide groups that are used to make polymer electrolyte membranes (PEM's), catalyst coated proton exchange membranes (CCM's) and membrane electrode assemblies (MEA's) that are useful in fuel cells and their application in electronic devices, power sources and vehicles.
• US7288599B2
  申请人：——

  公开号：US7288599B2

  公开（公告）日：2007-10-30
• Synthesis and photoresponsive behaviors of novel poly(arylene ether)s with di-azobenzene pendants
  作者：Jingjing Zhang、Haibo Zhang、Xingbo Chen、Jinhui Pang、Yuxuan Zhang、Yongpeng Wang、Qidai Chen、Songhao Pei、Weixian Peng、Zhenhua Jiang

  DOI：10.1016/j.reactfunctpolym.2011.01.011

  日期：2011.5

  Novel poly(arylene ether)s containing di-azobenzene moieties (diazo-PAEs) were synthesized from a new di-azobenzene monomer, bis(4-((4-cyanophenyl)diazenyl)phenyl)5,5'-carbonylbis(2-fluorobenzenesulfonate). These polymers show good thermal stability, with glass transition temperatures and 5% weight-loss temperatures above 160 degrees C and 406 degrees C, respectively. Upon irradiation with a 532 nm neodymium dope yttrium aluminum garnet (Nd:YAG) laser beam, these polymers present a high remnant value, and no fatigue phenomena were observed after several cycles of inscription-erasure-inscription sequences. By exposing diazo-PAE films to an interference pattern of laser beams (355 nm) at modest intensity (approximately 80 mW/cm(2)), stable surface relief gratings (SRGs) can be formed. (c) 2011 Elsevier Ltd. All rights reserved.