4-oxospiro<4.5>decane-1-carboxylic acid | 150267-78-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 4-oxospiro<4.5>decane-1-carboxylic acid
• 英文别名: 4-oxo-spiro[4.5]decane-1-carboxylic acid；4-Oxo-spiro[4.5]decan-1-carbonsaeure；4-Oxospiro[4.5]decane-1-carboxylic acid；4-oxospiro[4.5]decane-1-carboxylic acid
• CAS: 150267-78-0
• 化学式: C₁₁H₁₆O₃
• 分子量: 196.246
• InChiKey: LNZALHZGWDHXRQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  14
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.82
• 拓扑面积：
  54.4
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4-oxospiro<4.5>decane-1-carboxylic acid 在 硫酸 作用下， 生成 4-semicarbazono-spiro[4.5]decane-1-carboxylic acid ethyl ester
  参考文献：
  名称：

  Crustal motion of Chinese mainland monitored by GPS

  摘要：

  To measure and monitor the crustal motion in China, a GPS network has been established with an average side length of 1 000 km and with more than 20 points on the margins of each major tectonic block and fault zone in China. Three campaigns were carried out in 1992,1994 and 1996, respectively by this network. Here we present, for the first time, the horizontal displacement rates of 22 GPS monitoring stations distributed over the whole China and global IGS stations surrounding China, based on these GPS repeated measurements. From these results by GPS, we have obtained the sketch of crustal motion in China.

  DOI：

  10.1007/bf02959450
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 硫酸 作用下， 生成 4-oxospiro<4.5>decane-1-carboxylic acid
  参考文献：
  名称：

  Chatterjee, Journal of the Indian Chemical Society, 1936, vol. 13, p. 536,540

  摘要：

  DOI：

文献信息

• A novel route to usefully functionalised spiro[n.4] systems; application to a formal synthesis of (±)-α-cedrene
  作者：Subrata Ghosh、Debasis Patra、Goutam Saha

  DOI：10.1039/c39930000783

  日期：——

  A facile route for the construction of functionalised spiro[n.4] systems through pinacol type rearrangement of appropriately designed cyclobutane derivatives with an application to a synthesis of (±)-α-cedrene is described.

  描述了一种通过适当设计的环丁烷衍生物的匹诺卡尔类型重排构建功能化螺环[n.4]系统的简便路线，并应用于(±)-α-雪松烯的合成。
• Patra, Debasis; Ghosh, Subrata, Journal of the Chemical Society. Perkin transactions I, 1995, # 20, p. 2635 - 2642
  作者：Patra, Debasis、Ghosh, Subrata

  DOI：——

  日期：——
• Chatterjee, Journal of the Indian Chemical Society, 1936, vol. 13, p. 536,540
  作者：Chatterjee

  DOI：——

  日期：——
• Crustal motion of Chinese mainland monitored by GPS
  作者：Wenyao Zhu、Xiaoya Wang、Zongyi Cheng、Yongqin Xiong、Qiang Zhang、Shuhua Ye、Zongjin Ma、Junyong Chen、Houze Xu、Ziqing Wei、Xi’an Lai、Jingnan Liu、Biaoren Jin、Jinwei Ren、Qi Wang

  DOI：10.1007/bf02959450

  日期：2000.8

  To measure and monitor the crustal motion in China, a GPS network has been established with an average side length of 1 000 km and with more than 20 points on the margins of each major tectonic block and fault zone in China. Three campaigns were carried out in 1992,1994 and 1996, respectively by this network. Here we present, for the first time, the horizontal displacement rates of 22 GPS monitoring stations distributed over the whole China and global IGS stations surrounding China, based on these GPS repeated measurements. From these results by GPS, we have obtained the sketch of crustal motion in China.