dimethyl benzoquinone-2,5-dicarboxylate | 99476-88-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: dimethyl benzoquinone-2,5-dicarboxylate
• 英文别名: 2,5-Di-methoxycarbonyl-benzochinon；Dimethyl 3,6-dioxocyclohexa-1,4-diene-1,4-dicarboxylate
• CAS: 99476-88-7
• 化学式: C₁₀H₈O₆
• 分子量: 224.17
• InChiKey: GKPFFRNBFZCNNY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.2
• 重原子数：
  16
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  86.7
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  dimethyl benzoquinone-2,5-dicarboxylate 在 溴 、 potassium iodide 作用下， 生成 2,5-dihydroxy-3,6-diiodo-terephthalic acid dimethyl ester
  参考文献：
  名称：

  Hantzsch, Chemische Berichte, 1915, vol. 48, p. 797,809

  摘要：

  DOI：
• 作为产物：
  描述：

  2,5-二羟基对苯二甲酸二甲酯 在 2,6-二叔丁基吡啶 、 tetramethylammonium tetrafluoroborate 作用下， 以 水 、 乙腈 为溶剂， 以10%的产率得到dimethyl benzoquinone-2,5-dicarboxylate
  参考文献：
  名称：

  Dimethyl benzoquinone-2,5-dicarboxylate

  摘要：

  DOI：

  10.1021/jo00225a093

文献信息

• PYRIMIDOQUINAZOLINE PIGMENT, METHOD FOR MANUFACTURING PYRIMIDOQUINAZOLINE PIGMENT, AND PIGMENT COLORANT
  申请人：DAINICHISEIKA COLOR & CHEMICALS MFG. CO., LTD.

  公开号：US20190233649A1

  公开（公告）日：2019-08-01

  The present invention provides a pyrimidoquinazoline pigment having a novel pyrimidine skeleton, the pyrimidoquinazoline pigment having excellent pigment properties, such as coloring power and durability, and excellent infrared reflectivity and a method for producing the pyrimidoquinazoline pigment, and a pigment colorant using the pyrimidoquinazoline pigment. The present invention relates to a pyrimidoquinazoline pigment represented by the following formula (1), wherein R 1 and R 2 each independently represent a benzene ring or a naphthalene ring optionally having a substituent, and a method for producing the pyrimidoquinazoline pigment. In addition, the present invention relates to a pigment colorant containing the pyrimidoquinazoline pigment.

  本发明提供了一种具有新型嘧啶骨架的嘧啶喹啉颜料，该嘧啶喹啉颜料具有优异的颜料性能，如着色力和耐久性，以及优异的红外反射性能，以及一种生产该嘧啶喹啉颜料的方法，以及使用该嘧啶喹啉颜料的颜料着色剂。本发明涉及以下式（1）所代表的嘧啶喹啉颜料，其中R1和R2分别独立地表示具有取代基的苯环或萘环，以及生产该嘧啶喹啉颜料的方法。此外，本发明还涉及包含该嘧啶喹啉颜料的颜料着色剂。
• Novel benzoquinone derivatives and their use as color-developers in recording material, process for their production and the production of corresponding hydroquinones
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0164260A1

  公开（公告）日：1985-12-11

  Disclosed herein is a novel benzoquinone derivative represented by the following general formula (I): wherein R, means an alkyl or cycloalkyl group, R2 denotes an alkyl or cycloalkyl group, a phenyl group which may optionally contain one or more halogen atoms and/or alkyl, cycloalkyl, alkoxy, alkylne, phenoxy, phenyl and/or biphenylyl groups, or a benzyl or naphthyl group which may optionally contain one or more methyl groups. This compound is useful as an oxidative color-developing agent for recording materials. The compound can be prepared by oxidation of the corresponding hydroquinone.

  本文公开了一种新型苯醌衍生物，由以下通式(I)表示： 其中，R 表示烷基或环烷基，R2 表示烷基或环烷基、苯基（可选择含有一个或多个卤素原子和/或烷基、环烷基、烷氧基、烷烃基、苯氧基、苯基和/或联苯基）或苄基或萘基（可选择含有一个或多个甲基）。该化合物可用作记录材料的氧化显色剂。该化合物可通过氧化相应的对苯二酚制备。
• Pyrimidoquinazoline pigment, method for manufacturing pyrimidoquinazoline pigment, and pigment colorant
  申请人：DAINICHISEIKA COLOR & CHEMICALS MFG. CO., LTD.

  公开号：US10655017B2

  公开（公告）日：2020-05-19

  The present invention provides a pyrimidoquinazoline pigment having a novel pyrimidine skeleton, the pyrimidoquinazoline pigment having excellent pigment properties, such as coloring power and durability, and excellent infrared reflectivity and a method for producing the pyrimidoquinazoline pigment, and a pigment colorant using the pyrimidoquinazoline pigment. The present invention relates to a pyrimidoquinazoline pigment represented by the following formula (1), wherein R1 and R2 each independently represent a benzene ring or a naphthalene ring optionally having a substituent, and a method for producing the pyrimidoquinazoline pigment. In addition, the present invention relates to a pigment colorant containing the pyrimidoquinazoline pigment.

  本发明提供了一种具有新型嘧啶骨架的嘧啶喹唑啉颜料，该嘧啶喹唑啉颜料具有优异的颜料特性，例如着色力和耐久性，以及优异的红外反射率，还提供了一种生产该嘧啶喹唑啉颜料的方法，以及一种使用该嘧啶喹唑啉颜料的颜料着色剂。本发明涉及一种由下式（1）表示的嘧啶喹唑啉颜料，其中 R1 和 R2 各自独立地代表一个苯环或一个可选具有取代基的萘环；本发明还涉及一种生产嘧啶喹唑啉颜料的方法。此外，本发明还涉及一种含有嘧啶喹唑啉颜料的颜料着色剂。
• REINHARDT, BRUCE A.;UNROE, MARILYN R.
  作者：REINHARDT, BRUCE A.、UNROE, MARILYN R.

  DOI：——

  日期：——
• Guan Xiao-Pei, Yu Yong-Zhong, Youji huaxue (Org. Chem), 14 (1994) N 1, S 80-84
  作者：Guan Xiao-Pei, Yu Yong-Zhong

  DOI：——

  日期：——