2-(3-hydroxyphenoxy)-5-chloropyrimidine | 73222-52-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-(3-hydroxyphenoxy)-5-chloropyrimidine
• 英文别名: 3-[5-chloro-2-pyrimidyloxy]phenol；3-[(5-Chloropyrimidin-2-yl)oxy]phenol；3-(5-chloropyrimidin-2-yl)oxyphenol
• CAS: 73222-52-3
• 化学式: C₁₀H₇ClN₂O₂
• 分子量: 222.631
• InChiKey: WZETVLSTARMGAG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  55.2
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2-(3-hydroxyphenoxy)-5-chloropyrimidine 生成 5-chloro-2-[3-chloro-5-(5-chloropyrimidin-2-yl)oxyphenoxy]pyrimidine
  参考文献：
  名称：

  SERBAN, A.;WATSON, K. G.;WARNER, R. B.

  摘要：

  DOI：

文献信息

• Use of 2-phenoxypyrimidines as herbicides
  申请人：ICI Australia Limited

  公开号：US04427437A1

  公开（公告）日：1984-01-24

  A process of inhibiting the growth of, severely damaging, or killing plants which process comprises applying to the plant or to the growth medium thereof an effective amount of a composition comprising as active ingredient a compound of formula I: ##STR1## wherein A, B and D are independently chosen from the group consisting of hydrogen, halogen, hydroxy, nitro, cyano, thiocyano, optionally substituted alkyl, optionally substituted alkenyl, optionally substituted alkoxy, optionally substituted alkenyloxy, optionally substituted alkynyloxy, optionally substituted alkylthio, optionally substituted cycloalkyl, optionally substituted amino, optionally substituted phenyl, carboxy, alkoxycarbonyl, optionally substituted carbamoyl, sulfo, alkylsulfonyl and optionally substituted sulfamoyl; R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are independently chosen from the group consisting of hydrogen, halogen, nitro, cyano, thiocyano, formyl, optionally substituted alkyl, optionally substituted alkenyl, optionally substituted cycloalkyl, optionally substituted alkylcarbonyl, optionally substituted amino, optionally substituted phenyl, optionally substituted carbamoyl, sulfo, alkoxysulfonyl, optionally substituted sulfamoyl and the groups YR.sup.1 and ##STR2## wherein Y is oxygen or sulphur and R.sup.1 is chosen from the group consisting of hydrogen, optionally substituted alkyl, optionally substituted alkenyl, optionally substituted alkynyl, optionally substituted cycloalkyl, optionally substituted acyl, optionally substituted alkoxycarbonyl, optionally substituted phenyl and the cation of an inorganic or organic base; X is oxygen or sulphur; and B, R.sup.3 and R.sup.5 are not all hydrogen; or a geometrical or optical isomer thereof; or a tautomer thereof; or a salt thereof; and a carrier therefor.

  一种抑制植物生长、严重破坏或杀死植物的过程，该过程包括向植物或其生长介质施加有效量的含有化合物I式的活性成分的组合物的步骤： 其中A、B和D分别选择自氢、卤素、羟基、硝基、氰基、硫氰基、可选择取代的烷基、可选择取代的烯基、可选择取代的烷氧基、可选择取代的烯氧基、可选择取代的炔氧基、可选择取代的硫代烷基、可选择取代的环烷基、可选择取代的氨基、可选择取代的苯基、羧基、烷氧羰基、可选择取代的氨基甲酰基、磺酰基、烷基磺酰基和可选择取代的磺酰胺基；R.sup.2、R.sup.3、R.sup.4、R.sup.5和R.sup.6分别选择自氢、卤素、硝基、氰基、硫氰基、甲酰基、可选择取代的烷基、可选择取代的烯基、可选择取代的环烷基、可选择取代的烷基羰基、可选择取代的氨基、可选择取代的苯基、可选择取代的氨基甲酰基、磺酰基、烷氧基磺酰基、可选择取代的磺酰胺基和基团YR.sup.1和 其中Y为氧或硫，R.sup.1选择自氢、可选择取代的烷基、可选择取代的烯基、可选择取代的炔基、可选择取代的环烷基、可选择取代的酰基、可选择取代的烷氧羰基、可选择取代的苯基以及无机或有机碱的阳离子；X为氧或硫；且B、R.sup.3和R.sup.5不全为氢；或其几何或光学异构体；或其互变异构体；或其盐；以及用于载体。
• Bis[pyrimidyloxy(thio)]benzene derivatives
  申请人：ICI Australia Limited

  公开号：US04248619A1

  公开（公告）日：1981-02-03

  The invention concerns novel compounds of the formula I ##STR1## wherein W and X are independently chosen from oxygen and sulfur. The compounds are herbicides and in further embodiments the invention provides: herbicidal compositions containing as active ingredient a compound of formula I; processes for severely damaging or killing unwanted plants by applying to the plants or to the growth medium of the plants an effective amount of a compound of formula I; and processes for the synthesis of compounds of formula I.

  本发明涉及一种新型化合物，其化学式为I ##STR1## 其中W和X独立地选择氧和硫。这些化合物是除草剂，在进一步实施中，本发明提供：包含化合物I作为活性成分的除草剂组合物；通过将化合物I施用于植物或植物的生长介质来严重损坏或杀死不需要的植物的过程；以及化合物I的合成过程。
• SERBAN, A.;WATSON, K. G.;WARNER, R. B.
  作者：SERBAN, A.、WATSON, K. G.、WARNER, R. B.

  DOI：——

  日期：——
• 2-phenoxy-pyrimidines and their use as pesticides
  申请人：ICI AUSTRALIA LIMITED

  公开号：EP0001187B1

  公开（公告）日：1983-12-07
• Bis(pyrimidyloxy)-, bis(pyrimidylthio)-, and pyrimidyloxy-pyrimidylthio-benzene derivatives and their use as herbicides, and processes of preparing them
  申请人：ICI AUSTRALIA LIMITED

  公开号：EP0008192B1

  公开（公告）日：1983-10-12