1,2-epoxy-4-(5-norbornen-2-yl)butane | 391241-47-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 环氧化物
• 英文名称: 1,2-epoxy-4-(5-norbornen-2-yl)butane
• 英文别名: 2-[2-(2-Bicyclo[2.2.1]hept-5-enyl)ethyl]oxirane
• CAS: 391241-47-7
• 化学式: C₁₁H₁₆O
• 分子量: 164.247
• InChiKey: DNKWNPPMHHHLPK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.82
• 拓扑面积：
  12.5
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1,2-epoxy-4-(5-norbornen-2-yl)butane 、 丙二酸二叔丁酯 在 溶剂黄146 作用下， 以 四氢呋喃 为溶剂， 生成 γ-2-(5-norbornen-2-yl)ethyl-γ-butyrolactone
  参考文献：
  名称：

  Novel lactone compounds having alicyclic structure and their manufacturing method

  摘要：

  公式（1）的内酯化合物是一种新颖且有用的单体，可用于形成基础树脂，用于化学放大的抗蚀剂组合物，适用于微细图案化的光刻。其中，字母k为0或1，m为1-8的整数。

  公开号：

  US20020016477A1

文献信息

• HINDERED AMINE STABILIZED UV ACTIVE ORGANOPALLADIUM CATALYZED POLYCYCLOOLEFIN COMPOSITIONS AS OPTICAL MATERIALS
  申请人：PROMERUS, LLC

  公开号：US20220002453A1

  公开（公告）日：2022-01-06

  Embodiments in accordance with the present invention encompass compositions comprising a organopalladium compound, a photoacid generator, a photosensitizer, one or more olefinic monomers and a stabilizer, such as for example a hindered amine, which undergo vinyl addition polymerization when said composition is exposed to a suitable actinic radiation to form a substantially transparent film. The compositions of this invention are stable at room temperature for several days to several months and can also be stored at higher temperatures from about 40° C. to 60° C. for several days and undergo mass polymerization only when subjected to suitable actinic radiation. The monomers employed therein have a range of optical and mechanical properties, and thus these compositions can be tailored to form films having various opto-electronic properties. Accordingly, compositions of this invention are useful in various applications, including as coatings, encapsulants, fillers, leveling agents, sealants, adhesives, among others.
• US6472543B2
  申请人：——

  公开号：US6472543B2

  公开（公告）日：2002-10-29
• [EN] HINDERED AMINE STABILIZED UV ACTIVE ORGANOPALLADIUM CATALYZED POLYCYCLOOLEFIN COMPOSITIONS AS OPTICAL MATERIALS<br/>[FR] COMPOSITIONS DE POLYCYCLOOLÉFINE CATALYSÉES PAR ORGANOPALLADIUM ACTIVES AUX UV STABILISÉES PAR AMINE ENCOMBRÉE EN TANT QUE MATÉRIAUX OPTIQUES
  申请人：PROMERUS LLC

  公开号：WO2021262921A1

  公开（公告）日：2021-12-30

  Embodiments in accordance with the present invention encompass compositions comprising a organopalladium compound, a photoacid generator, a photosensitizer, one or more olefinic monomers and a stabilizer, such as for example a hindered amine, which undergo vinyl addition polymerization when said composition is exposed to a suitable actinic radiation to form a substantially transparent film. The compositions of this invention are stable at room temperature for several days to several months and can also be stored at higher temperatures from about 40 °C to 60° C for several days and undergo mass polymerization only when subjected to suitable actinic radiation. The monomers employed therein have a range of optical and mechanical properties, and thus these compositions can be tailored to form films having various opto-electronic properties. Accordingly, compositions of this invention are useful in various applications, including as coatings, encapsulants, fillers, leveling agents, sealants, adhesives, among others.
• Novel lactone compounds having alicyclic structure and their manufacturing method
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：US20020016477A1

  公开（公告）日：2002-02-07

  Lactone compounds of formula (1) are novel and useful as monomers to form base resins for use in chemically amplified resist compositions adapted for micropatterning lithography. 1 Letter k is 0 or 1 and m is an integer of 1-8.

  公式（1）的内酯化合物是一种新颖且有用的单体，可用于形成基础树脂，用于化学放大的抗蚀剂组合物，适用于微细图案化的光刻。其中，字母k为0或1，m为1-8的整数。