10H-thieno<3,2-a>carbazole | 240-14-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 10H-thieno<3,2-a>carbazole
• 英文别名: 10H-thieno[3,2-a]carbazole；10H-Thieno[3,2-a]carbazol；10H-Thieno[3,2-a]carbazole
• CAS: 240-14-2
• 化学式: C₁₄H₉NS
• 分子量: 223.298
• InChiKey: DLYCQVMEMCMHQL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  44
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  10H-thieno<3,2-a>carbazole 、 硫酸二甲酯 在 乙醚 、 乙基溴化镁 作用下， 生成 10-methyl-10H-thieno[3,2-a]carbazole
  参考文献：
  名称：

  CARCINOGENIC DERIVATIVES OF CARBAZOLE. II. ISOSTERIC COMPOUNDS OF CARBAZOLE CONTAINING A THIOPHENE NUCLEUS¹

  摘要：

  DOI：

  10.1021/jo01157a013
• 作为产物：
  描述：

  5,10-dihydro-4H-thieno[3,2-a]carbazole 在 四氯苯醌 、 xylene 作用下， 生成 10H-thieno<3,2-a>carbazole
  参考文献：
  名称：

  CARCINOGENIC DERIVATIVES OF CARBAZOLE. II. ISOSTERIC COMPOUNDS OF CARBAZOLE CONTAINING A THIOPHENE NUCLEUS¹

  摘要：

  DOI：

  10.1021/jo01157a013

文献信息

• COMPOUNDS HAVING PHOTOCHEMICALLY REMOVABLE PROTECTING GROUPS BASED ON AN ELECTROCYCLIC REACTION BETWEEN A CHROMOPHORE ATTACHED VIA AN ANILIDE GROUP TO A BENZOTHIOPHENE RING
  申请人：MARQUETTE UNIVERSITY

  公开号：US20130231484A1

  公开（公告）日：2013-09-05

  Disclosed herein are compounds having photoremovable protecting groups which are removed after the compounds absorbs light of a given wavelength and undergo an electrocyclic reaction between a chromophore in the compound attached via an anilide to a benzothiophene ring.

  本文披露了一种化合物，其具有光可去保护基团，该基团在化合物吸收特定波长的光并在连接到苯并噻吩环的苯胺上的染料团之间发生电环反应后被去除。
• NOVEL COMPOUND AND ORGANIC ELECTROLUMINESCENCE DEVICE COMPRISING SAME
  申请人：DOOSAN CORPORATION

  公开号：US20150236271A1

  公开（公告）日：2015-08-20

  The present invention relates to a novel compound and an organic electroluminescence device including the same, and the compound according to the present invention may be used in an organic material layer, preferably a light-emitting layer of an organic electroluminescence device, thereby enhancing the light-emitting efficiency, driving voltage, lifespan, and the like of the organic electroluminescence device.

  本发明涉及一种新型化合物和包括该化合物的有机电致发光装置，根据本发明的化合物可用于有机材料层，特别是有机电致发光装置的发光层中，从而提高有机电致发光装置的发光效率、驱动电压、寿命等。
• A method for preventing deposition of polymer scale and a coating agent therefor
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP0126991A1

  公开（公告）日：1984-12-05

  The invention provides a method for preventing deposition of polymer scale on the reactor walls in the polymerization of an ethylenically unsaturated monomer, in particular, by emulsion polymerization. The method comprises coating the reactor walls with a coating composition containing, as the essential components, (A) an organic compound having at least 5 conjugated π bonds in a molecule, (B) a chelating agent and (C) a metal compound capable of producing metal ions having a coordination number of at leas 2 which presumably forms a metallic chelate compound with the chelating agent contributing to the formation of a strongly adsorbed layer on the reactor walls. The coating composition may be further admixed with a silicic acid compound such as a colloidal silica.

  本发明提供了一种在乙烯基不饱和单体聚合，特别是乳液聚合过程中防止聚合物垢沉积在反应器壁上的方法。该方法包括在反应器壁上涂上涂层组合物，涂层组合物的主要成分包括：(A) 分子中至少有 5 个共轭 π 键的有机化合物；(B) 螯合剂；(C) 能够产生配位数至少为 2 的金属离子的金属化合物，该金属离子可与螯合剂形成金属螯合物，从而在反应器壁上形成强吸附层。涂层组合物还可进一步掺入硅酸化合物，如胶体二氧化硅。
• Enzymatic encoding methods for efficient synthesis of large libraries
  申请人：Nuevolution A/S

  公开号：EP2341140A1

  公开（公告）日：2011-07-06

  Disclosed is a method for obtaining a bifunctional complex comprising a molecule linked to a single stranded identifier oligonucleotide, wherein a nascent bifunctional complex comprising a chemical reaction site and a priming site for enzymatic addition of a tag is a) reacted at the chemical reaction site with one or more reactants, and b) reacted enzymatically at the priming site with one or more tag(s) identifying the reactant(s).

  本发明公开了一种获得双功能复合物的方法，该复合物由与单链标识寡核苷酸相连的分子组成，其中包含化学反应位点和用于酶加标记的引物位点的新生双功能复合物 a) 在化学反应位点与一种或多种反应物反应，b) 在引物位点与一种或多种标识反应物的标记进行酶反应。
• ORGANIC ELECTROLUMINESCENCE DEVICE
  申请人：Samsung Display Co., Ltd.

  公开号：EP3800679A1

  公开（公告）日：2021-04-07

  An organic electroluminescence device according to an embodiment of the present disclosure includes a first electrode, a second electrode, and an emission layer. The emission layer includes host compounds and dopant compounds. The hot compounds include a first host compound represented by Formula 1, and a second host compound represented by Formula 2, and the dopant compounds include an assistant dopant compound represented by Formula 3, and a light-emitting dopant compound represented by Formula 4: Accordingly, the organic electroluminescence device according to an embodiment may achieve high efficiency and long life.

  根据本公开的一个实施例，一种有机电致发光器件包括第一电极、第二电极和发射层。发射层包括宿主化合物和掺杂化合物。热化合物包括由式1表示的第一宿主化合物和由式2表示的第二宿主化合物，掺杂化合物包括由式3表示的辅助掺杂化合物和由式4表示的发光掺杂化合物： 因此，根据一个实施例的有机电致发光器件可实现高效率和长寿命。