(3E,7E)-1,1,1,10,10,10-hexachloro-4,7-dimethoxydeca-3,7-diene-2,9-dione

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (3E,7E)-1,1,1,10,10,10-hexachloro-4,7-dimethoxydeca-3,7-diene-2,9-dione
• 化学式: C₁₂H₁₂Cl₆O₄
• 分子量: 432.9
• InChiKey: HPKGONPDLFYGCN-KQQUZDAGSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  22
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

文献信息

• ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES
  申请人：Universal Display Corporation

  公开号：US20150380666A1

  公开（公告）日：2015-12-31

  Compounds having the structure of Formula M(L A ) x (L B ) y and Formula III, are disclosed. In Formula M(L A ) x (L B ) y , Ligand L A is and ligand L B is a mono anionic bidentate ligand. In these compounds, metal M has an atomic number greater than 40; x is 1, 2, or 3; y is 0, 1, or 2; x+y is the oxidation state of metal M; L 11 represents a linking group selected from alkyl, cycloalkyl, aryl, and heteroaryl; L 12 represents a linking group selected from NR 15 and PR 15 ; each R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 11 , R 12 , R 13 , R 14 , and R 15 is independently selected from a group of substituents, wherein any adjacent substituents are optionally joined to form a fused or unfused ring; and L A and L B are optionally joined to form a ligand that is at least tetradentate. Formulations and devices, such as OLEDs, that include the compound of Formula M(L A ) x (L B ) y are also described.

  揭示了具有FormuLA M(LA)x(LB)y和FormuLA III结构的化合物。在FormuLA M(LA)x(LB)y中，配体LA和配体LB分别是单阴离子双齿配体。在这些化合物中，金属M的原子序数大于40；x为1、2或3；y为0、1或2；x+y为金属M的氧化态；L11代表从烷基、环烷基、芳基和杂环烷基中选择的连接基；L12代表从NR15和PR15中选择的连接基；每个R1、R2、R3、R4、R5、R6、R11、R12、R13、R14和R15都是从一组取代基中独立选择的，其中任何相邻的取代基可以选择连接以形成融合或非融合环；LA和LB可以选择连接以形成至少四齿配体。还描述了包括FormuLA M(LA)x(LB)y化合物的配方和器件，例如OLEDs。
• Organic electroluminescent materials and devices
  申请人：Universal Display Corporation

  公开号：US10700293B2

  公开（公告）日：2020-06-30

  Compounds having the structure of Formula M(LA)x(LB)y and Formula III, are disclosed. In Formula M(LA)x(LB)y, Ligand LA is and ligand LB is a mono anionic bidentate ligand. In these compounds, metal M has an atomic number greater than 40; x is 1, 2, or 3; y is 0, 1, or 2; x+y is the oxidation state of metal M; L11 represents a linking group selected from alkyl, cycloalkyl, aryl, and heteroaryl; L12 represents a linking group selected from NR15 and PR15; each R1, R2, R3, R4, R5, R6, R11, R12, R13, R14, and R15 is independently selected from a group of substituents, wherein any adjacent substituents are optionally joined to form a fused or unfused ring; and LA and LB are optionally joined to form a ligand that is at least tetradentate. Formulations and devices, such as OLEDs, that include the compound of Formula M(LA)x(LB)y(LC)z are also described.

  具有式 M(LA)x(LB)y 和式 III 结构的化合物、 公开了具有式 M(LA)x(LB)y 和式 III 结构的化合物。在式 M(LA)x(LB)y 中，配体 LA 是 配体 LB 是单阴离子双齿配体。在这些化合物中，金属 M 的原子序数大于 40；x 为 1、2 或 3；y 为 0、1 或 2；x+y 为金属 M 的氧化态；L11 代表选自烷基、环烷基、芳基和杂芳基的连接基团；L12 代表选自 NR15 和 PR15 的连接基团；每个 R1、R2、R3、R4、R5、R6、R11、R12、R13、R14 和 R15 都独立地选自一组取代基，其中任何相邻取代基可选择连接以形成融合或未融合的环；以及 LA 和 LB 可选择连接以形成至少为四价的配体。还描述了包括式 M(LA)x(LB)y(LC)z 的化合物的制剂和器件，如 OLED。
• US9911931B2
  申请人：——

  公开号：US9911931B2

  公开（公告）日：2018-03-06