METHOD FOR PURIFYING TETRAKIS(FLUOROARYL) BORATE/MAGNESIUM HALIDE, TETRAKIS(FLUOROARYL) BORATE/ETHER COMPLEX AND PROCESS FOR PREPARING THE SAME, AND PROCESS FOR PREPARING TETRAKIS(FLUOROARYL) BORATE DERIVATIVE
申请人:Nippon Shokubai Co., Ltd.
公开号:EP0913400A1
公开(公告)日:1999-05-06
A method for purifying Ar4 BMgX which comprises treating a tetrakis(fluoroaryl) borate/magnesium halide (Ar4BMgX) with (1) an alkaline (earth) metal salt of carboxylic acid, (2) an acid, (3) an acid and then an alkaline (earth) metal hydroxide, or (4) an acid and then an alkaline (earth) metal salt of carboxylic acid; and a process for preparing a tetrakis(fluoroaryl) borate derivative (Ar4BZ) which comprises reacting the treated Ar4BMgX with a compound capable of generating monovalent cationic species. The above purification method permits separation and removal of impurities contained in Ar4 BMgX in an efficient and simple manner. The invention also provides a tetrakis(fluoroaryl) borate/ether complex, a process for preparing the same, and a process for preparing a tetrakis(fluoroaryl) borate derivative (Ar4BZ) by using the ether complex and the compound capable of generating monovalent cationic species as starting compounds. The ether complex can be easily purified to a high purity and hence is suitable as an intermediate for the preparation of various tetrakis(fluoroaryl) borate derivatives.
一种提纯 Ar4 BMgX 的方法,包括用(1)羧酸的碱(土)金属盐、(2)酸、(3)酸然后碱(土)金属氢氧化物或(4)酸然后羧酸的碱(土)金属盐处理四(氟芳基)硼酸盐/卤化镁(Ar4BMgX);以及制备四(氟芳基)硼酸酯衍生物(Ar4BZ)的工艺,包括将处理过的 Ar4BMgX 与能够生成一价阳离子物种的化合物反应。上述纯化方法可以高效、简单地分离和去除 Ar4 BMgX 中所含的杂质。本发明还提供了一种四(氟芳基)硼酸酯/醚络合物、制备四(氟芳基)硼酸酯/醚络合物的工艺,以及以醚络合物和能够生成一价阳离子种类的化合物为起始化合物制备四(氟芳基)硼酸酯衍生物(Ar4BZ)的工艺。醚络合物很容易提纯到高纯度,因此适合用作制备各种四(氟芳基)硼酸酯衍生物的中间体。