cadmium monoiodide | 14184-47-5

• 分子结构分类: 无机化合物 - 均质非金属化合物 - 卤代有机物
• 英文名称: cadmium monoiodide
• CAS: 14184-47-5
• 化学式: CdI
• 分子量: 239.315
• InChiKey: VNSNFZOWMGOSBX-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  cadmium(II) iodide 在 氮 作用下， 生成 cadmium monoiodide
  参考文献：
  名称：

  Excitation of HgI(B), CdI(B), ZnI(B), PbI(B), CdBr(B), and ZnBr(B) by excitation-transfer reactions of N2(A) with the dihalide compounds

  摘要：

  DOI：

  10.1016/0301-0104(90)80088-f

文献信息

• Jet emission spectra of cadmium monoiodide and mercury monoiodide and near-dissociation theory analyses for cadmium monoiodide and zinc monoiodide
  作者：K. J. Jordan、R. H. Lipson、N. A. McDonald、R. J. LeRoy

  DOI：10.1021/j100191a012

  日期：1992.6

  Emissions from CdI and HgI produced in a corona-excited supersonic jet discharge were photographed in high resolution. A study of the vibrationally and isotopically resolved spectra for the CdI ultraviolet D2-PI-3/2-X2-SIGMA+ transition near 338.4 nm and visible B2-SIGMA+-X2-SIGMA+ transition near 646.5 nm has yielded vibrational constants for the X, B, and D electronic states and estimates of their dissociation energies. Use of near-dissociation expansion analyses has yielded much mom reliable extrapolation properties for this system, and for the analogous states of ZnI, than use of conventional techniques. The analysis of the HgI B-X spectrum near 420 nm was found to be in excellent agreement with previous studies. The trends in the X- and B-state constants for the MI series (M = Zn, Cd, Hg) including dissociation energies derived from near-dissociation theory are rationalized in terms of the mixed ionic-covalent bonding expected for group IIB metal halide radicals.