[(Pd(CH2C9H6N))2bis(μ-trifluoroacetate)] | 158594-33-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯二氮卓类
• 英文名称: [(Pd(CH2C9H6N))2bis(μ-trifluoroacetate)]
• CAS: 158594-33-3
• 化学式: C₂₄H₁₆F₆N₂O₄Pd₂
• 分子量: 723.232
• InChiKey: KSZQNYFACUOBDI-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  [(Pd(CH2C9H6N))2bis(μ-trifluoroacetate)] 在 NaOH 作用下， 以 甲醇 、 水 为溶剂， 以70%的产率得到[Pd(CH2C9H6N)(μ-trifluoroacetate)(μ-OH)Pd(CH2C9H6N)]
  参考文献：
  名称：

  Synthesis and structural study of [{Pd(CH₂C₉H₆N)}₂(µ-O₂CR)(µ-X)] complexes (R = Me or CF₃; X = hydroxide, amide or thiolate)

  摘要：

  The di-mu-carboxylato complexes [{Pd(CH2C9H6N)(mu-O2CR)}2] (CH2C9H6N = 8-quinolylmethyl, R = Me or CF3) react in methanol with NaOH(aq) (1:1 molar ratio) to give the corresponding mixed hydroxocarboxylato-bridged complexes [{Pd(CHC9H6N)}2(mu-OH)(mu-O2CR)] (R = Me 1 or CF3 2). The reactions of 1 or 2 with arylamines or thiols (1:1 molar ratio) yielded the corresponding amido- or thiolato-carboxylato complexes [{Pd(CH2C9H6N)}2(mu-O2CMe)(mu-NHR)] (R = Ph 3, p-MeC6H4 4 or p-NO2C6H4 5) or [{Pd(CHC9H6N)}2(mu-O2CR)(mu-SR')] (R = Me, R' = Et 6, Bu(t) 7, Ph 8 orp-MeC6H4 9; R = CF3, R' = Bu(t) 10). The H-1 NMR data indicate a cis arrangement of the CH2C9H6N ligands. The crystal structure of complex 10 has been determined. It confirms the cis relationship of the CH2C9H6N ligands. The co-ordination at each palladium atom is approximately square planar and the oxygen atoms of the trifluoroacetate ligands are trans to carbon. The Pd2(mu-OCOCF3)(mu-SBu(t)) core is quite bent with an angle of 55-degrees between the two palladium co-ordination planes.

  DOI：

  10.1039/dt9940002353
• 作为产物：
  描述：

  三氟乙酸 、 [Pd(CH2-8-quinolyl)(OAc)]2 以 甲醇 为溶剂， 以70%的产率得到[(Pd(CH2C9H6N))2bis(μ-trifluoroacetate)]
  参考文献：
  名称：

  Synthesis and structural study of [{Pd(CH₂C₉H₆N)}₂(µ-O₂CR)(µ-X)] complexes (R = Me or CF₃; X = hydroxide, amide or thiolate)

  摘要：

  The di-mu-carboxylato complexes [{Pd(CH2C9H6N)(mu-O2CR)}2] (CH2C9H6N = 8-quinolylmethyl, R = Me or CF3) react in methanol with NaOH(aq) (1:1 molar ratio) to give the corresponding mixed hydroxocarboxylato-bridged complexes [{Pd(CHC9H6N)}2(mu-OH)(mu-O2CR)] (R = Me 1 or CF3 2). The reactions of 1 or 2 with arylamines or thiols (1:1 molar ratio) yielded the corresponding amido- or thiolato-carboxylato complexes [{Pd(CH2C9H6N)}2(mu-O2CMe)(mu-NHR)] (R = Ph 3, p-MeC6H4 4 or p-NO2C6H4 5) or [{Pd(CHC9H6N)}2(mu-O2CR)(mu-SR')] (R = Me, R' = Et 6, Bu(t) 7, Ph 8 orp-MeC6H4 9; R = CF3, R' = Bu(t) 10). The H-1 NMR data indicate a cis arrangement of the CH2C9H6N ligands. The crystal structure of complex 10 has been determined. It confirms the cis relationship of the CH2C9H6N ligands. The co-ordination at each palladium atom is approximately square planar and the oxygen atoms of the trifluoroacetate ligands are trans to carbon. The Pd2(mu-OCOCF3)(mu-SBu(t)) core is quite bent with an angle of 55-degrees between the two palladium co-ordination planes.

  DOI：

  10.1039/dt9940002353