(TPP)Ru(NO)(i-O-C5H11) | 246162-71-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: (TPP)Ru(NO)(i-O-C5H11)
• 英文别名: (tetraphenylporphyrinato dianion)Ru(NO)(O-i-C5H11)
• CAS: 246162-71-0
• 化学式: C₄₉H₃₉N₅O₂Ru
• 分子量: 830.951
• InChiKey: UOTJMVCJYAGIDM-NBICUONBSA-N

反应信息

• 作为反应物：
  描述：

  (TPP)Ru(NO)(i-O-C5H11) 、 三氯化硼 以 二氯甲烷 为溶剂， 生成 chloro-nitrosyl(meso-tetraphenylporphyrinato)ruthenium(II)
  参考文献：
  名称：

  Synthesis, characterization, and redox behavior of six-coordinate (por)Ru(NO)Cl compounds (por=porphyrinato dianion)

  摘要：

  A new high-yield preparative route to (por)Ru(NO)Cl compounds (por=porphyrinato dianion) from reactions of (por)Ru(NO)(alkoxide) precursors with boron trichloride is reported. These ruthenium nitrosyl chloride complexes are known to be useful precursors to (por)Ru(NO)-containing derivatives. The crystal structure of (OEP)Ru(NO)Cl (OEP = octaethylporphyrinato dianion) shows that the Ru-N-O linkage is linear. The redox behavior of the (por)Ru(NO)Cl compounds has been determined by cyclic voltammetry. Analysis of the data reveals that the first oxidation of the (por)Ru(NO)Cl compounds is porphyrin-ring centered. (c) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.06.031