| 724427-40-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• CAS: 724427-40-1
• 化学式: C₂₀H₂₂N₂Pt
• 分子量: 485.488
• InChiKey: BRLTVWXCNYTXMM-WNQUAZRHSA-N

反应信息

• 作为反应物：
  描述：

  、 、 乙酰氯 以 甲醇 、 二氯甲烷 为溶剂， 以38%的产率得到
  参考文献：
  名称：

  Five- and six-membered platinacycles derived from phenantryl and anthracenyl imines

  摘要：

  The reaction of [Pt2Me4(mu-SMe2)(2)] with ligands Me2NCH2CH2NCHAr (2a, Ar = 9-phenantryl; 2b, Ar = 9-anthracenyl) carried out in acetone at room temperature produced the corresponding Compounds [PtMe2{9-(Me2NCH2CH2NCH)C14H9}] (3) in which the imines act as bidentate [N,N'] ligands. Refluxing toluene solutions of compounds 3 gave cyclometallated [C,N,N] compounds [PtMe{9-(Me2NCH2CH2NCH)C14H8}] (4) as a mixture of two isomers containing either a five- or a six-membered metallacycles for 3a and as a single isomer containing a six-membered metallacycle for 3b. The reactions of compounds 4 with acetyl chloride and with methyl iodide produced. respectively, compounds [PtCl{9-(Me2NCH2CH2NCH)C14H8}] (5) and [PtMe2I{9-(Me2NCH2CH2NCH)C14H8}] (6). All compounds were characterised by NMR spectroscopies and analytical data. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.03.020
• 作为产物：
  描述：

  [PtMe2(Me2NC2H4NCH(phenanthryl))] 以 甲苯 为溶剂， 生成 、
  参考文献：
  名称：

  Five- and six-membered platinacycles derived from phenantryl and anthracenyl imines

  摘要：

  The reaction of [Pt2Me4(mu-SMe2)(2)] with ligands Me2NCH2CH2NCHAr (2a, Ar = 9-phenantryl; 2b, Ar = 9-anthracenyl) carried out in acetone at room temperature produced the corresponding Compounds [PtMe2{9-(Me2NCH2CH2NCH)C14H9}] (3) in which the imines act as bidentate [N,N'] ligands. Refluxing toluene solutions of compounds 3 gave cyclometallated [C,N,N] compounds [PtMe{9-(Me2NCH2CH2NCH)C14H8}] (4) as a mixture of two isomers containing either a five- or a six-membered metallacycles for 3a and as a single isomer containing a six-membered metallacycle for 3b. The reactions of compounds 4 with acetyl chloride and with methyl iodide produced. respectively, compounds [PtCl{9-(Me2NCH2CH2NCH)C14H8}] (5) and [PtMe2I{9-(Me2NCH2CH2NCH)C14H8}] (6). All compounds were characterised by NMR spectroscopies and analytical data. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.03.020